FOOD CHEMISTRY
·
2025
·
IF 9.8
Litao Hao,Yangchun Han,Shixi Zhang,Yingjie Luo,Kunli Luo
Trace elements in crops can affect the bioavailability of Se. To investigate the effect of trace element on Se bioavailability, trace element concentrations and Se bioavailability in crops from Se-rich area (Langao County, China) were analyzed using the physiologically-based extraction test (PBET) digestion model. Vegetables (rapes, radishes, and potatoes) had higher concentrations of total and bioavailable Se compared to grains (corn, rice, and sweet potatoes), suggesting they are more effective for Se supplementation. The bioavailability of Se was higher in the intestinal phase than in the gastric phase. Trace elements were positively correlated with the increased bioavailability of Se in corn, potato, and rape. Fe was a key element in increased bioavailability of Se in the gut model. Therefore, trace elements, particularly Fe, in crop can enhance Se bioavailability, suggesting their potential use in Se supplementation. The findings of this study provide valuable insights for dietary interventions to Se deficiencies.
研究领域:
营养学
·
植物学
✓ 已验证
DOI
PubMed
高影响因子
ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY
·
2018
·
IF 3.974
Zhiyue Liao,Huabin Cao,Xueyan Dai,Chenghong Xing,Xiongwei Xu,Gaohui Nie,Caiying Zhang
To investigate the toxic effects of Molybdenum (Mo) and Cadmium (Cd) on trace elements in digestive organs of Shaoxing duck ( Anas platyrhyncha ), 120 Shaoxing ducks were randomly divided into control group and 5 treatment groups which were treated with a commercial diet containing different dosages of Mo and Cd. On the 60th and 120th days, the beak, esophagus, glandular stomach, muscular stomach, small intestine, large intestine and feces were collected to determine contents of Mo, Cd, copper (Cu), iron (Fe), zinc (Zn) and selenium (Se), then correlation analysis was performed. The results showed that Cd content in digestive organs significantly increased in co-treated groups compared to single treated groups and Mo concentration increased in Mo-treated groups compared to control group, whereas Cu, Fe, Zn and Se concentrations in digestive organs decreased in co-treated groups. Furthermore, Cd and Mo were mainly accumulated in the small intestine and esophagus, respectively. There was a strongly positive correlation between Cd and Mo while they had negative correlation with Cu, Fe, Zn and Se, respectively. In feces, Mo and Fe contents in high dose of Mo group and high Mo combined with Cd group were significantly higher than those in control group, and Cu content in all treated groups significantly increased and Cd, Zn and Se concentrations had no difference. The results indicated that dietary Mo or/and Cd might disturb homeostasis of trace elements in digestive organs of Shaoxing duck. Moreover, the two elements presented a synergistic relationship.
研究领域:
动物生理学
·
环境毒理学
·
营养学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
METALLURGICAL AND MATERIALS TRANSACTIONS B-PROCESS METALLURGY AND MATERIALS PROCESSING SCIENCE
·
2025
·Vol. 56
·期 3
·2541-2557
·
IF 3.1
Cao Jianqi,Feng Shanshan,Wang Wanlin,Huang Daoyuan,Sun Yongqi
Vanadium, an extremely important metal element, is dominantly produced from the roasting–leaching process of vanadium–bearing slags, with the roasting process involving a conversion of vanadium–containing phases including iron–vanadium spinels and liquid phase into soluble vanadate. It is difficult to extract vanadium from iron–vanadium spinels due to their ultrastabilities and complex compositions. The presence of minor elements affects the stability of iron–vanadium spinels upon roasting as well as the further leaching process. In this study, the roles of various minor elements on phase and composition evolutions of iron–vanadium spinels upon calcium roasting were investigated by both advanced experimental characterizations (EPMA, XRD and XPS) and thermodynamic calculation using FactSage 8.3. The results first showed that the iron–vanadium spinel underwent a phase transition to form two distinct phases, namely a V-enriched phase and a Fe 2 O 3 solid solution. The presence of Cr 2 O 3 , MnO and MgO did not produce a new phase, but affected the compositions of the two phases formed. However, new phases were generated in the presence of TiO 2 and Al 2 O 3 , namely a Fe 2 TiO 5 phase and an Al-enriched phase, respectively. Moreover, a higher roasting temperature enhanced the partitioning of TiO 2 , Al 2 O 3 and Cr 2 O 3 from the V-enriched phase to the Fe 2 O 3 solid solution, which promoted the enrichment of V 2 O 5 into the V-enriched phase. A lower roasting temperature promoted the formation of manganese vanadate and magnesium vanadate for further leaching process. These findings offer a guidance for optimizing the roasting conditions for maximum vanadium extraction from iron–vanadium spinels.
