As a luxurious textile for more than five thousand years, silk fibers/products have always been favored by consumers and the markets, but the poor photostability seriously hinders its utilization in fashionable apparel. Even if enduing the functionality of silk fiber through surface modification, it is often at the expense of its comfort. Here, an ultra-thin amorphous titanium dioxide nano-film with a thickness of only five in a thousand of fiber diameter and the add-on percentage ≤ 5.33% was prepared on the surface of silk fibers/fabrics by atomic layer deposition (ALD) methods. The tensile strength of the modified silk fiber maintains 89.17% of the original fiber after exposure to UV light for 672 h. They can also withstand multi-cycle laundering and accelerate light-aging, which exhibiting an excellent UV resistance. Most importantly, the functional coating has a negligible impact on the comfortable and wearability performance of silk fibers/fabrics. In addition, ALD-coated silk fabric is also further used as an outdoor reflective cooling material and achieving a superior thermal insulation effect with the temperature reduction up to 10.1 °C.
Chung King Yan,Xu Bingang,Tan Di,Yang Qingjun,Li Zihua,Fu Hong
Naturally crosslinked carbonaceous liquid metal aqueous printable ink mediated by biopolymers.
E-textile with conductivity, stability, wearability, and aesthetic characteristics.
Multi-applications in health monitoring, pressure sensing, and energy harvesting.
Making a hydrogel-based first-aid bandage with green resources, desirable biocompatibility, universal adhesive properties, low cost and simple production is a long-standing research aspiration. Considering this, three naturally existing organic acids, namely tannic acid, thioctic acid and phytic acid, were used to construct a novel adhesive gel (TATAPA hydrogel) for epidermal tissue bandage applications. This hydrogel could be synthesized under mild conditions with no need for a freeze–thawing shaping procedure, and was transparent, moldable and stretchable with good stability under continuous water immersion. In lap-shear tests, the TATAPA hydrogel could adhere to various hydrophilic and hydrophobic surfaces. Moreover, in the case of skin tissue adhesion, the hydrogel could be easily peeled off from the skin, meeting wearability requirements. Rheological tests showed that the hydrogel possessed thermal sensitive properties derived from multi-supramolecular interactions. The methicillin-resistant Staphylococcus aureus (MRSA)-infected burn wound test demonstrated that the hydrogel had desirable antibacterial activity and was beneficial for wound healing. A femoral artery bleeding assay was also used to reveal that the TATAPA hydrogel could be directly pasted onto the bleeding site for hemostasis. Overall, this hydrogel demonstrates potential as a surgical bioadhesive for a broad range of medical applications.