SEPARATION SCIENCE AND TECHNOLOGY
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2016
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IF 1.083
Shengji Xia,Yukun Wan,Nana Li,Yu Zhao
Despite the great advance in nano-filtration (NF) process development in various applications, its performance in water treatment is still impeded by the undesired fouling phenomenon, which is not yet fully understood nowadays. In this study, a comprehensive investigation on the fouling behavior, more specifically the combined fouling behavior with the presence of more than one type of foulant was carried out under various solution chemistries and feed hydraulic pressures. The interaction between the model organic foulant (alginate) and inorganic foulant (silica colloid) was systematically studied with nano-filtration membranes, with a more severe fouling observed in the combined fouling than individual foulants. However, the results also revealed that the commonly observed synergistic effect of combined fouling in the forward osmosis process was not present in the nano-filtration process. In addition, the solution chemistries (pH and calcium ions) and feed hydraulic pressure were also found to have certain influence on the combined fouling, especially the feed hydraulic pressure which exhibited a more pronounced impact on the flux decline than the other factors, thus in turn, affecting more on the reversibility of the membrane fouling.
研究领域:
环境科学
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化学工程
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水处理技术
✓ 已验证
DOI
高影响因子
CHEMOSPHERE
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2024
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IF 8.1
Vahid Vatanpour,Seyed Ali Naziri Mehrabani,Ahmad Dehqan,Samira Arefi-Oskoui,Yasin Orooji,Alireza Khataee,Ismail Koyuncu
In this work, the hydrophobic polyethersulfone (PES) membrane was modified by incorporating Ti 3 AlCN MAX phase. Synthesis of Ti 3 AlCN MAX phase was performed using the reactive sintering method. The scanning electron microscopy (SEM) images showed a 3D compressed layered morphology for the synthesized MAX phase. The Ti 3 AlCN MAX phase was added to the casting solution, and the mixed-matrix membranes were fabricated by the non-solvent induced phase inversion method. The performance and antifouling features of bare and modified membranes were explored by pure water flux, flux recovery ratio ( FRR), and fouling resistance parameters. Through the modification of membranes by introducing the Ti 3 AlCN MAX phase, the enhancement of these features was observed, in which the membrane containing 1 wt% of MAX phase showed 17.7 L/m 2 .h.bar of permeability and 98.6% for FRR . Also, the separation efficiency of all membranes was evaluated by rejecting organic and inorganic pollutants. The Ti 3 AlCN MAX membranes could reject 96%, 95%, and 88% of reactive blue 50, Rose Bengal, and azithromycin antibiotics, respectively, as well as 98%, 80%, 86%, and 36% of Pb 2+ , As 5+ , Na 2 SO 4, and NaCl, respectively. Finally, the outcomes indicated the Ti 3 AlCN MAX phase was an excellent and efficient novel additive for modifying the PES membrane.
研究领域:
环境科学
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材料科学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
FUEL
·
2021
·
IF 6.609
Hongliang Qian,Donghang Yin,Beichen Qin,Licheng Li,Jiahua Zhu,Liwen Mu,Caolong Li,Bin Dong,Dechun Huang,Xiaohua Lu
Biogas-residue-based mesoporous carbons with high adsorption capacity have been successfully synthesized via a facile template-free and one-step approach by sodium amide activation and applied in the removal of organic and inorganic pollutants in wastewater for the first time in this study. A “waste” and widely available resource, biogas residue, was utilized as carbon precursor. Different mesoporous carbons were prepared by direct co-milling and activation at various conditions, among which largest surface area of 1278 m 2 /g and maximum adsorption of 556 mg/g on methylene blue were achieved, respectively. It is also verified to possess superior adsorption capacity on typical organic pollutant phenanthrene (112 mg/g) and typical inorganic pollutant N/P element (N, 113 mg/g; P, 12 mg/g). The results show that the prepared mesoporous carbons possess high and universal adsorption performance toward both organic and inorganic pollutants in wastewater. Finally, the adsorption mechanism such as the relationship between the adsorption capacities and characterization results was also discussed. The low-valued raw materials, convenient procedure, energy conservation, minimum pollution and corrosion, high adsorption capacity show feasible manufacture in industry.
研究领域:
环境科学
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材料科学
✓ 已验证
产品关联
DOI
高影响因子
CHEMICAL ENGINEERING JOURNAL
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2022
·
IF 16.744
Yanlong Wang,Jiang Xu,Kun Yang,Daohui Lin
Water scarcity is one of the most pressing global challenges and limits economic and social development. Multiple processes of current technologies for water purification are needed to meet water quality objectives due to their contaminant-specific removal capability. Here, we developed Fe 0 @SiO 2 @CaO 2 nanocomposite with three layers of core–shell structure that could achieve an array of water contaminants removal by oxidation, reduction, and flocculation. >99 % of 50 mg/L tetracycline, 20 mg/L pentachlorophenol, 450 mg/L Cd(Ⅱ), 20 mg/L Cr(Ⅵ), or 80 mg/L P (in form of PO 4 3− ) was removed by 2 g/L Fe 0 @SiO 2 @CaO 2 in 24 h. Moreover, Fe 0 @SiO 2 @CaO 2 (2 g/L) showed an excellent performance in turbidity removal (239 mg/L kaolinite suspension, removal rate > 99 %) and water decolorization (50 mg/L humic acid, removal rate > 93 %). Cd(II) and Cr(VI) could be reduced to Cd(0) and Cr(III), respectively, through electronic reduction reactions using Fe 0 and •H, which is formed during the reaction Fe 0 + 2H + →2•H + Fe 2+ ; Cd(Ⅱ) and the formed Cr(III) could coprecipitate with the formed orthosilicic acid and OH − . The removal of P was mainly resulted from the coordination with released Ca 2+ and iron compounds. Charge neutralization by nanocomposite and coagulation with the products from nanocomposite transformation were responsible for the kaolinite removal. Reduction by •H and Fe 0 , oxidation by •OH derived from the Fenton reaction, and/or coagulation accounted for the organic contaminant removal. This work provides a novel material that can be used to simultaneously remove a range of contaminants in wastewater treatment.
