Polymer Chemistry
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2025
·
IF 3.9
Xu Han,Le Chang,Zeqian Wang,Feng Liu
One-component polysulfide adhesive preparation by diisocyanate-terminated prepolymers and 1,4-butanedithiol (BSO) can provide convenient moisture curing and excellent mechanical properties, but the formation of polysulfide-urea (–NHCOS–) groups causes some reduction in solvent resistance limiting their further application in aircraft fuel tank sealing. Introducing silane side chains into polysulfide adhesive systems is a viable approach to improving the solvent resistance. In this work, a series of novel silane side chain-modified one-component polysulfide adhesives were synthesized by using chain extenders in different proportions of BSO and (3-(2-aminoethyl)aminopropyl)trimethoxysilane (AEAPTMS). The results showed that a moderate amount of silane side chains and restricting the formation of Si–O–Si crosslinked networks can effectively enhance the elongation, interfacial interaction and solvent resistance. The optimal overall performance was obtained when the mass ratio of BSO and AEAPTMS was 7 : 1 (Si-OCPS3). Conversely, the oil and water absorption content after 21 days of Si-OCPS3 were 2.21 ± 0.06% and 2.81 ± 0.31%, being 20.50% and 43.57% lower than before modification (Si-OCPS0), respectively. Moreover, Si-OCPS3 exhibited higher tensile strength of 17.34 ± 0.66 MPa (oil) and 15.67 ± 0.32 MPa (water) than Si-OCPS0. We believe our paradigm can provide a feasible approach for designing high-performance one-component polysulfide adhesives.
研究领域:
材料科学
·
化学工程
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产品关联
DOI
高影响因子
Foods
·
2023
·Vol. 12
·期 13
·2579
·
IF 5.2
Lingshan Li,Mei Fan,Yan Xu,Liang Zhang,Yu Qian,Yongqing Tang,Jinsong Li,Jinsong Zhao,Siqi Yuan,Jun Liu
The solid-state fermentation process of strongly flavored Baijiu is complicated by the co-fermentation of many different microorganisms in the fermentation pools. The traditional fermentation pools of strong flavor Baijiu are sealed with mud, and this sealed-pit mud is not easy to maintain; therefore, the pit cap is prone to cracks and to caving in. The destruction of the sealed-pit mud may lead to instability in the composition and an abundance of microorganisms in the fermentation process that results in fluctuations of product quality. Thus, the production method of replacing the mud cap with a new steel cap is gradually attracting the attention of scientific and technical workers in the industry. However, so far, there have been relatively few reports on the use of steel lids for sealing pits for fermentation and brewing. In this study, the volatile flavor components of 270 Baijiu samples from mud-sealing and steel-sealing pits of a Chinese Baijiu distillery were studied qualitatively and quantitatively using Gas Chromatography–Mass Spectrometry (Abbreviated as GC-MS). Our statistical methods included Hierarchical Cluster Analysis (Abbreviated as HCA), Principal Component Analysis (Abbreviated as PCA), and Discriminant Analysis (Abbreviated as DA). A statistical analysis was carried out on the yield of strongly flavored Baijiu, and we made a comprehensive evaluation of the Baijiu produced under the two pit-sealing modes with regard to flavor and economic efficiency. The yield of strong flavored Baijiu was 6.7% higher with steel-sealing pits compared with mud-sealing pits. Cluster analysis categorized the strongly flavored Baijiu samples into two categories initially: (1) samples produced using mud-sealing pits and (2) samples using steel-sealing pits. Our analysis also indicated that the 28 compounds used for quantification were selected correctly. Surprising to the experimental staff, the overall score for the steel-sealing pits was greater than that of the mud-sealing pits based on PCA. Using DA, the prediction results were 100% accurate. In summary, through a comparative analysis of the flavor and yield, which are the two main factors that affect the quality of Baijiu in a distillery, and systematic combination at both experimental and theoretical levels, the differences between the Baijiu production by steel-sealing and the traditional mud-sealing were clear. Regardless of the impact of age, the detectable flavor components of Baijiu from the mud-steeling pits were very consistent with those of the steel-sealing pits in terms of richness or concentration. However, steel-sealing pits were significantly superior to mud-sealing pits with respect to output, consistency in quality, and cost (human and economic) savings.Keywords:flavor compounds;strong flavor Baijiu;pit cap;mud-sealing pits;steel-sealing pits;Gas Chromatography-Mass Spectrometry
研究领域:
食品科学
·
发酵工程
·
分析化学
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产品关联
DOI
PubMed
