Dual-layer Janus charged nanofiltration membranes constructed by sequential electrospray polymerization for efficient water softening
The separation of hardness ions such as calcium and magnesium from hard water can improve water quality, which is important but technically challenging. Nanofiltration (NF) has attracted much attention because of its efficiency, environmental friendliness and low cost. However, common NF membranes with a singly (either positively or negatively) charged layer have insufficient water softening capacity. In this work, two types of dual-layer Janus charged polyamide NF membranes composed of oppositely charged inner and outer layers were developed for the first time by sequential electrospray polymerization strategy for efficient water softening. The effect of the microstructure of the dually charged barrier layer on the separation performance of divalent salt ions was explored. Detailed mechanistic studies revealed that the microstructure of the outer layer of the barrier layer played a crucial role in the ion separation of the Janus membrane due to its control of the reverse transport of ions. Janus charged polyamide NF membrane with a loose outer layer exhibited better water softening performance (93.6% of hardness removed) compared to the singly charged NF membranes due to the simultaneous dual electrostatic effect and no ion reverse transport confinement. This Janus charged NF membrane also possessed good antifouling performance, mainly due to its negatively charged outer layers. The mechanistic insights gained in this study reveal the huge potential of microstructural design toward high-performance Janus charged NF membranes, and provide important guidance on the future development of high-efficiency water softening NF membranes.
危险品化学品经营许可证（带存储）