JOURNAL OF ELECTROANALYTICAL CHEMISTRY
·
2013
·
IF 2.672
Yangyang Gao,Huan Wang,Liping Guo
In this work, a glassy carbon electrode (GCE) modified with large mesoporous carbon and Nafion composites (LMC/Nafion) was constructed and used for simultaneous determination of theophylline (TP) and caffeine (CF). The electrochemical behaviors of TP and CF on the LMC/Nafion/GCE were carefully investigated by cyclic voltammetry (CV) and differential pulse voltammetry (DPV). The results show that the DPV peaks of the two analytes can be distinguished at the modified electrode with peak-to-peak separation about 150 mV, which means that LMC/Nafion/GCE is suitable for simultaneous determination of TP and CF. Under the optimized condition, the detection limits of TP and CF were 0.37 and 0.47 μM ( S / N = 3) with linear ranges of 0.8–180.0 μM and 1.3–230.0 μM, respectively. The proposed method was successfully applied to the simultaneous determination of TP and CF in human blood serum and beverages with reliable recovery.
研究领域:
分析化学
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电化学
✓ 已验证
产品关联
DOI
高影响因子
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
·
2022
·
IF 4.326
Longsheng Pei,Hanlun Yang,Shouhui Chen,Li Wang
The metal–organic framework (MOF) UiO-66-NH2 was synthesized and attached to kenaf stem-derived three-dimensional macroporous carbon (3D-KSC) simultaneously, and then, the isothiocyanate functional group was introduced into UiO-66-NH2 MOFs to prepare UiO-66-NHC(S)NHMe/3D-KSC nanocomposites. The amount of UiO-66-NHC(S)NHMe MOFs on 3D-KSC can be controlled easily by the monomer concentration. There were three adsorption sites (two nitrogen atoms and one sulfur atom) on each structural unit of UiO-66-NHC(S)NHMe for adsorption toward heavy metal ions (HMIs) and well-regulated pores and 3D macropores of 3D-KSC to promote the transfer of HMIs. Therefore, UiO-66-NHC(S)NHMe/3D-KSC nanocomposites can be applied for the removal and electrochemical detection of Cd2+, Pb2+, Cu2+, and Hg2+. The detection limits of Cd2+, Pb2+, Cu2+, and Hg2+ were 0.0125, 0.0124, 0.0111, and 0.0094 μM, respectively. The sensitivities were 879.1, 887.6, 992.5, and 1160.7 μA μM–1 cm–2, respectively. UiO-66-NHC(S)NHMe/3D-KSC showed fine reproducibility and stability as well as strong anti-interference ability. In addition, the HMIs can be removed effectively by UiO-66-NHC(S)NHMe/3D-KSC with the maximum adsorption capacity of 88, 391, 223, and 935 mg·g–1 for Cd2+, Pb2+, Cu2+, and Hg2+, respectively. The results show that UiO-66-NHC(S)NHMe/3D-KSC has great potential for the adsorption and detection of HMIs.
研究领域:
材料科学
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环境科学
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分析化学
✓ 已验证
DOI
高影响因子
RARE METALS
·
2021
·Vol. 41
·期 1
·189-198
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IF 4.003
Tang Jing,Hui Zhen-Zhen,Hu Tao,Cheng Xin,Guo Jia-Hao,Li Zi-Rong,Yu Hao
The composite of zeolitic imidazolate frameworks (ZIF-67) and ordered macroporous carbon (OMC) was successfully synthesized via in situ growth from the OMC matrix. The ZIF67–OMC composite was verified by scanning electron microscopy (SEM) and transmission electron microscopy (TEM), powder X-ray diffraction (XRD) and electrochemical impedance spectroscopy (EIS) and then evaluated as a modified material for electrochemical sensor. Benefitting from the large surface area and enhanced conductivity of the ZIF67–OMC composite, ZIF67–OMC nanocomposite showed superior electrocatalytic performance toward acetaminophen (AP) oxidation. The redox reaction of AP underwent a quasi-reversible redox reaction with higher anodic current at ZIF67–OMC modified electrode compared with the bare glassy carbon electrode (GCE). In optimal condition, the ZIF67–OMC/GCE was stable, reproducible and had a linear range of 0.05–100 μmol·L −1 AP concentration, with the detection limit of 20 nmol·L −1 (signal-to-noise of S / N = 3). In addition, the prepared sensing platform for the detection of AP was evaluated for the compound paracetamol tablets and urine samples. Graphic abstract
研究领域:
材料科学
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分析化学
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医学检测
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
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2020
·Vol. 167
·期 6
·067504
·
IF 3.721
Jing Tang,Renhao Liu,Jie Li,Zhenzhen Hui,Shengbiao Zheng,Jiwei Wu,Jiahao Guo,Xuchun Wang,Jianfei Wang
A Co-containing zeolitic imidazolate framework (ZIF-67) and ordered macroporous carbon (OMC) composite has been made via in situ growing ZIF-67 in the suspension of OMC. Different sizes of ZIF67-OMC-x (400, 700, 1000 nm) hybrid composites were synthesis by adding different amount of polyvinyl pyrrolidone (PVP). The SEM and TEM images demonstrated that the sizes of ZIF-67 matched well with the macropores of the OMC matrix in as-prepared ZIF67-OMC-400 nm composites. The intriguing structure of ZIF67-OMC-400 hybrid composites utilized synergistic interactions between the large surface area and ordered porosity structure of ZIF-67 and the high conductivity of OMC. More importantly, ZIF67-OMC-400 was explored as a novel modifying material for fabricating electrochemical sensor and then was utilized successfully for catechol (CC) and hydroquinone (HQ) simultaneous detection. Under the optimized condition, wide linear responses of this sensor were obtained for HQ and CC detection in the range of 0.1 μM to 100 μM. The modified electrode was successfully demonstrated for real samples such as river water with satisfactory results.
