COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
·
2022
·
IF 5.518
Danzhang Liu,Xiaoqing Weng,Yanfeng Jin,Richard M. Kasomo,Shunfu Ao,Hongqiang Li
Feldspar is a typical sesquioxide which is associated with phosphate ore. It can greatly prevent the formation of calcium sulfate crystals during the wet process of phosphoric acid production, resulting in the loss of P 2 O 5 , and therefore lowering the phosphoric acid recovery. To achieve the selective separation of feldspar from phosphate ore, we first tried using a new Gemini quaternary ammonium salt as the collector in conjunction with a reverse flotation approach. The flotation tests of single minerals and artificially mixed minerals were employed to investigate the collecting ability and selectivity of the collector, the adsorption mechanism was also evaluated by means of zeta potential measurements and molecular dynamic calculations. The flotation results demonstrate that the collector showed a strong harvesting effect and selectivity on feldspar rather than fluorapatite . When the Gemini concentration was set at 7.5 × 10 −6 mol/L, the P 2 O 5 grade could reach 31.69% with a corresponding recovery of 77.57%, indicating that Gemini collector could suitably be used as a potential chemical to achieve the effective removal of feldspar from phosphate ore. The results obtained from zeta potential measurements and molecular dynamics simulations indicate that the adsorption of Gemini collector on feldspar was more pronounced compared to that on fluorapatite surface and the interaction between Gemini and both minerals was mainly ascribed to electrostatic interaction . This work aims to provide a reference for using Gemini as collector combined with reverse flotation approach to achieve the effective removal of sesquioxide from phosphate ore and further enhance the quality of phosphate fertilizers .
研究领域:
矿物加工工程
·
化学工程
✓ 已验证
DOI
高影响因子
CHINESE JOURNAL OF CHEMICAL ENGINEERING
·
2012
·
IF 0.826
Jianxian ZENG,Xiahui SUN,Lifeng ZHENG,Qincheng HE,Shu LI
Polyquaternium-6 (PQ6) as the water-soluble polymer was used for complexing the anion forms of tungsten (VI) before ultrafiltration. Tungsten (VI)-PQ6 complex was retained by polysulfone hollow fiber ultrafiltration membrane in the complexation-ultrafiltration process. Effects of various operating parameters such as polymer metal ratio(PMR), pH and chloride ion concentration on permeate flux ( J ) and tungsten rejection coefficient ( R ) were investigated. The integration of four experiments including concentration, decomplexation, diafiltration and reuse of regenerated polymer was carried out. In the process of concentration, J declines slowly and R is about 1 at PMR of 3 and pH of 7. Tungsten concentration in the retentate increases linearly with volume concentration factor. Tungsten is concentrated efficiently with the membrane. The concentrated retentate was used further for the decomplexation. It takes about 6 min to reach the decomplexation equilibrium at chloride ion concentration of 50 mgL −1 . The decomplexation percentage of tungsten (VI)-PQ6 complex reaches 56.1%. In the diafiltration process, tungsten (VI) can be extracted effectively by using 50 mgL −1 chloride ion solution, and the purification of the regenerated PQ6 is acceptably satisfactory. The regenerated PQ6 was used to bind tungsten (VI) at various pH values. The binding capacity of the regenerated PQ6 is close to that of fresh PQ6, and the recovery percentage of binding capacity is higher than 90%.
研究领域:
化学工程
·
环境科学
✓ 已验证
产品关联
DOI
高影响因子
Journal of Materials Chemistry B
·
2022
·Vol. 10
·期 45
·9413-9423
·
IF 7.571
Yuxia Zhang,Xiaoyu Lu,Chongyi Chi,Yanyan Zheng,Qinhui Chen
It is of utmost importance that bleeding should be stopped and infection be prevented in people with trauma. In this study, an anisotropic Janus mesoporous silica nanosheet (MSNS) with different functional groups was designed and prepared. In order to endow both sides of the MSNS with independent fast hemostasis and effective antibacterial action, the MSNS was modified with cardanol (CA) and 2,3-epoxypropyltrimethylammonium (GTA). The addition of CA significantly improved the hemostatic property of the MSNS. In a SD rat femoral artery injury model, the hemostatic time of CA-MSNS-GTA was 47% shorter than that of the MSNS, attributed to the sealing of the hydrophobic alkyl side chain and the adhesion of phenolic hydroxyl groups in CA. CA-MSNS-GTA could form a three-dimensional network with fibrin to further accelerate the coagulation process. This Janus material exhibited excellent antibacterial effects (∼90%) against Gram-positive bacteria (S. pneumoniae) and Gram-negative bacteria (E. coli) due to the presence of GTA. The cytotoxicity test showed that CA-MSNS-GTA exhibited biosafety, which provided safety guarantee for clinical applications in the future. This Janus dressing with different functions on two opposite sides provides synergetic multifunctional effects during wound healing.