研究领域:
冶金学
·
材料科学
✓ 已验证
产品关联
DOI
高影响因子
BIOLOGICAL TRACE ELEMENT RESEARCH
·
2016
·Vol. 174
·期 1
·85-92
·
IF 1.798
Zhou Sihui,Zhang Caiying,Xiao Qingyang,Zhuang Yu,Gu Xiaolong,Yang Fan,Xing Chenghong,Hu Guoliang,Cao Huabin
Molybdenum (Mo) is an essential trace element for animals and human beings. However, the negative effects on rumen function and distribution of trace elements in tissues induced by excessive Mo have not been well understood. Therefore, the purpose of present study was to investigate the impact of Mo on rumen microbiota, distribution of trace elements in various organs, and hematological parameters of goats. A total of 36 goats were randomly distributed into three groups with equal number and low-Mo and high-Mo groups were orally administered ammonium molybdate at 15 and 45 mg · Mo · kg −1 · BW respectively, while the control group received corresponding quantitative deionized water. The results showed that the total number of ciliate and protozoa protein concentration decreased significantly ( P < 0.01) on days 25 and 50. Concentrations of ammonia nitrogen and bacterial protein were significantly higher ( P < 0.05) in low-Mo group, while they were lower ( P < 0.05) in high-Mo group than the control group on days 25 and 50. In addition, Mo accumulated in serum and all detected tissues. Copper (Cu) and zinc (Zn) contents significantly decreased ( P < 0.05) in hair and serum on days 25 and 50, while Cu contents increased ( P < 0.05) and the change of Zn contents were not obvious ( P > 0.05) in other tissues on days 25 and 50. Besides, there was no obvious variation in iron (Fe) contents during whole experiment period ( P > 0.05). Furthermore, excessive Mo content had no significant effect on red blood cell (RBC) counts and hemoglobin (HGB) concentration ( P > 0.05) on days 25 and 50, while white blood cell (WBC) counts increased significantly ( P < 0.05) on day 50. These results indicated that excessive Mo content could impact the balance of ruminal microorganisms and interfere with the absorption and distribution of Mo and Cu mainly.
研究领域:
动物营养学
·
微生物学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
SCIENCE OF THE TOTAL ENVIRONMENT
·
2021
·
IF 7.963
Junzhi Yu,Zhansheng Wu,Xiongfang An,Fei Tian,Bing Yu
The stability of biochar is a crucial parameter in determining the potential of biochar for carbon sequestration . Many studies have demonstrated that the addition of clay during the pyrolysis of biomass is beneficial for the production of biochar with a high stability, but finding a strategy for a further improvement of stability of clay-modified biochar is still highly desirable. Herein, the co-pyrolysis of biomass and clay mediated by trace metal elements is proposed as a new strategy for the production of biochar with exceptionally high stability. The results indicate that the biochar resistance index for biochar obtained from the trace metal elements mediated the co-pyrolysis of biomass and clay is ~0.75, which is much higher than that of biochars obtained from biomass pyrolysis or the co-pyrolysis of biomass and clay, demonstrating that the presence of metal ions during the co-pyrolytic process can significantly improve the oxidation resistance of biochar. Thermogravimetric analysis reveals that the carbon retention value is reduced when the addition of metal ions during the co-pyrolytic process, and the presence of metal ions can reduce the starting temperature of the pyrolysis reaction and catalyze the process of biomass pyrolysis. In addition, the percentages of C C, C C, and C H in all biochars obtained from trace metal elements mediated the co-pyrolysis of biomass and clay are greater than 41.82%, which are higher than that of original biochar. Besides, the percentage of oxygen-containing functional groups is found to be decreased after the presence of metal ions during the co-pyrolytic process. The presence of metal ions can form metal nano-sulfides and oxides on the surface, which plays a physical barrier to the anti-oxidation performance of biochar. Furthermore, compared to BBC or BC, MnBBC and ZnBBC have a better leaching resistance to P, while FeBBC has almost no leaching resistance to soil P. Overall, the study reveals that the addition of trace element metal ions during the co-prolysis of biomass and bentonite is an effective method to increase the stability of obtained biochar, and it is also beneficial for retarding the release of nutrients in the soil and thus increase the utilization of nutrients.
