Coatings
·
2023
·Vol. 13
·期 1
·110
·
IF 3.4
Xixi Yu,Yun Hu,Wen Lei,Chengguo Liu,Yonghong Zhou
Developing environmentally friendly UV-curable polymers with multi-functionality is very significant for sustainable development and environmental protection. In this work, a novel tung-oil-based UV-curable oligomer (TOMAH) was synthesized by Diels–Alder and ring-opening reactions via microwave technology. Subsequently, catalyst-free self-healing UV-curable materials based on a maleate monoester transesterification (MMETER) were developed by co-photopolymerization of TOMAH and hydroxyethyl methacrylate (HEMA). The obtained UV-cured materials possessed a high glass transition temperature (Tg> 81 °C), excellent adhesion (grade 1), and flexibility (2 mm). Particularly, the outstanding photopolymerization activity of the UV-curable resins was proved by UV-curing kinetics. In addition, dynamic transesterifications occurred without an external catalyst at a moderate temperature, resulting in good self-healing properties (with a scratch-repair efficiency of 78.6–93.3%) and shape-memory properties for the obtained UV-cured materials. This work combines the multiple advantages of biomass raw material, microwave synthesis technology, UV-curing method, and multifunctional polymers, thus providing an innovative strategy to fabricate sustainable and intelligent coatings.Keywords:UV-curable coatings;self-healing;tung oil;catalyst-free;microwave technology
研究领域:
材料科学
·
环境科学
✓ 已验证
产品关联
DOI
高影响因子
FUEL PROCESSING TECHNOLOGY
·
2015
·
IF 3.352
Hui Shang,Yu Liu,Jin-Chun Shi,Quan Shi,Wen-Hui Zhang
Most crude oils contain traces of metal complexes, among which vanadium (V) and nickel (Ni) compounds are the most harmful poisons to the catalysts of fluid catalytic cracking (FCC) and hydrogenation units. These metals are proven to be extremely hard to remove, since they exist in crude oil as stable oil-soluble complexes. The microwave technology provides a new way for Ni/V removal, their removal efficiency using chemical reagents and the mechanism of microwave-assisted demetallization were studied in this paper. It was concluded that the demetallization efficiency can be highly enhanced under microwave irradiation . There is no specific structural selectivity for vanadium porphyrins during microwave treatment process. The demetallization agent — methanesulfonic acid , containing a sulfonyl acid group was found to react with VO 2 + and Ni 2 + . Ni and V were removed from porphyrin ring without destroying the ring structure, corresponding water soluble inorganic salts were formed, thus can be successfully separated from crude oil by washing or desalting process.
研究领域:
化学工程
·
石油加工
·
环境科学
✓ 已验证
产品关联
DOI
高影响因子
SENSORS AND ACTUATORS A-PHYSICAL
·
2017
·
IF 2.499
Mohammad Russel,Sun Zhenxiang,Liu Changrui,Zhou Hao,Liu Lifen,Sophocleous Marios,Zhou Yong
A microwave-based, rapid and non-destructive spectroscopic technique has been developed to monitor contamination in beach-sand. A set of in-vitro experiments were designed to test beach-sand samples contaminated with meta-cresol (m-cresol) and water with weight/weight percentages of 0–20%, using a prototype probe with a long sample holder (16 mm). The frequency range used was 10 MHz–1 GHz during the whole experiment. Air and Teflon were investigated as low-loss materials, whilst ethanol was used as a typical, frequency-dependent, polar material to further verify the technique. The real part of the relative complex permittivity was found to be very close to the theoretical and fitting very well with the Debye model. This dielectric technique showed a linear relationship between the real part of relative complex permittivity and m-cresol/water content, for a frequency range of 0.02–0.7 GHz for water and 0.02–0.2 GHz for m-cresol. The sensitivity was calculated to be 0.58% −1 and 0.12% −1 for water and m-cresol, respectively.
研究领域:
环境科学
·
化学工程
✓ 已验证
产品关联
DOI
高影响因子
Materials Express
·
2021
·Vol. 11
·期 12
·2015-2023
·
IF 0
Han Zhaohui,Xu Yang,Xu Lei,Guo Shenghui
In this research, the diamond particles were coated with titanium by microwave heating method, then the Ti-coated diamond particles were used as raw material to fabricate the diamond/Al composites by microwave sintering. The result shows that the diamond particles could be covered with
a uniform and continuous Ti coating under microwave irradiation, and the best Ti coating was obtained at 810 °C for 1 h. The metallic bond between diamond and Ti was formed to generate the intermediate transition layer of TiC. The diamond/Al composites which used Ti-coated diamond particles
as raw material and were fabricated by microwave sintering show high relative density and hardness. The relative density and hardness of the diamond/Al composites increased with the temperature. While the composites were sintered at 710 °C for 1 h, the density could reach 2.855 g·cm−3,
and relative density was 92.09%, which shows better microstructures and properties. There is Al3Ti alloy phase in Ti-coated diamond/Al composites, so the Ti-coated diamond can be well combined with the Al matrix, which can further improve the properties of the composites.
