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四维PARAFAC
MICROCHEMICAL JOURNAL · 2018 · IF 2.746

Discussion on the superiority of third-order advantage: Analytical application for four-way data in complex system

Xiao-Hua Zhang,Xiang-Dong Qing,Hai-Long Wu

In this paper, the ‘third-order advantage’ was explored through comparing the performance of PARAFAC and four-way PARAFAC using simulated and experimental data sets. The results demonstrated that the third-order calibration method could extract more inherent information from the data, and easily solve the problems of serious collinearity, high-intensity noise and strong background interference. As an example, a real experimental data set has been processed for the quantitative analysis of three phenolic acids in cosmetic samples. However, PARAFAC is disappointing due to serious collinearity and high-intensity noise of the experimental data in this report. In contrast, the satisfactory results (average recovery, 99.96–101.49%, average relative error, 6.26–13.48%) are provided by four-way PARAFAC.

CAS / MDL: 331-39-5
研究领域: 分析化学 · 复杂系统建模
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