研究领域:
环境科学
·
土壤学
✓ 已验证
DOI
高影响因子
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
·
2019
·Vol. 26
·期 14
·14073-14086
·
IF 2.914
Tudi Muyesaier,Phung Dung Tri,Ruan Huada Daniel,Yang Lin-sheng,Guo Hai-Jun,Connell Des,Sadler Ross,Chu Cordia
The concentration level related to toxicities of trace elements in drinking water, rice, wheat flour, and their associated negative impacts on human health have become an emergent issue in China. Because Xinjiang is the largest province in China with the majority of arable pasture land available for cultivation, it is important to analyze the concentrations of trace elements in relation to their toxicities in water, rice, and wheat flour and to investigate the health risk differences between agricultural and pastoral areas in Bay County, Xinjiang. The study results showed that (1) metal concentrations from drinking water, rice, and wheat flour were within the permissible limits; (2) concentration levels of trace elements and their total risk from drinking water and rice were higher in the agricultural areas than those in the pastoral areas, whereas concentration levels of trace elements and their total risk from wheat flour were higher in the pastoral areas than those in the agricultural areas; (3) the concentration level of the trace elements in rice were higher than in the wheat flour, but the risk from the wheat flour was higher than the risk from rice; (4) total non-cancer risk from the flour (HI f ) in both areas exceeded the respective safe reference doses; (5) total cancer risk from the wheat flour, rice, and water exceeded the safety limit (1 × 10 −4 ); (6) for the exposed population, arsenic was suggested as the most evident pollutant leading to carcinogenic concerns regarding the water, rice, and wheat flour; (7) the risk index from the wheat flour made up the highest percentage both in the total cancer risk and the non-cancer risk, followed by rice and then water; and (8) the human health risk was attributed to influence from the local environment in the agriculture areas, while it was attributed to the external environment in the pastoral areas.
Graphical abstract
研究领域:
环境科学
·
公共卫生
✓ 已验证
产品关联
DOI
PubMed
高影响因子
SOIL USE AND MANAGEMENT
·
2019
·Vol. 35
·期 4
·664-674
·
IF 1.958
Xuewei Wang,Yanju Gao,Baowei Hu,Guixin Chu
Polyphosphate is an alternative phosphorus (P) source which can substitute for orthophosphate-based P fertilizers in agriculture. In order to explore the effects of polyphosphate addition on soil P availability, and how pH and temperature affect polyphosphate hydrolysis, an aqueous and a soil incubation experiment were conducted at different pHs (5.0 and 8.2) and temperatures (15, 25 and 35°C); the influence of polyphosphate addition on soil available micronutrients (i.e., iron—Fe, manganese—Mn and zinc—Zn) was also studied. The experiments used three different polyphosphate fertilizers (solid and liquid ammonium polyphosphate and polyphosphoric acid) and two soil types (acid and alkaline). In aqueous incubation conditions, the average amount of phosphate ( ) released from polyphosphate fertilizers at 35°C was 2.7 times greater than at 25°C. The average Olsen P in polyphosphate-treated soil at 35°C was 1.12 times greater than at 25°C, indicating that higher temperature facilitates polyphosphate hydrolysis. Polyphosphate hydrolysis increased as the pH decreased in aqueous solution, but its hydrolysis rate was greater in calcareous soil than in acid soil. Moreover, polyphosphate significantly increased soil available Fe, Mn and Zn concentrations by an average of 14%, 16% and 20%, respectively, relative to orthophosphate fertilizer. In summary, high temperature and low pH favour the hydrolysis of short-chain polyphosphate (aqueous incubation experiment), and polyphosphate significantly increases soil P availability and mobilizes soil micronutrients. The application of polyphosphate can be recommended as a pragmatic P management strategy in agriculture: however, soil temperature and pH should be taken into account when using polyphosphate fertilizers.
