JOURNAL OF ALLOYS AND COMPOUNDS
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2025
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IF 6.3
Menghang Qi,Liangsheng Tian,Yutong Wang,Xin Xin,Hang Zhao,Theeranun Siritanon,M.A. Subramanian,Peng Jiang
To alleviate the urban heat island effect, reduce building energy consumption and improve the living environment for residents, the development of highly reflective pigments and coatings is of great significance for sustainable development. In this study, Mg 2.4- x Cr x TiO 4.4+δ (0.1 ≤ x ≤ 0.3) and Mg 2.4- x Co x TiO 4.4 (0.1 ≤ x ≤ 0.4) pigments with intense green/sky blue colors were successfully synthesized through solid state method. The crystal structure, color development mechanism and optical properties of as-synthesized samples are analyzed. The as-prepared pigments demonstrate excellent NIR reflectance with the highest solar reflectance up to 83%. Furthermore, the color coatings with high NIR solar reflectance were successfully prepared by mixing the pigments with acrylic resin. A solar reflectance of 69.81% is achieved among the green/blue coatings. The thermal shielding effect of the coatings in practical applications was tested through chamber simulation experiments. The test temperature of the prepared coating was 8.8 ℃ lower than that of the blank stainless steel plate after radiating with a 250 W infrared lamp for 30 minutes, which proved its good heat insulation performance. Through pickling and alkali washing experiments, the color coordinates of the coatings are very stable, indicating the excellent acid-base resistance in the practical applications.
研究领域:
材料科学
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无机化学
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光学性能
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建筑节能
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可持续发展
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产品关联
DOI
高影响因子
JOURNAL OF SOLID STATE ELECTROCHEMISTRY
·
2018
·Vol. 23
·期 1
·19-25
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IF 2.509
Chen Xiaoming,Yang Mingdi,Xu Wenzong,Qu Qishu,Zhao Qingchun,Zou Wensheng
A novel conjugated polymer PProDOT(MeEO) 2 based on dioxythiophene with symmetric double ethoxymethyl pendant groups was successfully synthesized through electrochemical polymerization. The polymer film exhibits reversible electrochromism switching between broadly absorbing bluish black neutral state (− 0.1 V) and transmissive sky blue oxidized state (0.7 V). The symmetric double short-chain ethoxymethyl substitution pattern was utilized to realize the broadly absorbing bluish black neutral state of the polymer film. The electrochemical, spectroelectrochemical, and electrochromic switching properties of the polymer film were studied in detail.
研究领域:
材料科学
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电化学
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聚合物科学
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产品关联
DOI
高影响因子
Journal of Materials Chemistry C
·
2019
·Vol. 8
·期 4
·1319-1325
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IF 6.641
Siyuan Zeng,Shasha Shi,Shirong Wang,Yin Xiao
Achieving efficient blue emission with spectrum stability in perovskite light-emitting diodes (PeLEDs) is a great challenge, although the external quantum efficiency (EQE) of PeLEDs for red and green emission has exceeded 20%. Here, we report efficient sky-blue PeLEDs with high brightness based on mixed-ligand confined quasi-2D perovskites. By detailed characterization of the optical and physicochemical properties of n-butylammonium (BA) or 2-phenylethylammonium (PEA)-based perovskites with various alkyl ammonium bromides as co-ligands, it is found that the molecular size and charge on the amino-groups of the co-ligand hold the key to constructing effective mixed-ligand systems. Accordingly, dimethylammonium (DMA) is an ideal co-ligand in both BA- and PEA-based quasi-2D perovskites. Thanks to its appropriate molecular size, DMA could help to confine the diameter of perovskite nanocrystals (NCs) and improve their dispersity in organic ligands. Besides, DMA is prone to disperse among PEA or BA molecules to cap the perovskite synergistically, and the phase of n = 1 caused by excess co-ligands could be effectively avoided benefiting from the relatively weak coordination ability of DMA due to the relatively small positive charge on amino-groups. The optimized PeLEDs based on BA2DMA1.6Cs2Pb3Br11.6 and PEA2DMA1.2Cs2Pb3Br11.2 exhibit color-stable sky-blue (490 nm) and bluish green (499 nm) emission with a record maximum luminance of 2825 and 7760 cd m−2 respectively. The applicability of this approach in the red emission region is also demonstrated, which provides a versatile strategy for full spectrum modulation.
