Five higher chlorinated benzenes (including hexachlorobenzene (HCB), pentachlorobenzene (PeCB) and three isomers of tetrachlorobenzens) were measured in the livers of grass carp and common carp collected from five markets in Xinxiang city, China. HCB and PeCB were detected in all samples. The major component of the higher CBs residue was HCB and significant correlations existed between HCB and PeCB in both grass carp and common carp livers. The ratio range of HCB/PeCB in grass carp and common carp were 3.4–6.2 and 4.9–7.7, respectively, which implied the sources of higher CBs originate mainly from the revolatilization of industrial HCB with a minor impact from PeCB.
Li Yongfang,Yang Zhongzhi,Kong Xiaoduo,He Guangjie
As facile “environmental media”, the outdoor dust may reflect the changes of contaminants in environment more promptly. In the present study, selected organochlorine contaminants (OCs) include hexachlorocyclohexanes (HCHs), dichlorodiphenyltrichloroethanes (DDTs), hexachlorobenzene (HCB), and pentachlorobenzene (PeCB) were detected in 20 outdoor dust samples collected from Xinxiang City. The concentrations of ΣHCHs, ΣDDTs, HCB, and PeCB in dust were in the range of 0.18–5.05 ng/g dry weight, 0.44–13.50 ng/g dry weight, 0.13–51.61 ng/g dry weight and ND-0.74 ng/g dry weight, respectively. Long-range transport, historical use, and recent impact of impure pesticides might be the main sources of OCs in the outdoor dust. The results of this study indicated that impure pesticide application maybe an important source of DDTs and HCB in the environment.
Yang Zhong-Zhi,Li Yong-Fang,Li Zhi-Chun,Gu Yu-Mei,Zhu Ya,Zhang Zhan-Jun
Five higher Chlorinated Benzenes (CBs), include Hexachlorobenzene (HCB), pentachlorobenzene (PeCB) and three isomers of tetrachlorobenzens, were analyzed in 20 outdoor dust samples collected from a fast developing city, Xinxiang. Only HCB was detected in all outdoor dust samples. The dominate part of the CBs residue in most samples was HCB and the mean HCB concentration (4.13 ng/g dry weight) in this study was in the range of global background soil HCB levels (ranging from 0.010 to 5.20 ng/g dry weight). The higher ratios of HCB/PeCB in the outdoor dust samples in the present study indicate that pesticide application may be an important source of HCB in China.