研究领域:
材料科学
·
复合材料制备
✓ 已验证
产品关联
DOI
MATERIALS CHEMISTRY AND PHYSICS
·
2020
·
IF 3.408
Ruimin Hu,Tao Fan,Jinlong Yang,Hang Xiao,Yiping Liu,Ming Lu
Recent years have witnessed the explosive progress of functional nano materials in textile field, requires us to re-recognize and understand the potential hazards of nanoparticles . A harmless, cost-effective and facile approach of growing functional particles with special morphology and immobilizing onto cellulose fabric (CF) to prepare functional fabrics is highly desired. Here, commercial TiO 2 nanoparticles (TiO 2 NPs) grow under ultrasound-microwave and form a flake-like structure, which retain excellent photocatalytic degradation ability and prevented the potential harm to human body when nanoparticles fell off. The method was implemented based on 4-methylmorpholine-N-oxide (NMMO) aqueous system which was approved as a favorable solvent for dissolving cellulose, and grew flake-TiO 2 on cotton fibers under the assistance of the ultrasound and microwave. The as-prepared TiO 2 -CF possessed satisfactory photocatalytic activity for Methylene blue (MB) and Rhodamine B (RhB) dyes under ultraviolet light with the low dye residue rate of about 5% and 1%, respectively. After 50 times rigorous washing procedures, the titania loading next to 18% was confirmed by thermogravimetric analysis , which proved that TiO 2 -CF had good wash fastness.
研究领域:
材料科学
·
纺织工程
·
环境科学
✓ 已验证
产品关联
DOI
高影响因子
Functional Materials Letters
·
2024
·
IF 1.2
Yuqi Li,Jianghong Xu,Sujuan Guo
The application of microwave technology has penetrated all aspects of life, but also lead to the electromagnetic pollution, therefore the research of high efficiency microwave absorption materials has been widely concerned. In this work, a new type of Al based CAU-10-H MOF was prepared by hydrothermal method. The particles were polyhedral in size of 2 μ m. After high temperature annealing, the interplanar spacing increased with the annealing temperature, and the lattice structure was destroyed at 400 ∘ C. CAU-Al/rGO aerogels were prepared by freeze-drying of hydrogels. With the increase of CAU-Al content and the annealing temperature, the carbon crystallinity decreases, and the pores of the aerogels became larger and fluffier. The real parts of permittivity of CAU-Al/rGO aerogels were between 5 and 30, which can be tuned by the annealing temperature and CAU-Al content. For the microwave absorption performance, the CAU-Al/rGO aerogel with a ratio of 3:1 achieved the minimum reflection loss of − 37.8 dB at 3 mm. Moreover, the CAU-Al/rGO aerogels showed a wide effective bandwidth, which reached 5.1 GHz under the thickness of 2.5 mm. Therefore, the CAU-Al/rGO aerogels could be used as a kind of broadband microwave absorber with excellent microwave absorption performance.
研究领域:
材料科学
·
电磁学
·
纳米科技
✓ 已验证
DOI
高影响因子
Asia-Pacific Journal of Chemical Engineering
·
2022
·Vol. 17
·期 5
·e2790
·
IF 1.777
Bingyi Zhou,Tao Ge,Xiaoman Luo,Zhaohui Wang,Yueyue Qiao,Chuanchuan Cai,Jingyao Xu
Under the two frequency microwave conditions of 915 and 2450 MHz, orthogonal tests were designed to investigate the effects of organic acid reagent, microwave irradiation time, and mixing time of additives and coal samples on the desulfurization effect of coal. Results show that the effect of irradiation time on the experimental desulfurization efficiency under frequency microwave conditions is large and is the main factor. The desulfurization effect under 915 MHz microwave condition is better than 2450 MHz microwave condition. Two sets of experimental optimal coal samples were used for characterization and analysis. Thermogravimetric analysis revealed that the combustion temperature range of the coal samples is shortened and the integrated combustion index is considerably higher after the microwave irradiation experiment. Fourier-transform infrared spectroscopy analysis showed that the overall chemical structure of the coal samples does not change significantly after the experimental treatment. X-ray photoelectron spectroscopy analysis showed that the intensity of organic sulfur in coal samples is weakened after microwave irradiation, the characteristic peaks of thiols and thioethers are reduced to a great extent, and an increase in the intensity of sulfoxide organic sulfur is observed. On the basis of the results of experimental analysis and quantum chemical simulation calculations, the mechanism of organosulfur structure removal under the action of microwave is revealed.