研究领域:
材料科学
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光电子学
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纳米技术
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光子学
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产品关联
DOI
高影响因子
Advanced Science
·
2021
·Vol. 8
·期 19
·2102213
·
IF 16.806
Yang Shen,Jing-Kun Wang,Yan-Qing Li,Kong-Chao Shen,Zhen-Huang Su,Li Chen,Ming-Lei Guo,Xiao-Yi Cai,Feng-Ming Xie,Xiao-Yan Qian,Xingyu Gao,Ivan S. Zhidkov,Jian-Xin Tang
While tremendous progress has recently been made in perovskite light-emitting diodes (PeLEDs), large-area blue devices feature inferior performance due to uneven morphologies and vast defects in the solution-processed perovskite films. To alleviate these issues, a facile and reliable interface engineering scheme is reported for manipulating the crystallization of perovskite films enabled by a multifunctional molecule 2-amino-1,3-propanediol (APDO)-triggered “anchoring effect” at the grain-growth interface. Sky-blue perovskite films with large-area uniformity and low trap states are obtained, showing the distinctly improved radiative recombination and hole-transport capability. Based on the APDO-induced interface engineering, synergistical boost in device performance is achieved for large-area sky-blue PeLED (measuring at 100 mm 2 ) with a peak external quantum efficiency (EQE) of 9.2% and a highly prolonged operational lifetime. A decent EQE up to 6.1% is demonstrated for the largest sky-blue device emitting at 400 mm 2 .
研究领域:
材料科学
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光电学
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半导体物理
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DOI
PubMed
高影响因子
PROGRESS IN ORGANIC COATINGS
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2020
·
IF 4.469
Longyang Li,Jingfang Zhu,Zhixiang Zeng
Efforts made to efficiently fabricate traditional superhydrophobic coating have always faced limitations such as high cost, recontamination, and sophistication. An artificial superhydrophobic copper stearate (CS) polydimethylsiloxane (PDMS) coating was fabricated to achieve the transition of a water-adhesion surface to a water-repellent surface. This coating formed superhydrophobic surfaces in different types of substrates through dipping, spraying, and brushing, and demonstrated excellent water repellency, low contact angle hysteresis, and weak adhesive forces after exposure to tape-peeling cycles (VHB, 3 M), abrasion cycles, acid/alkali solutions, corrosive solutions, freezing water, and boiling water. Additionally, experiments were conducted on potential applications of the superhydrophobic coating in oil/water separation, self-cleaning, and anti-corrosion.
研究领域:
材料科学
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表面化学
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涂层与薄膜
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环境工程
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DOI
高影响因子
ADVANCED FUNCTIONAL MATERIALS
·
2022
·Vol. 32
·期 41
·2206574
·
IF 19.924
Yang Shen,Yan-Qing Li,Kai Zhang,Liu-Jiang Zhang,Feng-Ming Xie,Li Chen,Xiao-Yi Cai,Yu Lu,Hao Ren,Xingyu Gao,Haijiao Xie,Hongying Mao,Satoshi Kera,Jian-Xin Tang
Perovskite light-emitting didoes (PeLEDs) have shown considerable potential in solution-processable display applications. However, the performance of blue PeLEDs in terms of efficiency and stability hinders their practicality on account of severe trap-mediated nonradiative recombination losses and halide phase segregation. To ameliorate these issues, mixed-halide sky-blue perovskite materials are strategically modulated through crystal defect passivation with a trifurcate isocyanate oligomer, which leads to the synergistical suppression of charge trap density and halide ion migration. The proposed approach enables the performance improvement for sky-blue PeLEDs, exhibiting a peak external quantum efficiency of 14.82% and spectrally stable emission at 487 nm. In addition, prolonged operational lifetime and enhanced capability of moisture resistance are achieved simultaneously, approaching a half-lifetime of ≈2900 s at an initial brightness of 178 cd m –2 .
研究领域:
材料科学
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光电技术
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显示技术
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产品关联
DOI
高影响因子
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