研究领域:
材料科学
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分析化学
✓ 已验证
产品关联
DOI
高影响因子
ANALYTICA CHIMICA ACTA
·
2017
·
IF 4.95
Yashuang Hei,Xiqian Li,Xiao Zhou,Jingju Liu,Mimi Sun,Tianze Sha,Cuixing Xu,Wanyi Xue,Xiangjie Bo,Ming Zhou
In this paper, kelp ( Laminaria japonica ), as a kind of abundant biomass, is used as the precursor for the preparation of kelp-derived hierarchical meso-macroporous carbons (K-dHMMCs) through the carbonization under nitrogen (N 2 ) atmosphere at high temperature. The K-dHMMCs exhibits the unique structure with high specific surface area of 416.02 m 2 g −1 , large pore volume of 0.24 cm 3 g −1 , the hierarchical meso-macroporous size distribution centered at 2, 12 and 82 nm and high density of defective sites, enabling K-dHMMCs attractive for the electrocatalysis . Drop-casting K-dHMMCs on the glassy carbon (GC) surface allows the construction of K-dHMMCs based electrochemical sensing platform, which shows electrocatalytic activities towards many electroactive molecules, such as potassium ferricyanide , nicotinamide adenine dinucleotide (NADH), hydrogen peroxide (H 2 O 2 ), dopamine (DA), uric acid (UA), ascorbic acid (AA), epinephrine (EP), l -tyrosine (Tyr) and acetaminophen (APAP). Especially, the K-dHMMCs modified GC (K-dHMMCs/GC) electrode exhibits higher sensitivity, wider linear range, and lower detection limit than both carbon nanotubes modified GC (CNTs/GC) and GC electrodes for H 2 O 2 detection, which makes the K-dHMMCs/GC electrode to be able to determine the H 2 O 2 levels in human urine sample and monitor the H 2 O 2 released from human cancer cells. These results demonstrate that K-dHMMCs/GC possesses a great potential for conventional electrochemical sensing applications.
研究领域:
材料科学
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电化学
·
生物医学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
SENSORS AND ACTUATORS B-CHEMICAL
·
2020
·
IF 7.1
Jiajia Han,Jingguo Yu,Yufei Guo,Li Wang,Yonghai Song
The indissolubility or poor dissolubility of covalent-organic frameworks (COFs) limits their wide applications. Here, the COF BTLP-1 which were prepared by the aminaldehyde condensation between 1,4-benzenedithiol-2,5-diamino-hydrochloride and 1,3,5-triformylbenzene was controllably grown on kenaf stem-derived macroporous carbon (3D-KSC). Compared with COF BTLP-1 powder, the COF BTLP-1 grown on 3D-KSC avoided their random orientation effectively. The results showed that the amount of COF BTLP-1 could be effectively controlled by adjusting the concentration of monomers and growing time. Each unit of COF BTLP-1 has 12 adsorption sites (6 sulfur atoms and 6 nitrogen atoms) for heavy metal ions (HMIs) and regular holes to facilitate the transfer of HMIs. A large number of adsorption sites of HMIs could identify and captured HMIs selectively, and accordingly Cd 2+ , Pb 2+ , Cu 2+ and Hg 2+ could be detected simultaneously by using the COF BTLP-1 /3D-KSC electrode. The detection limits for Cd 2+ , Pb 2+ , Cu 2+ and Hg 2+ are 12.3 nM, 11.8 nM, 18.6 nM and 21.4 nM, respectively. The sensitivities are up to 1337.4 μA/μM cm 2 , 1389.0 μA/μM cm 2 and 886.2 μA/μM cm 2 , 770.0 μA/μM cm 2 , respectively. The COF BTLP-1 /3D-KSC may be also applied in other fields of electroanalytical chemistry.