研究领域:
材料科学
·
生物医学工程
·
创伤护理
✓ 已验证
产品关联
DOI
PubMed
高影响因子
JOURNAL OF MOLECULAR LIQUIDS
·
2022
·
IF 6.633
Xudong Zhang,Wenbo Zhao,Jun Shen,Yugao Wang,Gang Liu,Yanxia Niu,Qingtao Sheng
Carbazole is an important organic chemical raw material with high added value, mainly derived from crude anthracene. In this research, three quaternary ammonium salts (QASs), containing triethylmethylammonium chloride (TEMAC), tetraethylammonium chloride (TEAC) and tetrapropylammonium chloride (TPAC), were innovatively used to separate carbazole from model anthracene oil by forming deep eutectic solvents (DESs). The results indicated that TEAC showed the highest separation ability among three QASs. Afterwards, the influences of mass ratio of TEAC to model anthracene oil (MO), stirring time, extraction temperature and initial concentration on the separation effect of carbazole were investigated. Under the optimized conditions (25℃, 25 min, mass ratio 1:5), the extraction efficiency (EE), distribution coefficient (DI) and selectivity (SE) of carbazole could reach up to 91.25 %, 24.26 and 66.09 %, respectively. The purity and yield of carbazole product separated from model anthracene oil were 91.02 % and 76.89 %, respectively. Moreover, carbazole with purity of 90.42 % could be separated from real crude anthracene with TEAC under the above optimized conditions. In addition, environment friendly water was used to regenerate the TEAC. After recycled for five times, the extraction ability of TEAC for carbazole did not change obviously. Finally, the hydrogen bond (N H…Cl) and van der Waals interaction (C H…π) existed between QASs and carbazole were revealed by FT-IR analysis and quantum calculations. The green and novel method presented in this work has implications for the separation of other high value-added products from coal tar.
研究领域:
化学工程
·
环境科学
✓ 已验证
DOI
高影响因子
JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY
·
2014
·
IF 0.705
Yiwei Li,Raymond Seekell,Sihui Zhan,Jie Cao,Jing Jing,Yi Li
In this article, positively charged GVs were electroformed in a binary system of quaternary ammonium salts and egg phosphatidylcholine (EggPC) under an alternative current (AC) electric field. The diameter and charge density of the GVs is controlled by doping suitable cationic quaternary ammonium molecules into the EggPC bilayer. By developing positively charged GVs, there will be expanded the applications for phospholipids vesicles, especially the investigation of charge-induced interactions between cationic lipid membranes and macromolecules, such as colloidal particles or proteins.
研究领域:
生物化学
·
材料科学
✓ 已验证
产品关联
DOI
高影响因子
MOLECULES
·
2023
·Vol. 28
·期 20
·7151
·
IF 4.6
Jiangxun Dou,Jiaoyan Liu,Yan Wang,Lifei Zhi,Jixian Shen,Guoyong Wang
This paper reports the synthesis of a novel quaternary surfactant containing a hydroxyethyl group (PFPE-C) and the surface properties of its aqueous solution (investigated by comparisons with two structurally similar chemicals, dodecyl-(2-hydroxyethyl)-dimethylammonium chloride (DHDAC) and PFPE-A). The minimum surface tension (γCMC) and critical micelle concentration (CMC) of the PFPE-C aqueous solution were 17.35 mN/m and 0.024 mmol/L, respectively. This study confirms that surfactants containing hydroxyethyl groups efficiently reduce the surface tension of aqueous solutions, and fluorocarbon surfactants exhibit better surface activity than ordinary hydrocarbon surfactants with similar structures. The micellization, aggregation, air-water interfacial adsorption, and wettability of PFPE-C aqueous solutions have been systematically investigated. Highly concentrated PFPE-C aqueous solutions exhibit good wettability on PTFE and paraffin films. Moreover, the aggregates of PFPE-C in the aqueous solution were clearly seen as vesicles on Cryo-TEM micrographs. Primary biodegradation results indicate that 19% of PFPC-C can be degraded within one week.Keywords:fluorocarbon surfactant;quaternary ammonium salt;solution property
研究领域:
化学
·
材料科学
✓ 已验证
DOI
PubMed
高影响因子
Microorganisms
·
2021
·Vol. 9
·期 11
·2258
·
IF 4.128
Xinya Zhang,Yiruo Xia,Yunlu Jia,Assaf Sukenik,Aaron Kaplan,Chanyuan Song,Guofei Dai,Fang Bai,Lin Li,Lirong Song
