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CERAMICS INTERNATIONAL · 2021 ·Vol. 48 ·期 3 ·3875-3883 · IF 4.527

Investigation on the microcrcaks strengthening effect in the damage behavior of Al2TiO5 flexible ceramics based on the AE

Qingliang Shan,Qian Ma,Changrong Chen,Qiankun Xu,Yudong Xue,Hao Xiong,Yewei Wang,Yuqian Zhou,Anze Shui

In this study, the effect of microcrcaks strengthening on damage evolution of Al 2 TiO 5 (AT) flexible ceramics was investigated by acoustic emission (AE). Results reveal that with increasing content of ZrO 2 , the strength of AT flexible ceramics improves gradually and the strain increases at first then decreases. When the content of ZrO 2 is 12% and 8%, the strength and strain at maximum stress are increased by 154.92% and 38.27%, respectively. In addition, thanks to the “strengthening effect” of ZrTiO 4 on grain boundary microcracks, the damage development thresholds ( σ min and σ onset ), elastic modulus and fracture toughness of AT flexible ceramics modified with ZrO 2 are significantly improved. Moreover, the visible transverse cracks and matrix shedding in ATZ-0 are the most, but the cumulative AE damage events in ATZ-8 and ATZ-4 are more than ATZ-0 at late stage, for which the fracture of ZrTiO 4 glass phase and crack branching induced by ZrTiO 4 should be responsible.

研究领域: 材料科学 · 陶瓷学 · 固态物理 · 力学性能 · 结构表征 · 断裂力学
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MATERIALS & DESIGN · 2016 · IF 3.997

Bio-inspired design and fabrication of an ultralight and strong nano-carbon gradient composite

Yanjie Wang,Min Li,Weibang Lu,Yizhuo Gu,Shaokai Wang,Rui Sun,Xuetong Zhang,Qingwen Li,Zuoguang Zhang

A nano-carbon composite, consisting of a graphene aerogel-carbon nanotube (CNT) film, is constructed by coating a strong and flexible CNT film onto the surface of a porous graphene aerogel core. The prepared gradient composite, ultralight and strong, can carry objects more than 15,000 times its own weight, exhibiting impressive compression resistance. Compared to the original graphene aerogel , the composite exhibits 8–9-fold increased values in its elastic modulus and compressive strength at a strain of 20% and an approximately 10-fold increase in electrical conductivities in the axial direction . In addition, the elastic recovery ability after compressive deformation and the ability to preserve liquid are also improved.

研究领域: 材料科学 · 纳米科技 · 复合材料工程 · 生物启发设计 · 力学性能研究 · 功能材料 · 电学性能
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JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS · 2018 ·Vol. 56 ·期 19 ·1281-1286 · IF 2.499

Hydrogen bond-reinforced double-network hydrogels with ultrahigh elastic modulus and shape memory property

Yan Jie Wang,Chen Yu Li,Zhi Jian Wang,Yiping Zhao,Li Chen,Zi Liang Wu,Qiang Zheng

Development of tough hydrogels has greatly expanded their applications as load-bearing materials. However, the elastic modulus of tough hydrogels is usually lower than 1 MPa. It remains a challenge to design tough hydrogels with high modulus. We report here a series of tough double-network (DN) hydrogels with ultrahigh elastic modulus (up to 200 MPa) by forming robust hydrogen bonds between the first poly(acrylic acid) network and the second poly( N -isopropyl acrylamide) network. The dense cooperative hydrogen bonds greatly reduce the segmental mobility and thus improve the rigidity of gel matrix. Owing to the dynamic nature of hydrogen bonds, the modulus of hydrogels is strongly influenced by temperature and pH, affording the gels shape memory property. The strategy by forming robust noncovalent bonds between interpenetrating networks should be applicable to other systems for designing tough and versatile hydrogels with diverse promising applications. © 2018 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2018 , 56 , 1281–1286

研究领域: 高分子物理 · 生物材料 · 软物质科学 · 智能响应材料 · 组织工程
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APPLIED SURFACE SCIENCE · 2017 · IF 3.387

Structural evolution of plasma-sprayed nanoscale 3 mol% and 5 mol% yttria-stabilized zirconia coatings during sintering

Yan Zhao,Yang Gao

The microstructure of plasma-sprayed nanostructured yttria-stabilized zirconia (YSZ) coatings may change during high-temperature exposure, which would influence the coating performance and service lifetime. In this study, the phase structure and the microstructural evolution of 3YSZ (zirconia-3   mol% yttria) and 5YSZ (zirconia-5   mol% yttria) nanostructured coatings were investigated by means of sintering at 1400   °C for 50–100   h. The microhardness, elastic moduli, and thermal shock cycles of the 3YSZ and 5YSZ nanostructured coatings were also investigated. The results showed that the redistribution of yttrium ions at 1400   °C caused the continuous increase of monoclinic-phase zirconia, but no obvious inter-splat cracking formed at the cross-sections, even after 100   h. Large voids appeared around the nanoporous zone because of the sintering of nanoscale granules upon high-temperature exposure. The microhardness and elastic moduli of the nanostructured coatings first increased and then decreased with increasing sintering times. The growth rate of the nanograins in the 3YSZ coating was lower than that in 5YSZ, which slowed the changes in 3YSZ coating porosity during sintering. Although the 3YSZ coating was prone to monoclinic phase transition, the experimental results showed that the thermal shock resistance of the 3YSZ coating was better than that of the 5YSZ coating.

研究领域: 材料科学 · 表面工程 · 陶瓷涂层 · 热障涂层 · 高温材料
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