研究领域:
农业科学
·
土壤学
✓ 已验证
产品关联
DOI
高影响因子
ANALYTICAL LETTERS
·
2018
·
IF 1.206
Ziwei Li,Dongming Han,Mingchuan Wang,Yuexin Zhang,Yang Wang,Xiufeng Yan,Qiuying Pang
This study aimed to develop a precise and accurate method of sample preparation of Auricularia auricula for inductively coupled plasma-optical emission spectrometry-based trace element determination and to compare concentrations of seven trace elements (Mg, Fe, Mn, Zn, Ni, Cr, Sr) in six A. auricula samples belonging to three varieties with two cultivation substrates. Five sample preparation procedures, microwave-assisted digestion, nitric acid digestion with hot plate heating, nitric acid and perchloric acid digestion with hot plate heating, nitric acid digestion with ash content, and aqua regia digestion with ash content, were compared. The performance of the procedures was determined based on the precision and accuracy of the results and the limits of detection of the elements. The best results, with limits of detection of 0.60–6.60 ng · mL−1 and recoveries for spiked samples between 93.80 and 105.00%, were found using nitric acid digestion with ash content. Six A. auricula samples were analyzed using the proposed procedure. Among the tested elements, the concentration of Fe was highest in all six A. auricula samples up to a maximum concentration of 284.83 µg · g−1. The concentrations of Mn, Cu, and Ni increased in mixed stands (basswood, birch, and mongolica) compared with pine sawdust cultivation.
研究领域:
食品科学
·
分析化学
✓ 已验证
产品关联
DOI
高影响因子
Journal of Environmental Sciences
·
2020
·
IF 4.302
Qiangying Zhang,Ming Que,Wei Li,Shuang Gao,Xin Tan,Duo Bu
Gangba sheep are known for having typical sensory characteristics attributed to free range conditions and grazing on wild plants. The genuine Gangba mutton was selected as the experimental group, and the commercial Tibetan mutton was selected as the control group, the nutritive composition of basic chemical components, amino acids and fatty acids in mutton were investigated to correlate its unique meat quality and eating satisfaction. The results showed that fatty acids were significantly higher ( P <0.05) in Gangba mutton than in commercial mutton, and the higher content of flavoring amino acids (glutamic acid and aspartame) were primarily responsible for the taste attributes umami of meat juices. Moreover, the trace elements analysis in mutton and grazing factors (forage, water source and soil) were conducted, to explain the source of essential trace elements in mutton. The concentrations of essential trace elements show that the Gangba mutton was a valuable source for highly available Cu and Zn in human nutrition, and well managed with few detected of toxicity metal. The concentrations of essential trace elements in mutton are closely related to the trace elements in environmental grazing factors. In conclusion, the congenital grazing conditions (a highly mineralized water resource, natural forages and clean soils) were shown to contribute to the unique meat characteristics of Gangba sheep.
研究领域:
动物科学
·
食品科学
·
营养学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
Asia-Pacific Journal of Chemical Engineering
·
2016
·Vol. 11
·期 2
·305-313
·
IF 0.728
Xing Li,Lei Bei,Zhi Sun,Kun Liu,Xu Zhang,Xiaozhao Han
The study aimed at investigating the addition effects of P, K, and micronutrient fertilizers on the permeability of N-nutrient fertilizer urea through a representative polymer membrane, which is of great importance in polymer-coated compound fertilizer. Specifically, the permeability of urea through polystyrene membrane was determined experimentally at the nominal temperature of 298 K using the Ussing chamber method for fertilizer solutions of urea–water, urea–NaH 2 PO 4 –water, urea–Ca(H 2 PO 4 ) 2 –water, urea–KCl–water, and urea–NaCl–water. The experimental data showed that the addition effects of NaH 2 PO 4 , KCl, and NaCl on urea permeability were pronounced and could be promotion or suppression depending on the amounts added. The variation of urea permeability with additive concentration could be explained by the ‘solution–diffusion’ model, suggesting that the specific intermolecular and interionic interactions in the permeation solution were an important factor determining the permeability. Using the saturated urea–water solution as basis, the addition of saturated KCl increased the urea permeability by 2.5 times, while the addition of saturated Ca(H 2 PO 4 ) 2 and NaH 2 PO 4 decreased the permeability by 41% and 76%, respectively. © 2016 Curtin University of Technology and John Wiley & Sons, Ltd.
