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Journal of Chemistry · 2010 ·Vol. 9 ·期 1 ·435-442 · IF 0

Polymeric Organo-Silane Coatings for Aluminum Alloy Corrosion Protection by Self-Assembled Metho

Yabin Wang,Yanni Li,Fang Wang

The protective performances of coating formed by organo-silane with a linear alkyl chain for promoting aluminum alloy corrosion protection were evaluated by electrochemical techniques. The coatings were self-assembled in the hydrolyzed hydroalcoholic bath of n -octyltriethoxysilane (OS) and cured at hot air oven by different time. The coatings prepared by the less self-assembled number and shorter cured time, were always porous and scarcely protective. On the contrary, those built by the more self-assembled number and the longer cured time had higher coverage on aluminum surface and favorable corrosion resistant property. The best results were obtained when n -octyltri-ethoxysilane (OS) was hydrolyzed 25 h, self-assembling of OS was conducted for five times and the multi-layers were cured at 120 for 1∼2 hours. In this case, the thicker, high cross-linked and more scarcely defective layer was formed on aluminum alloy surface.

研究领域: 材料科学 · 表面工程 · 腐蚀与防护 · 高分子化学 · 电化学
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