研究领域:
能源化学
·
煤化学
·
环境工程
·
材料科学
·
物理化学
·
分析化学
·
清洁燃料技术
✓ 已验证
DOI
高影响因子
Journal of Materiomics
·
2025
·
IF 9.6
Tauqeer Ahmad,Wen Lei,Burhan Ullah,Wen-zhong Lu
A series of (Sr 0.4 Ce 0.4 )TiO 3 + 4% (in mass) Sr 2 CeO 4 + x % B 2 O 3 (SCTO + 4% SCO + x % B 2 O 3 for 1≤ x ≤ 5) composites were synthesized via solid-state reaction to investigate the effects of Sr 2 CeO 4 and B 2 O 3 additives on their structural evolution and microwave dielectric properties. X-ray diffraction (XRD) and Rietveld refinement confirmed the dominant orthorhombic phase (O-phase), with SCO as a secondary phase, indicating a chemically stable composite system. HRTEM and SAED analyses further confirmed the formation of the O-phase through direct observation of the superlattice reflections. Microstructural evolution demonstrated B 2 O 3 -assisted liquid-phase sintering, reducing porosity (0.017→ 0.006) and increasing grain size (3.34 → 6.01 μm) with increasing x % (in mass). Raman spectroscopy verified octahedral tilting and Ce–O stretching, while B 2 O 3 incorporation modified the TiO 6 network via BO 3 /BO 4 interactions. The ε r decreased from 113 (SCTO) to 27 at x = 5%, while τ f improved from +213 to +12×10 –6 /°C. The reduction in ε r arises from a complex interplay of internal factors (ionic polarizability) and external factors (porosity, and density), whereas the variation in τ f is governed by compensating effects from Sr 2 CeO 4 and B 2 O 3 . Optimal microwave performance was achieved at x = 5%, with Q×f = 43,603 GHz, ε r =27, and τ f of +12×10 –6 /°C. The study demonstrates that SCO and B 2 O 3 act as effective modifiers, enhancing densification and dielectric properties in SCTO-based microwave ceramics.
研究领域:
材料科学
·
电子材料
·
功能陶瓷
·
介电材料
·
微波技术
·
固态化学
✓ 已验证
产品关联
DOI
高影响因子
CERAMICS INTERNATIONAL
·
2025
·Vol. 51
·期 30
·63013-63021
·
IF 5.6
Ning Zhang,Junqi Chen,Ning Guan,Huaicheng Xiang,Ying Tang,Yuandong Qin,Liang Fang
Two novel ceramics, Li 2 Mg 2 Ga 2 Ti 3 O 12 (LMGT) and Li 2 Zn 2 Ga 2 Ti 3 O 12 (LZGT), featuring a spinel structure, were synthesized utilizing the solid-state method. Comprehensive characterization confirms that LZGT ( P 4 3 32) forms a B-site 1:3 ordered spinel, while LMGT ( Fd -3 m ) adopts a disordered spinel structure. The ceramics exhibit outstanding microwave dielectric properties, characterized by low ε r of 14.92 and 19.11, high Q×f of 120,000 and 93,800 GHz, and negative τ f of −40.21 and −32.83 ppm/°C for LMGT and LZGT, respectively. The observed ε r values significantly exceed theoretical values due to underestimated Ti 4+ polarizability along with the rattling effect of Ti 4+ and Ga 3+ . Q×f values correlate with packing fraction, lattice energy, and electrical properties. The negative τ f values stem from dominant positive τ ε and τ αm contributions. Utilizing LMGT with ultra-low loss, a dielectric resonator antenna was designed, achieving a radiation efficiency of 93.01 % and a gain of 6.12 dBi at 6.60 GHz, highlighting significant potential for C-band communication satellite applications.
