(Bi0.5Na0.5)TiO3-based relaxor ferroelectrics with simultaneous high energy storage properties and remarkable charge-discharge performances under low working electric fields for dielectric capacitor applications
High energy storage and charge-discharge performances under low electric field are desirable for lead-free dielectric materials because of environmental hazards, the risk of high voltage and the high cost of insulation technology. Herein, lead-free ceramics based on 0.6BNT-0.4Sr 0.775 Bi 0.15 TiO 3 (BNT-SBT) were designed, which simultaneously achieves a large energy storage density ( W rec ~ 2.41 J/cm 3 ) and a high efficiency ( η ~87.5%) under a low electric field of 190 kV/cm due to enhanced dielectric properties and the relaxation response. Moreover, the energy storage properties of the BNT-SBT ceramic exhibit moderate temperature stability, excellent frequency dependence, and cycling reliability. Furthermore, the charge-discharge performance simultaneously features a high power density ( P D ~51.4 MW/cm 3 ), an ultrafast discharge speed ( t 0.9 –77 ns), and remarkable stability against temperature and cycling. This study exploits a high-efficiency BNT-related ceramics with concurrently high energy storage and charge-discharge performances under low electric fields, which provides great potential in practical dielectric capacitor applications.
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