AgPd nanoparticles supported on zeolitic imidazolate framework derived N-doped porous carbon as an efficient catalyst for formic acid dehydrogenation
Formic acid (FA) has tremendous potential as a safe and convenient source of hydrogen for renewable energy storage, but controlled and efficient dehydrogenation of FA by a robust solid catalyst constitutes a major challenge. In this report, a metal nanoparticle functionalized zeolitic imidazolate framework (ZIF) derived N-decorated nanoporous carbon (NPC) support was fabricated and used as an efficient FA decomposition catalyst for the first time. The resultant AgPd@NPC catalyst exhibited 100% H2 selectivity and high catalytic activity (TOF = 936 h−1) toward the dehydrogenation of formic acid at 353 K. The synergetic interaction between the metal nanoparticles and NPC greatly enhances the catalytic performance of the as-prepared catalyst.
研究领域:
催化化学
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能源材料
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纳米材料
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物理化学
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氢能存储
✓ 已验证
DOI
高影响因子
危险品化学品经营许可证（带存储）