高影响因子
ACS Omega
·
2023
·
IF 4.1
Huimei Wu,Yishan Lou,Xiaopeng Zhai,Zhonghui Li,Bin Liu
In this study, we present an innovative intelligent polymer sealant designed to mitigate CO2 leakage during underground geological storage (CCUS). This sealant is formulated by cross-linking CO2-responsive polymers, specifically acrylamide (AM) and N-[3-(dimethylamino) propyl] methacrylamide (DMAPMA), with polyethylenimine (PEI) serving as the cross-linking agent. The polymer sealant’s characteristics were systematically investigated, varying the CO2-responsive polymer content (1.5 wt %) and PEI content (0.1–0.6 wt %). A comprehensive analysis encompassing the rheological properties, thermal behavior, conductivity, and microstructures was conducted. Experimental results indicate that the polymer sealant exhibits excellent injectability, rapid response kinetics, thermal stability, and robust mechanical strength. Upon encountering CO2, the polymer system undergoes a transition from sol to gel state, forming a surface-smooth, uniformly porous three-dimensional (3D) network skeleton structure. Remarkably, the gel’s modulus remains relatively unaffected by the shear frequency. Core fluid displacement experiments demonstrated a substantial sealing efficiency of 73.6% for CO2 and an impressive subsequent injection water sealing rate of 96.2%, underscoring its superior sealing and migration performance. In conclusion, the proposed CO2-responsive gel sealant exhibits an exceptional potential for successful utilization in CCUS operations. This advancement introduces a novel avenue to enhance the effectiveness of CO2-responsive gel sealants, thereby contributing to the advancement of CO2 leakage mitigation strategies in geological storage scenarios.
研究领域:
材料科学
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环境工程
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化学工程
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DOI
PubMed
高影响因子
JOURNAL OF SOLID STATE CHEMISTRY
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2022
·
IF 3.656
Tao Zhang,Qinggang Li
NH 4 VO 3 is an important vanadium source for the preparation of VO 2 . In the previous studies, the extra gas or solid reagents consumption is necessary for the preparation of VO 2 by using NH 4 VO 3 as vanadium source. The current work proposed a facile way for the fabrication of VO 2 (M) by the thermolysis of NH 4 VO 3 under the sealed atmosphere without extra gas or solid reagents consumption. The VO 2 (M) could be successfully synthesized by two step—thermolysis of NH 4 VO 3 at 400 °C under the sealed condition and heat treatment of VO 2 (B) at 500 °C under the N 2 condition. The dosage of NH 4 VO 3 and decomposition temperature had significant influences on the thermolysis process under the sealed condition. The NH 3 produced by the thermolysis provided a protective atmosphere that prevented the oxidization of VO 2 (B) by residual O 2 in the sealed reactor. Furthermore, the VO 2 (M) could be prepared directly under the sealed atmosphere by increasing reaction temperature to 700 °C. In this process, NH 4 VO 3 underwent a phase transition as the follows: NH 4 VO 3 →ammonium vanadium bronze→VO 2 (B)→VO 2 (M). The directly synthesized VO 2 (M) at 700 °C by the thermolysis of NH 4 VO 3 under the sealed condition showed great environmental stability and phase transition performance.
研究领域:
材料科学
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化学工程
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产品关联
DOI
高影响因子
FOOD RESEARCH INTERNATIONAL
·
2023
·
IF 8.1
Rong-Jian Dong,Xie-Huang Sheng,Qian-Tu Xie,Xiaolin Huang,Fujie Yan,Songbai Liu
Yellow tea, a unique type of tea in China which is characterized with yellow color, has gained increasing popularity due to its pleasant taste. However, transformation of aroma compounds during sealed yellowing has been poorly understood. Results of sensory evaluation exhibited that yellowing time was the key factor for flavor and fragrance formation. A total of 52 volatile components during sealed yellowing process of Pingyang yellow soup were further collected and analyzed. The results demonstrated that the sealed yellowing process significantly increased the ratio of alcohol and aldehyde compounds in the aroma volatiles of yellow tea, which were primarily composed of geraniol, linalool, phenylacetaldehyde, linalool oxide and cis -3-hexenol, and their proportion increased with the prolongation of sealed yellowing. Mechanistic speculation revealed that the sealed yellowing process promoted release of alcoholic aroma compounds from their glycoside precursors and enhanced Strecker and oxidative degradation. This study revealed the transformation mechanism of aroma profile during the sealed yellowing process, which would facilitate processing of yellow tea.
