Oxygen vacancies-enriched porous CeO2-Co3O4 hybrid nanosheets for high-efficiency toluene catalytic oxidation
Catalytic oxidation is an efficient method for mitigating toluene emissions, but enhancing catalytic performance for toluene oxidation remains a challenge. To enhance the oxidation capacity of catalysts, appropriate morphology and composition adjustments are required. Herein, the porous CeO 2 -Co 3 O 4 hybrid nanosheets (CeO 2 -Co 3 O 4 HNSs) have been designed and prepared by the hydrothermal method . Compared with single composition CeO 2 and Co 3 O 4 , the CeO 2 -Co 3 O 4 HNSs exhibit superior performance, achieving a remarkable 90% toluene conversion at a reaction temperature of 215°C with a space velocity of 36,000 mL/(h·g). Their enhanced activity can be attributed to the unique morphology and multi-component synergistic effect. The introduction of Co can significantly increase the content of oxygen vacancy and optimize the electronic structure, which can enhance the formation of surface-active oxygen and accelerate the cycle of the Ce 3+ /Ce 4+ redox pair. This work establishes a promising avenue for treating volatile organic compounds in exhaust emissions.
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