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CERAMICS INTERNATIONAL · 2016 ·Vol. 43 ·期 3 ·2969-2973 · IF 2.758

Mechanical force-driven growth of elongated BaTiO3 lead-free ferroelectric nanowires

Bing Xie,Haibo Zhang,Hao Kan,Sisi Liu,Ming-Yu Li,Zeyu Li,Shuai Zhu,Shiyong Qiu,Shenglin Jiang

This work demonstrates a highly efficient method for large-scale synthesis of elongated BaTiO 3 nanowires via a novel stirring hydrothermal process. Compared with conventional hydrothermal reaction , one-dimensional (1D) lead-free BaTiO 3 nanowires can be realized at an even lower temperature with a shorter dwelling time. Results suggest that the mechanical force-driven stirring process improved the diffusion and surface reaction rate of BaTiO 3 nanocrystal growth in the solution phase, apparently, leading to the growth of the BaTiO 3 nanowires via an oriented attachment mechanism. Meanwhile, to the best of our knowledge, this method is also the first reported protocol which is capable to grow elongated BaTiO 3 nanowires with length up to tens of micrometers. This research outcome provides a promising option for low cost, high-throughput fabrication of 1D nanostructure in respect of mass-manufacturing.

研究领域: 材料科学 · 纳米科技 · 无机合成 · 功能材料 · 铁电材料
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