Mitigation of harmful cyanobacterial blooms that constitute a serious threat to water quality, particularly in eutrophic water, such as in aquaculture, is essential. Thus, in this study, we tested the efficacy of selected cyanocides towards bloom control in laboratory and outdoor mesocosm experiments. Specifically, we focused on the applicability of a group of cationic disinfectants, alkyltrimethyl ammonium (ATMA) compounds and H2O2. The biocidal effect of four ATMA cations with different alkyl chain lengths was evaluated ex situ usingMicrocystiscolonies collected from a fish pond. The most effective compound, octadecyl trimethyl ammonium (ODTMA), was further evaluated for its selectivity towards 24 cyanobacteria and eukaryotic algae species, including Cyanobacteria, Chlorophyta, Bacillariophyta, Euglenozoa and Cryptophyta. The results indicated selective inhibition of cyanobacteria by ODTMA-Br (C18) on both Chroccocales and Nostocales, but a minor effect on Chlorophytes and Bacillariophytes. The efficacy of ODTMA-Br (C18) (6.4 μM) in mitigating theMicrocystispopulation was compared with that of a single low dose of H2O2treatments (117.6 μM). ODTMA-Br (C18) suppressed the regrowth ofMicrocystisfor a longer duration than did H2O2. The results suggested that ODTMA-Br (C18) may be used as an effective cyanocide and that it is worth further evaluating this group of cationic compounds as a treatment to mitigate cyanobacterial blooms in aquaculture.
研究领域:
环境科学
·
水生生物学
✓ 已验证
DOI
高影响因子
GREEN CHEMISTRY
·
2020
·Vol. 22
·期 24
·8728-8733
·
IF 9.48
Qun Liu,Dan Pan,Tingting Ding,Mengchao Ye,Fengjiao He
The spent pickling solution, which comes from the pickling process of iron and steel, is indispensable in the manufacturing industry. Iron gets dissolved in the acid solution during the pickling process. When the concentration of metal ions in the acid solution accumulates to a certain value, it cannot to be used to wash iron and steel materials and becomes spent pickling solution that should be treated before discharge. At present, spent pickling solutions are treated via neutralization precipitation techniques in industries. This treatment method has a large discharge of wastewater, and the cost is high due to which it cannot meet the needs of green cycle in industry production. In this study, a new method, which is based on the formation of quaternary ammonium salt precipitate in a strong acid solution, is proposed to treat the spent pickling solution. The spent pickling solution was recycled and reused by precipitation separation of iron ion. The quaternary ammonium salt was recycled by dissolving the obtained precipitate in an alkali solution. The new ferric hydroxide precipitate formed and quaternary ammonium salt was returned to the solution. In the whole process, only a few amount of alkali was consumed. The removal rate of iron ion was up to 99.72%. Compared with the traditional neutralization precipitation method, the acid is not consumed and it can be reused; the alkali was consumed only for the precipitation of iron ions, not for the neutralization of the acid. The proposed method is an effective and economic method for the recovery of the spent pickling solution. It is expected to satisfy the requirements of green cycle and environmental protection in industry production.
研究领域:
环境科学
·
材料科学
✓ 已验证
DOI
高影响因子
Journal of Oleo Science
·
2025
·
IF 1.8
Guangqun Cao,Guofang Gao,Penghui Liang,Junxia Wang,Yilei Ruan,Zhiyong Hu,Hailin Zhu
Surface activity parameters such as critical micelle concentration (CMC), saturation adsorption (Гmax), and limiting molecular area (Amin) of three triazinyl bisquaternary ammonium salts with different hydrophobic chain lengths (C6-2-C6, C8-2-C8 and C12-2-C12) were analyzed from surface tension tests. The results showed that the CMC value of C12-2-C12 was much lower (0.026 mmol/L) than that of C6-2-C6 and C8-2-C8. The corrosion inhibition performances of three triazinyl bisquaternary ammonium salts on Q235 in 1 mol/L HCl solution were investigated by weight loss measurements and electrochemistry measurements. The results showed that the longer the hydrophobic chain length, the better the corrosion inhibition performance at the same concentration. The corrosion inhibition efficiencies of C12-2-C12, C8-2-C8 and C6-2-C6 at 0.2 mmol/L were 98.10%, 96.09% and 94.64%, respectively. Surface analysis and quantum chemical calculations showed that the three triazinyl bisquaternary ammonium salts can be adsorbed on the surface of carbon steel effectively to inhibit the corrosion of the carbon steel surface.