研究领域:
材料科学
·
环境科学
·
分析化学
✓ 已验证
产品关联
DOI
高影响因子
CARBON
·
2013
·
IF 5.868
Hetao Chu,Zhichun Zhang,Yanju Liu,Jinsong Leng
A meso/macropore carbon nanotube paper (CNP) and a self-heating fiber reinforced polymer composite of CNP/glassfiber/epoxy (CGE) based on the meso/macropore CNP were fabricated in this article. The pore diameters mainly distribute from 30 to 90 nm characterized using nitrogen adsorption isotherms at 77 K. The electric conductivities of the CNP and CGE composite are 77.8 and 64.9 S cm −1 . Electric heating performance of CGE was investigated at different heat flux densities , wind speed and ambient temperature. A uniform temperature distributed was observed on the surface of CGE detected by an infrared temperature camera. The electric heating performance was verified by deicing a certain amount of ice at different heat flux densities under two kinds of ambient conditions: −22 °C without wind and −22 °C with 14 m/s of the wind speed. The deicing time under the two conditions were less than 220 and 450 s, respectively. The feasibility of the deicing performance was demonstrated through a series of experiments and the results indicate this material is a promising candidate as an electric heating material for deicing.
研究领域:
材料科学
·
能源工程
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF COLLOID AND INTERFACE SCIENCE
·
2021
·
IF 8.128
Na Wu,Linyu Wang,Yi Xie,Yan Du,Yonghai Song,Li Wang
Riboflavin (RF) is one of the necessary vitamins. If human body lacks RF, it will lead to inflammation and dysfunction of mouth, lips and skin. Thus sensitive and accurate determination of RF is necessary. Here, an electroactive covalent-organic framework nanobelt (COF TFPB-Thi ) with thickness of 1.4 nm was prepared by amine-aldehyde condensation reaction between thionine and 1, 3, 5-tris (p-formylphenyl) benzene, which was then grown vertically on three-dimensional porous carbon derived from kenaf stem (3D-KSC) for double signal ratiometric electrochemical detection of RF. The resulted 3D-KSC/COF TFPB-Thi showed two reduction peaks at −0.08 V and −0.23 V, which came from the reduction of COF TFPB-Thi and the conjugated structure of COF TFPB-Thi , respectively . In the presence of RF, those RF molecules near the electrode surface were oxidized at 0.6 V. Then some oxidized RF (RF ox ) adsorbed on COF TFPB-Thi would oxidize COF TFPB-Thi into COF TFPB-Thi (ox) while other RF ox adsorbed on 3D-KSC kept unchanged. When the potential was scanned from 0.6 V to −0.6 V, both COF TFPB-Thi (ox) and RF ox adsorbed on 3D-KSC were reduced at −0.08 V and −0.45 V accordingly, while the reduction peak of −0.23 V of the conjugated structure of COF TFPB-Thi kept constant. When j -0.45 /j -0.23 was used as the response signal, the detection limit was 44 nM and the linear range was 0.13 μM −0.23 mM. By using j -0.08 /j -0.23 as the response signal, a detection limit of 90 nM and a linear range of 0.30 μM-0.23 mM (S/N = 3) were obtained. By using double signals, the measurement results can be corrected to make the results more accurate and reliable. The sensor also showed good selectivity, reproducibility and stability, which provided a good application prospects.
研究领域:
分析化学
·
材料科学
·
电化学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
Analytical Methods
·
2013
·Vol. 5
·期 20
·5785-5791
·
IF 1.855
Yangyang Gao,Liping Guo
A novel theophylline (TP) sensor was developed using a single walled carbon nanotube–large mesoporous carbon/Nafion composite modified glassy carbon electrode (SWCNT–LMC/Nafion/GCE). The morphology of the SWCNT–LMC microstructure was characterized by transmission electron microscopy (TEM) and the surface of the modified electrode was characterized by cyclic voltammetry (CV). The results showed enhanced electrochemical reactivity and voltammetric response of TP. Under the selected conditions the peak current was linear with TP concentration from 0.3 to 38.0 μM with a detection limit of 0.08 μM (S/N = 3), as determined by differential pulse voltammetry (DPV). The SWCNT–LMC/Nafion/GCE was successfully applied for the determination of TP in human blood serum and urine samples with good recoveries.
