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JOURNAL OF ELECTRONIC MATERIALS · 2021 ·Vol. 50 ·期 6 ·3222-3227 · IF 1.938

Synthesis of Cu@HBP-SH@Ag Particles by Using Thiol-Terminated Hyperbranched Polymer as Template and Dispersant

Han Wensong,Guo Qin,Su Tianhui

Cu@HBP-SH@Ag particles have been prepared by a facile synthesis strategy. Initially, thiol-terminated hyperbranched polymer (HBP-SH) was synthesized by stepwise polymerization. Subsequently, Cu particles covered with HBP-SH were prepared by reduction technology using HBP-SH as dispersant and template. Finally, Cu@HBP-SH@Ag particles were obtained by reduction reaction. Fourier-transform infrared (FT-IR) and ultraviolet–visible (UV–Vis) spectroscopy confirmed presence of HBP-SH on the surface of the Cu particles. The crystal structure was examined by x-ray diffraction (XRD) analysis. Scanning electron microscopy (SEM) and energy-dispersive spectrometry (EDS) analysis confirmed formation of Cu@HBP-SH@Ag particles. Thermogravimetric analysis (TGA) showed that the Cu@HBP-SH@Ag particles had better antioxidation properties than the Cu particles.

研究领域: 材料科学 · 化学工程
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