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Small · 2019 ·Vol. 15 ·期 30 ·1902280 · IF 10.856

High Energy Capacitors Based on All Metal-Organic Frameworks Derivatives and Solar-Charging Station Application

Xijun Wei,Wanping Hu,Huarong Peng,Yuli Xiong,Peng Xiao,Yunhuai Zhang,Guozhong Cao

High energy and efficient solar charging stations using electrochemical capacitors (ECs) are a promising portable power source for the future. In this work, two kinds of metal-organic framework (MOF) derivatives, NiO/Co 3 O 4 microcubes and Fe 2 O 3 microleaves, are prepared via thermal treatment and assembled into electrochemical capacitors, which deliver a relatively high specific energy density of 46 Wh kg −1 at 690 W kg −1 . In addition, a solar-charging power system consisting of the electrochemical capacitors and monocrystalline silicon plates is fabricated and a motor fan or 25 LEDs for 5 and 30 min, respectively, is powered. This work not only adds two novel materials to the growing categories of MOF-derived advanced materials, but also successfully achieves an efficient solar-ECs system for the first time based on all MOF derivatives, which has a certain reference for developing efficient solar-charge systems.

研究领域: 材料科学 · 电化学 · 能源存储 · 纳米材料 · 可再生能源
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