Environmentally friendly synthesis of Co-based zeolitic imidazolate framework and its application as H2O2 sensor
The work presented that by regulating the proportion between cobalt and 2-methylimidazole in distilled water, a series of Co-based imidazolate framework compounds with diverse shapes were synthesized at ambient temperature. The morphology and structural characteristics of the compounds were surveyed by scanning electron microscope, energy disperse spectra, powder X-ray diffraction and N 2 absorption-desorption. It was found by cyclic voltammetry that the zeolitic imidazolate framework compound synthesized at a ratio of 1:20 had the best electrocatalytic activity to H 2 O 2 reduction, therefore, the compound was chosen to fabricate a H 2 O 2 electrochemical sensor. Electrochemical studies indicated that the sensor had a determination limit of 0.7 μM and short response time within 3 s. The catalytic current was linear with H 2 O 2 concentration from 2.5 to 212.5, 212.5 to 1662.5 and 1662.5 to 6662.5 μM and the sensitivity were 12.2, 5.3 and 2.4 μA mM −1 cm −2 , respectively. Furthermore, the proposed sensor showed a good anti-interference capacity, repeatability and stability.
危险品化学品经营许可证（带存储）