Simultaneously enhancing the Td and the thermal stability of the real-time d33 in BNT-based piezoceramics
One of the inherent disadvantages of Bi 0.5 Na 0.5 TiO 3 -based (BNT-based) piezoceramics is that an increment of the depolarization temperature ( T d ) is generally accompanied by a deterioration of the temperature stability of the real-time piezoelectric constant ( d 33 ), which severely restricts the practical applications of the materials. Herein, we propose a new strategy to mitigate the conflict between the elevation of T d and the temperature stability of the real-time d 33 in BNT-based ceramics via integrating the pressure-assisted sintering and quenching process. By this strategy, we not only increased the T d from 109 to 166°C but also improved the temperature stability of the real-time d 33 (the temperature coefficient T tc = ± 13 pC/N) in 0.94Bi 0.5 Na 0.5 TiO 3 –0.06BaTiO 3 ceramic. Both the built-in field and the increment of the field-induced R 3 c phase fraction play the significant role in enhancing the T d and the temperature stability of the real-time d 33 . Thus, our work provides a simple and effective approach for designing piezoceramics with high T d and a superior temperature stability of the real-time d 33 .
危险品化学品经营许可证（带存储）