研究领域:
农业科学
·
材料科学
✓ 已验证
产品关联
DOI
高影响因子
BIOLOGICAL TRACE ELEMENT RESEARCH
·
2020
·Vol. 198
·期 1
·58-67
·
IF 2.639
Wang Hetao,Liu Hao,Zhou Meijuan,Shi Hanping,Shen Mei
We established a method of determining 13 trace elements (TEs) in whole blood, determined the levels of the TEs in patients with colorectal cancer (CRC), and examined the correlations between the TEs and circulating tumor cells (CTCs). A total of 93 CRC patients and 48 control subjects in Guangzhou, China, were included. Inductively coupled plasma mass spectrometry (ICP-MS) was used to measure the blood levels of 13 TEs. CTCs of 13 CRC patients were examined using CanPatrol™. The levels of Mg, Fe, Zn, Se, Sr, Mo, and Ba in CRC patients were lower than those in control subjects (all, P < 0.05). The levels of Mg, Fe, Zn, Se, and Ba decreased with increasing TNM stage. The reductions of Zn and Se levels were higher in early-stage than late-stage CRC patients. The levels of Cu and Ni were higher in CRC patients than in control subjects (both, P < 0.05). The Cu level increased with increased TNM stage, and Ni level was higher in early-stage CRC patients as compared with late-stage CRC patients. Consequently, the TE levels showed differences as the process of TNM stage of CRC patients. There were correlations between the amount of CTCs and epithelial-CTCs (E-CTCs) and interstitial-CTCs (M-CTCs) ( P < 0.05). The levels of Mg, Cr, Fe, Cu, Zn, Se, Sr, and Ba were correlated with the number of CTCs ( P < 0.05). Specific TE patterns in whole blood may assist in the early diagnosis of CRC. The combined determination of TE levels and CTCs may be useful as an adjunct to staging and guiding treatments.
研究领域:
医学
·
肿瘤学
·
临床检验
✓ 已验证
产品关联
DOI
PubMed
高影响因子
Scientific Reports
·
2021
·Vol. 11
·期 1
·1-9
·
IF 4.38
Huang Xiao-Ping,Lei Lei,Lei Shun-Xin,Zhu Wei-Wei,Yan Jun
Siraitia grosvenorii (LHG) is widely used as a medicinal and edible material around the world. The objective of this study was to develop an effective method for the authentication of the geographical origin of LHG in its main producing area Guangxi, China, which is identified as Chinese Protected Designation of Origin product, against other producing regions in China. The content of 14 elements (K, Na, Ca, P, Mg, Al, B, Ba, Cu, Fe, Mn, Ni, Zn, and Sr) of 114 LHG samples was determined by inductively coupled plasma optical emission spectrometry. Multivariate analysis was then performed to classify the geographical origin of LHG samples. The contents of multielement display an obvious trend of clustering according to the geographical origin of LHG samples based on radar plot and principal component analysis. Finally, three supervised statistical techniques, including linear discriminant analysis (LDA), k -nearest neighbours (k-NN), and support vector machine (SVM), were applied to develop classification models. Finally, 40 unknown LHG samples were used to evaluate the predictive ability of model and discrimination rate of 100%, 97.5% and 100% were obtained for LDA, k -NN, and SVM, respectively. This study indicated that it is feasible to attribute unknown LHG samples to its geographical origin based on its multielement content coupled with chemometric techniques.
研究领域:
植物学
·
食品科学
·
分析化学
✓ 已验证
DOI
高影响因子
危险品化学品经营许可证（带存储）