研究领域:
食品科学
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植物学
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产品关联
DOI
PubMed
高影响因子
Polymers
·
2024
·Vol. 16
·期 12
·1614
·
IF 4.7
Daqi Li,Shuyang Gao,Zhichuan Tang,Huimei Wu,Yayun Zhang
The development of micro cracks in shale formations can easily lead to wellbore instability caused by liquid phase invasion. In order to effectively seal the shale micropores, the surface treatment of nano-SiO2particles was developed using the silicane coupling agent A-1891. Then, the temperature-sensitive polypenic acrylamide polymer was modified onto the surface of the nanoprocal particle through reaction to obtain the nanosomal blocking agent ASN. The infrared spectrum shows that there are chemical bonds between the generated polymer chains, rather than simple physical composites, indicating the successful synthesis of the temperature-responsive nanosealing agent ASN. The particle size analysis showed that the synthesized nanoparticles in ASN have a uniform particle size distribution and display no agglomeration phenomenon. Applying ASN as a sealing agent in drilling fluid effectively fills the nanoscale micropores and microcracks in shale, making shale denser and significantly improving the wellbore stability of shale formations. In addition, it has good temperature resistance, can adapt to reservoirs at different temperatures, is non-toxic and environmentally friendly, and has good prospects for stable applications in shale formation wellbore.
研究领域:
石油工程
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材料科学
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产品关联
DOI
PubMed
高影响因子
CHEMISTRY & BIODIVERSITY
·
2025
·
IF 2.5
Jiayu Yang,Qiaoling Li,Jianpeng Zhang,Siyang Wu,Min Zhang,Lihui Chen,Hui Wu,Shengchang Lu
Adhesive patches are optimum candidates for distinct biomedical applications including tissue adhesion and leakage sealing in outpatient or surgical procedures. Unfortunately, most adhesive patches are significantly less effective at providing strong adhesion to the surface of wet tissue, which increases the risk and reduces the fault tolerance in surgery. Meanwhile, customization is difficult to achieve in terms of mechanical adaptability. To tackle this problem, we developed a chitosan-containing bioadhesive patch (ANC) comprising dual cross-linked carboxymethyl chitosan methacrylate (CMCS-MA), acrylic acid and acrylic acid N-hydroxysuccinimide ester. This ingenious and convenient design strategy facilitates the integrated polymerization of the patch, while circumventing the necessity for additional crosslinkers. ANC patches in dry state and the rich carboxyl groups contained therein enable rapid removal of moisture from tissue surfaces. Subsequently, robust adhesion based on hydrogen bonding and NHS-amine interaction is formed. The dual-crosslinked ANC patch achieve good adjustable mechanical performance and swelling behavior by controlling the addition of CMCS-MA. Furthermore, compared with commercially available fibrin glue, ANC patches own robust adhesion and superior sealing performance for stomach fluid leakage. This intricately designed ANC patch sheds new light on biomedical patch design and broadening the scope of chitosan-containing materials in tissue adhesive and sealant applications.
研究领域:
生物医学工程
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材料科学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
LANGMUIR
·
2024
·
IF 3.7
Zhengpeng Gu,Qingwen Dai,Chenbo Ma,Wei Huang,Xiaolei Wang
In this paper, the effects of surface roughness and wettability on the leakage performance of static seals were highlighted. The results show that the leakage rate is negatively correlated with the contact pressure and positively correlated with surface roughness. Surface wettability affects leakage performance. Leakage retardation is achieved by modifying the roughness and wettability at the interface. The seal interface consists of two oleophobicity surfaces and exhibits an excellent seal performance, of which the leakage reduction is approximately 64%. A theoretical model based on wettability is established to predict the leakage rates under varying wettability conditions, and its validity is confirmed. This research result is expected to be applied in the field of seals and predict the leakage performance of interfaces with different wettabilities to minimize and reduce the leakage of oil in static sealing systems.
研究领域:
工程学
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材料科学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
PROGRESS IN ORGANIC COATINGS
·
2022
·
IF 6.206
Guojing Chen,Wenyu Fu,Zhiqiang Liu,Hao Wei,Zhijia Zhang,Guojun Wang,Songsong Zhang,Qiang Wang,Rui Li,Xiao Ouyang
Fuel leakage accidents of storage facilities and pipelines are one of greatest threats to the environment, life safety and economics. Appling self-sealing coating to pipe surface is an economical and effective method to prevent the fuel leakage. In this work, the high oil-absorption resin was designed and synthesized by suspension polymerization . The oil-absorption performance and oil-absorption volume expansion ratio of the high oil-absorption resin for gasoline, kerosene, and diesel were characterized, respectively. The saturated absorption rate of the high oil-absorption resin for gasoline reached 11.14 g/g, and the volume of the high oil-absorption resin expanded to 6 times when the absorption was saturated. The outstanding oil/water separate property of the high oil-absorption resin illustrated the adsorptive selectivity and the potential application of them for pipelines protecting in ocean. The high oil-absorption resin, as a functional filler to the polyurethane resin , exhibited excellent expanding in volume performance to seal the hole of the composite coating . The composite coating with 25 wt% of the high oil-absorption resin sealed a hole of 1.5 mm in diameter in 1 min. As the bottle with filled by kerosene was perforated by a needle with 3 mm in diameter, the composite coating with 25 wt% of the high oil-absorption resin was successfully instantaneous sealed the leak.