研究领域:
分析化学
·
生物医学工程
✓ 已验证
DOI
高影响因子
Nature Communications
·
2024
·Vol. 15
·期 1
·1-9
·
IF 14.7
Zhang Yihan,Huang Zongming,Peng Chenchen,Gao Ning,Xu Xie George,Li Yaping,Zheng Cheng,Chen Wenjing,Yang Yidong,Zhao Jingjing,Yang Junjie,Chen Tao,Xiao Zhengguo
The thickness of X-ray detectors needs to reach hundreds of micrometers to absorb X-ray, and therefore, high voltages over tens or hundreds of volts should be applied to extract X-ray-generated carriers. Here, we propose a bulk Schottky junction for X-ray detection using interpenetrated macroporous-carbon electrodes and metal-halide perovskite networks. The X-ray-generated holes are extracted by the macroporous-carbon electrodes under the built-in electric field, while the electrons in the perovskite phase result in a high gain effect. A high sensitivity of 1.42×10 5 μC Gy air −1 cm −2 and a low detection limit of 48 nGy air s −1 at a low voltage of −1 V are achieved. We fabricated a dry battery-powered portable X-ray alarm prototype. The pixel detector shows a decent stability under X-ray exposure, and a spatial resolution of up to 5.0 lp mm −1 , and the detector arrays also exhibit remarkable uniformity, demonstrating its potential application in X-ray imaging.
研究领域:
材料科学
·
辐射探测技术
✓ 已验证
产品关联
DOI
PubMed
高影响因子
CATALYSIS TODAY
·
2017
·
IF 4.636
Lan-Lan Lou,Ting Yang,Wenjun Yu,Huaxin Qu,Yajun Feng,Hao Li,Kai Yu,Shuangxi Liu
Pt nanoparticles supported on three-dimensionally ordered macroporous carbon (Pt/3DC) were prepared and applied as catalyst after chirally modified with cinchonidine for the enantioselective hydrogenation of ethyl pyruvate. The catalyst was characterized by SEM, TEM, powder XRD, N 2 sorption , and CO chemisorption , which confirmed the well-defined periodic macroporous structure of Pt/3DC and the high dispersion of Pt nanoparticles on the support. High catalytic performance was achieved over chirally modified Pt/3DC catalyst in the asymmetric hydrogenation of ethyl pyruvate. A high turnover frequency of 11,800 h −1 with an enantiomeric excess of 79.5% was acquired in acetic acid. In particular, this catalyst exhibited high durability in the asymmetric hydrogenation system and could be easily reused at least 13 times with well-maintained catalytic activity and slightly decreased enantioselectivity. Moreover, the comparison of catalytic performance between Pt/3DC and commercial Pt/C as well as Pt/Al 2 O 3 was carried out.
研究领域:
催化化学
·
材料科学
✓ 已验证
产品关联
DOI
高影响因子
Sustainable Materials and Technologies
·
2022
·
IF 10.681
Mingming Xie,Danqing Li,Xin He,Hu Fu,Xiaobo Zhu,Hongyuan Fu,Mei Ding,Chuankun Jia
Rechargeable alkali-ion (Li + , Na + , and K + ) batteries with high conversion efficiency have attracted much attention for portable and sizeable energy storage. Deriving valuable battery materials from valueless waste materials is highly desirable to meet the surging demand of energy storage. However, waste-derived carbon materials often show low specific capacity and poor reversibility due to untamed physiochemical properties. In this paper, nitrogen doped meso-macroporous carbon (NMPC) materials are produced from waste asphalt with the assistance of nano-Fe 2 O 3 template and melamine modification. The products show interconnected three-dimensional meso-macroporous structures and tunable nitrogen contents. As an anode material for Li-ion batteries, the NMPC with optimum nitrogen content delivers a reversible capacity of 602.3 mA h g −1 at 0.2 A g −1 . Furthermore, it also discharges a reversible capacity of 210.8 mA h g −1 after 200 cycles and 201.5 mA h g −1 after 500 cycles for Na-ion batteries and K-ion batteries, respectively. The excellent and versatile electrochemical properties enable the concept of waste recovery and resource utilization, which can be used for the manufacture of environmentally friendly energy storage systems .
研究领域:
材料科学
·
能源存储技术
✓ 已验证
产品关联
DOI
高影响因子
危险品化学品经营许可证（带存储）