The nano zero valent iron (nZVI) is an efficient environmental remediation material, but it is easy to be oxidized and agglomerated, which limits its application in the environment. In this paper, bacterial cellulose membrane was used as a carrier material to reduce three different concentrations of ferrous ions by in-situ liquid-phase reduction method using sodium borohydride , and three kinds of bacterial cellulose membrane loaded with nanometer zero valent iron (BC-nZVI) samples were successfully prepared. The physical and chemical properties of BC-nZVI before and after the reaction were characterized by SEM, XRD and XPS . The effects of pH, dose and reactive oxygen species (ROS) on the inactivation of bacteriophage MS2 were studied. The results showed that nano-zerovalent iron was successfully loaded on the bacterial cellulose membrane. The particle size of nZVI particles loaded in BC-nZVI was about 200 nm under the condition of low ferrous sulfate, effectively alleviating the agglomeration phenomenon. And the inactivation efficiency of BC-nZVI on MS2 has been improved, reaching 4 log in 5 min. BC-nZVI showed two stages of inactivation characteristics, the first stage was 5 min to achieve 4 log high-efficiency inactivation stage, the second stage was the follow-up slow inactivation stage. At different pH value, the removal rate of MS2 by BC-nZVI increased with the increase of pH value, which was different from that of nZVI. The radical scavenger experiments showed that the main factor affecting the removal rate of MS2 in the first stage was •O 2 − , followed by Fe (IV), while the effect of •OH was not significant. In the second stage, the main influencing factors was •OH. Under alkaline condition, the yield of •O 2 − was increased, the reaction time was prolonged, and the deactivation rate of MS2 was increased. These results provide new ideas for the practical application of nZVI in the treatment of pathogenic microorganisms .
Jinxin Lan,Yao Wu,Changmei Lin,Jiazhen Chen,Ruiqi Zhu,Xiaojuan Ma,Shilin Cao
The worldwide spread of COVID-19 has put a higher requirement for personal medical protective clothing, developing protective clothing with sustained antibacterial and antiviral performance is the priority for safe and sustaining application. For this purpose, we develop a novel cellulose based material with sustained antibacterial and antiviral properties. In the proposed method, the chitosan oligosaccharide (COS) was subjected to a guanylation reaction with dicyandiamide in the presence of Scandium (III) triflate; because of the relatively lower molecular weight and water solubility of the COS, GCOS (guanylated chitosan oligosaccharide) with high substitution degree (DS) could be successfully synthetized without acid application. In this instance, the minimum inhibitory concentration (MIC) and minimum bactericidal concentration (MBC) of the GCOS were only 1/8 and 1/4 of that of COS. The introduction of GCOS onto the fiber endowed the fiber with extremely high antibacterial and antiviral performance, showing 100% bacteriostatic rate against Staphylococcus aureus and Escherichia coli and 99.48% virus load reduction of bacteriophage MS2. More importantly, the GCOS modified cellulosic fibers (GCOS-CFs) exhibit excellent sustained antibacterial and antiviral properties; namely, 30 washing cycles had negligible effect on the bacteriostatic rate (100%) and inhibition rate of bacteriophage MS2 (99.0%). Moreover, the paper prepared from the GCOS-CFs still exhibited prominent antibacterial and antiviral activity; inferring that the sheeting forming, press, and drying process have almost no effect on the antibacterial and antiviral performances. The insensitive of antibacterial and antiviral activity to water washing (spunlace) and heat (drying) make the GCOS-CFs a potential material applicable in the spunlaced non-woven fabric production.
危险品化学品经营许可证（带存储）