研究领域:
材料科学
·
环境科学
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF APPLIED POLYMER SCIENCE
·
2019
·Vol. 136
·期 46
·48219
·
IF 2.188
Wan Li,Xingjiang Liu,Jinbi Wu,Linzhi Wu,Ailing Sun,Liuhe Wei
A new two-component modified polyurethane (PU) sealant was designed and synthesized for insulating glass. This sealant was designed based on a crosslinked reaction between a p -chlorophenol-blocked PU pre-polymer (Pre-polymer 2 ) in Component A and a poly-functional hyperbranched polyamine polymer (polyamide resin 300 # ) in Component B. During the synthesis of Pre-polymer 2 , Fourier transform infrared spectral analysis was used to track the process, and the optimal reaction time and temperature were 1.5 h and 80 °C, in the presence of 4, 4′-diphenylmethane diisocyanate (MDI). Different curing agents also used as deblocking agents were screened and it was found that polyamide resin 300 # was a good candidate for the curing reaction. In addition, the low-temperature curing rate was also improved by using dibutyltin dilaurate (DBTDL) and organobentonite together as a composite catalyst. Finally, the prepared two-component modified PU sealant for insulating glass was successfully used in an assembly line with good performance. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136 , 48219.
研究领域:
材料科学
·
化学工程
✓ 已验证
DOI
高影响因子
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
·
2025
·
IF 5.4
Zhiyuan Guo,Jingfu Song,Guoqing Wang,Gai Zhao
The 2A12 aluminum alloy is widely utilized in aerospace, automotive, and marine engineering due to its excellent strength-to-weight ratio and good machinability. However, its wear and corrosion resistance under harsh conditions are insufficient and require improvement. This study combined micro-arc oxidation (MAO) with paraffin sealing to enhance the corrosion resistance and tribological properties of 2A12 Aluminum Alloy. The results indicate that the MAO process significantly increases hardness and tribological properties, but the porosity into the oxidation layer may accelerate corrosion in corrosion environments. Paraffin sealing effectively fills these pores, reducing the penetration of corrosive agents and significantly improving corrosion resistance. Additionally, friction tests show that the hybrid coating after paraffin sealing exhibit a lower friction coefficient and wear rates. Molecular dynamics simulations (MD) further reveal the distribution of paraffin within the pores and its effect on wear and corrosion resistance. This study demonstrates that MAO combined with paraffin sealing is an effective approach to enhancing the corrosion and tribological properties of 2A12 aluminum alloy, providing new insights for its applications.
研究领域:
材料科学
·
表面工程
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产品关联
DOI
高影响因子
AIP Advances
·
2023
·Vol. 13
·期 10
·
IF 1.6
Li Yinhe,Guo Zhiqiang,Ma Shunfa,Tian Rumeng,Liu Xingjiang,Wei Liuhe
A new hydroxy-silane coupling agent was synthesized from 3-butene-1-alcohol and mercaptopropyl-3-methoxysilane based on a click reaction between double bonds and sulfhydryl groups and was successfully used in the synthesis of silane-modified polyether (STPE). The effect of molecular weight of polypropylene glycol (PPG) on the properties of silane-modified polyether was studied. It was found that with the increase in PPG molecular weight, the initial thermal decomposition temperature and hardness of STPE elastomers decreased, but the molecular structure hardly changed. In addition, with the increase in molecular weight, the elongation at break of the elastomer will gradually increase, but the tensile strength of the elastomer does not change much. When the molecular weight reaches 20 000 g/mol, the resin with a viscosity of 1.6 × 10 5 mPa s can be obtained, and the elongation at break of the cured elastomer reaches 383.4% and the tensile strength is 0.25 MPa. After the STPE resin was prepared into a silane modified sealant, the tensile strength reached 1.31 MPa and the elongation at break reached 406.2%, which had the best mechanical properties among the prepared sealants. This shows that the sealant prepared from high molecular weight resin has stronger mechanical properties, which provides a new idea for the preparation of sealants.
研究领域:
材料科学
·
化学工程
✓ 已验证
产品关联
DOI
高影响因子
危险品化学品经营许可证（带存储）