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COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS · 2024 · IF 4.9

Efficient mineralisation and disinfection of neonicotinoid pesticides with unique ZnAl-LDH intercalation structure and synergistic effect of Cu2O crystalline surface

Jiangfu Zheng,Changzheng Fan,Xiaoming Li,Qi Yang,Dongbo Wang,Abing Duan,Shuaijun Pan

Photocatalysts based on crystallographic effects and visible light-driven tunable nanostructures have been confirmed as a novel, scalable, and easy-to-implement technology. The hydrothermal reaction serves as the main method of synthesis for its novelty, becoming a viable alternative to other complex physical and chemical processes. In this study, hydrothermal conditions' parameters were set for nanostructured Cu 2 O/ZnAl-LDH photocatalysts. The nanostructured I-scheme Cu 2 O/ZnAl-LDH photocatalysts were prepared with an intercalated morphology. The prepared photocatalysts became the most effective photocatalyst for mineralizing and degrading nitenpyram solution, achieved nearly complete degradation and exceptionally high mineralization values (>40%) after 210 min of reaction, and exerted some ex vivo antibacterial, sterilising effects and potential for treating waste leachate (removal = 78%). The synergistic effect of Cu 2 O/ZnAl-LDH with both crystalline surface effect and intercalation structure can lead to reusability, high stability, versatility, and excellent photocatalytic performance in mineralize neonicotinoid pesticides.

研究领域: 环境科学 · 材料科学 · 农业科学
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