Self-assembled Ti3C2Tx/SCNT composite electrode with improved electrochemical performance for supercapacitor
Two-dimensional titanium carbide has gained considerable attention in recent years as an electrode material for supercapacitors due to its high melting point , good electrical conductivity , hydrophilicity and large electrochemically active surfaces. However, the irreversible restacking during synthesis restricts its development and practical applications. Here, Ti 3 C 2 T x /SCNT self-assembled composite electrodes were rationally designed and successfully synthesized by introducing single-walled carbon nanotubes (SCNTs) as interlayer spacers to decrease the restacking of the Ti 3 C 2 T x sheets during the synthesis process. SCNTs can not only increase the specific surface area as well as the interlayer space of the Ti 3 C 2 T x electrode, but also increase the accessible capability of electrolyte ions , and thus it improved the electrochemical performance of the electrode. The as-prepared Ti 3 C 2 T x /SCNT self-assembled composite electrode achieved a high areal capacitance of 220 mF/cm 2 (314 F/cm 3 ) and a remarkable capacitance retention of 95% after 10,000 cycles.
危险品化学品经营许可证（带存储）