研究领域:
材料科学
·
表面化学
·
腐蚀与防护
✓ 已验证
产品关联
DOI
PubMed
高影响因子
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
·
2018
·
IF 2.829
Jiahao Ren,Lan Zheng,Yuqi Wang,Xiyu Zang,Jinqiao Wu,Yijun Yue,Xiaolong Han,Le Wu
To improve the diesel conductivity and avoid the electrostatic spark explosion/fire accidents, a series of room temperature ionic liquids (ILs) were synthetized by four kinds of long-chain alkyl quaternary ammonium salt (DTAC, TTAC, HTAC and STAC) and n-butyl naphthenate sulfonic acid using ultrasound method, which were added into the diesel as antistatic agents . Nuclear magnetic resonance spectrum (NMR), Fourier transform infrared spectrometer (FT-IR), thermogravimetric analysis (TGA) and element analysis (EA) were employed to characterize the structures and properties of the ILs, confirming the successful synthesis of the ILs. Experimental results indicated that the prepared ILs can significantly improve the diesel antistatic ability even at ppm level, while the ILs showed an acceptable effect on the diesel combustion performance. The mechanisms of action were also clarified and discussed based on the reverse micelles (RM) microstructures and physicochemical properties of the synthesized ILs. It should be noted that the new diesel antistatic agents have a few features such as high efficiency, lasting effects, mild reaction conditions and low cost, which is bound to have broad application prospect for diesel antistatic accordingly.
研究领域:
化学工程
·
能源科学
✓ 已验证
产品关联
DOI
高影响因子
Materials Science & Engineering C-Materials for Biological Applications
·
2015
·
IF 3.088
Rui Wang,Tao Xiang,Wei-Feng Zhao,Chang-Sheng Zhao
The complex synthesis through multistep reactions and tedious purifications based on different monomers or macromolecules limits the practical applications of functional polymers. Herein, a facile approach toward a series of functional polyurethanes (PUs) is designed for versatile biological applications within fewer step reactions under mild conditions. The tertiary amino groups in the PU are converted into zwitterions or quaternary ammonium salt via simple one-step synthesis, and then used to prepare PU/polyethersulfone composite membranes. The composite membrane with tertiary amine groups exhibits significant adsorption capability to anionic dye Congo red (CR) and toxin bilirubin. The membrane bearing zwitterionic PU displays excellent blood compatibility; while which with quaternary ammonium salts has antibacterial property. Furthermore, carboxybetaine-functional composite membrane is exploited to bear Ag nanoparticles to endow with dual functions of antibacterial and antifouling properties. This work demonstrates the potential of PUs as readily available, multi-functional, and easy-to-use materials for biological applications.
研究领域:
生物材料
·
化学工程
·
医学工程
✓ 已验证
产品关联
DOI
PubMed
高影响因子
JOURNAL OF COLLOID AND INTERFACE SCIENCE
·
2017
·
IF 4.233
Ning Pan,Long Li,Jie Ding,Ruibing Wang,Yongdong Jin,Chuanqin Xia
A novel approach for facile covalent functionalization of graphene oxide (GO) was proposed in the present study in order to effectively avoid necessary anhydrous conditions and the usage of harsh reagents during the chemical functionalization of GO. Herein, a GO derivative that was functionalized with a primary amine derivative bearing a positively charged quaternary ammonium group, GO-S, was synthesized through a Schiff base condensation reaction between the amine groups of the primary amine derivative and the aldehyde groups of GO. The introduction of the quaternary ammonium groups can prevent GO from stacking and improve the dispersibility of GO after modification. The formation of imine bonds ( N CH ) between the primary amine and GO has been confirmed by Fourier transform infrared and X-ray photoelectron spectroscopy. The GO-S demonstrated good dispersion stability in aqueous medium and also exhibited better adsorption performance than GO for Th(IV) and U(VI), with a maximum thorium adsorption capacity of 2.22 mmol/g and a maximum uranium adsorption capacity of 0.83 mmol/g, suggesting a great potential for the application of graphene oxide-based materials for facilitating the removal of Th(IV) and U(VI) from nuclear waste solutions.
研究领域:
环境科学
·
材料科学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
危险品化学品经营许可证（带存储）