研究领域:
材料科学
·
无机非金属材料
·
电子功能材料
·
微波技术
·
天线工程
·
固态化学
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
·
2025
·Vol. 36
·期 14
·831
·
IF 2.8
Zhao Tianqun,Zeng Tianrui,Jin Shilei,Li Xiaohui,Yu Zhiqiang
BNT (BaO–Nd 2 O 3 –TiO 2 ) system was modified via doping using sol–gel method, and BNST-Mn/PTFE microwave dielectric composite was prepared by mechanical blending. Scanning electron microscopy (SEM), thermal dilatometer, and split post-dielectric resonator (SPDR) were used to characterize the microstructure, dielectric properties, and thermal properties of the composite materials. The results indicate that as the amount of ceramic filler supplied grows, the agglomeration of fillers becomes more pronounced. At a filler content of 10 wt%, the dispersion of the filler in the matrix resin is relatively uniform. The dielectric constant and dielectric loss of the composites increased, and the bonding ability between the two phases diminished with the increase in filler content. When the mass fraction of the ceramic was increased to 70 wt%, the dielectric constant of the composite was 10.92 and the Q·f value was measured at 3584 GHz. At the same time, the coefficient of thermal expansion (CTE) of the composites reached 23 ppm/°C, which was a good compatibility with the copper foil. Lichtenecker equation, Maxwell–Wagner equation, Jayasundere–Smith equation, and effective medium theory equation (EMT) were used to predict the dielectric constant of the composites. In comparison, the dielectric constant values calculated using the EMT equation were in good agreement with the experimental values, especially at low filling volumes. Also, the simulation results of the thermal expansion coefficient of composite materials using the Lichtenecker equation and its improved form are in good agreement with the experimental values.
研究领域:
材料科学
·
陶瓷与复合材料
·
介电材料
·
微波技术
✓ 已验证
产品关联
DOI
高影响因子
FOOD HYDROCOLLOIDS
·
2024
·
IF 11
Xiangcun Wang,David Julian McClements,Zhenlin Xu,Man Meng,Chao Qiu,Jie Long,Zhengyu Jin,Long Chen
Pre-fried microwaveable foods are popular with many consumers because of the simplicity and speed of their preparation. However, these foods often lose their desirable crispiness after microwaving, which reduces their sensory quality and consumer acceptance. In this study, we prepared and characterized calcium-starch (CA-S) chelates and then investigated their impact on crispness retention during the microwaving of a model food (chicken nuggets). As expected, the amount of calcium bound by the CA-S chelates increased as the calcium concentration was raised. Multi-scale structural analysis of the CA-S chelates showed that calcium binding disrupted the hierarchical structure of the starch. During gelatinization, CA-S chelates exhibited a higher peak viscosity than regular starch. Adding the CA-S chelates to batter of chicken nuggets significantly improved their crispness after microwaving, without adversely affecting their color, taste, and other sensory attributes. Chicken nuggets containing 15% CA-S chelates had the highest crispness, with the value being almost 50% greater than the control group. The coating and microwave heating properties of the batter were also improved by adding the CA-S chelates. For instance, incorporating 25% CA-S chelates into the batter increased the coating “pick-up”, dielectric constant, and dielectric loss constant values by around 55%, 21%, and 20%, respectively. This increase in dielectric properties is beneficial because it enhances heat transfer to the batter during microwaving, thereby increasing the crispiness of the chicken nuggets.
研究领域:
食品科学
·
材料科学
·
微波技术
✓ 已验证
产品关联
DOI
高影响因子
FOOD RESEARCH INTERNATIONAL
·
2024
·
IF 7
Xingwei Wang,Heping Cui,Xiaoming Zhang,Jingyang Yu,Shuqin Xia,Chi-Tang Ho
Directional and rapid formation of the Amadori rearrangement product (ARP) from the glutamic acid and xylose was achieved through intermittent microwave heating. The yield of ARP reached 58.09 % by subjecting the system to intermittent microwave heating at a power density of 10 W/g for 14 min. Dehydration rate and microwave effects were found to be key factors to optimize the conditions for directional and rapid preparation of the ARP. Through a comprehensive analysis of the ARP degradation and further browning under both conductive and microwave thermal processing, it was observed that microwave processing significantly accelerated the browning degree of systems, leading to a tenfold reduction in the heating time required for browning. This research presented a promising avenue for the development of novel and expedited methods for the production of ARP and highlighted the potential of ARP in enhancing color quality in fast-cooking applications utilizing microwave.
研究领域:
食品科学
·
化学工程
·
微波技术
✓ 已验证
产品关联
DOI
PubMed
高影响因子
危险品化学品经营许可证（带存储）