研究领域:
环境科学
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材料科学
✓ 已验证
产品关联
DOI
高影响因子
MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING
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2016
·
IF 2.264
Jin Liu,Wei Lu,Hongzhang Wu,Lin Jin,Bin Hu,Lili Li,Zhenling Wang
Rice-like HT-ZnGa 2 O 4 were successfully synthesized by using commercially available Ga 2 O 3 as an in situ sacrificial templates. The composition, morphology and microstructure of rice-like HT-ZnGa 2 O 4 were characterized in detail. Rice-like HT-ZnGa 2 O 4 were found to be composed of hundreds of nanoparticles . The pH-dependent experiment results indicated that the dispersive rice-like HT-ZnGa 2 O 4 was obtained at pH 8.0. The photocatalytic degradation results showed that the rice-like HT-ZnGa 2 O 4 exhibited high photocatalytic activity and excellent stability for the photocatalytic removal of organic and inorganic pollutants in solution. Finally, the mechanism involved in the photocatalytic process have been investigated by theory and experiment analyses.
研究领域:
材料科学
·
环境科学
✓ 已验证
DOI
高影响因子
SEPARATION AND PURIFICATION TECHNOLOGY
·
2022
·
IF 9.136
Libing Zheng,Min Tang,Yize Wang,Deyin Hou,Xiaoyu Li,Jun Wang
In this study, a novel Janus membrane was developed by constructing Cu-1,3,5-benzenetricarboxylic acid (Cu-BTC) metal–organic frameworks (MOFs) hydrophilic coating on polyvinylidene fluoride (PVDF) membrane. The Cu-BTC@PVA/PVDF Janus membrane showed a rougher surface with an in-air water contact angle of 27.4˚ and an underwater oil contact angle of 152.8°. The Cu-BTC had minimal impact on mass transfer efficiency in MD process, and the Janus membrane exhibited excellent anti-oil-fouling and anti-NOM-fouling properties. The formation of the hydration layer, the slip boundary effect, and the electrostatic repulsion by the hydrophilic serrated interface were the main antifouling mechanisms. The hydrophobic-hydrophobic interaction was the main fouling mechanism of PVDF membrane for both oil and NOM. Sodium alginate (SA) displayed severe fouling with a compacted fouling layer in PVDF membrane due to the concentration polarization (CP) and gel layer formation. Inorganic fouling was the predominant fouling for the high CP and inorganic–organic coupling. While humic acid (HA) surpassed SA in Cu-BTC@PVA/PVDF Janus membrane for the stronger hydrogen bond, hydrophobic-hydrophobic interaction was significantly alleviated. Inorganic fouling was also significantly alleviated due to the strong electrostatic repulsion effect. The prepared Janus membrane has great potential to promote MD dealing with hypersaline industrial wastewaters containing complex organic matters.
研究领域:
材料科学
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环境工程
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膜技术
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水处理
✓ 已验证
DOI
高影响因子
CHEMICAL ENGINEERING JOURNAL
·
2024
·
IF 13.3
Yanli Li,Mei Chen,Xinyi Sun,Minliang Zhang,Jinning Wang,Daqian Jiang,Ruobin Dai,Junjian Zheng,Xin Wang
Fouling, particularly biofouling caused by microbial adhesion and subsequent biofilm formation, limits the widespread applications of membrane-based technologies. Although integrating contact-killing agents ( i.e., quaternary ammonium compounds, QACs) to fabricate antibiofouling membranes has been proven as an effective approach to mitigate this issue, the long-term effectiveness of the modified membranes after foulants covering remains a challenge. Herein, hydrophilic photocatalyst nanosheet g-C 3 N 4 (NCN) was introduced into QAC-modified ultrafiltration (UF) membranes to address this limitation. Results showed that the hydrophilic surface of NCN can improve the antiadhesion properties of hydrophobic QAC modified membranes. Moreover, NCN can degrade organic and inorganic pollutants on QAC modified membrane surface under visible light, thereby restoring the antibacterial ability of QAC. Furthermore, the composite QAC/NCN modified membrane demonstrated long-term stability with sustained remarkable antibacterial performance even after numerous fouling-chemical cleaning cycles. These findings underscore the efficacy of the synergistic integration of contact-killing bactericidal activity and photocatalysis as a versatile and promising solution for combating biofouling, thereby contributing to the advancement of membrane technology in environmental remediation applications.
研究领域:
环境工程
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膜技术
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光催化
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抗生物污染
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水处理
✓ 已验证
产品关联
DOI
高影响因子
危险品化学品经营许可证（带存储）