CHEMICAL ENGINEERING JOURNAL
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2024
·
IF 13.3
Qi-Hua Yang,Gui-Hua Li,Yu-Chen Ao,Shu-Juan Zhao,Han-Qi Wei,Le Fu,Zhi-Wei Luo,Tian-Liang Zhou,Chu-Jie Wang,Ge-Mei Cai
As a new generation of environmentally friendly halide materials, Cs 3 Cu 2 I 5 shows up the promising application in scintillation, LED, and photoelectric detection fields. However, liquid phase methods cannot produce Cs 3 Cu 2 I 5 on a large scale, and the preparation process is accompanied by serious pollution. Although the ball milling method can solve the problems caused by the liquid phase synthesis method, the Cs 3 Cu 2 I 5 obtained has many surface defects and low luminescence efficiency. In this work, a strategy of doping-assisted ball-milling synthesis using ZnI 2 is proposed. Similar to the chemical preparation of Cs 3 Cu 2 I 5 , the iodine-rich environment during the modified ball milling process can also play a role in repairing surface defects. And it has been demonstrated through experiments and first principles calculations that the distortion of [Cu 2 I 5 ] 3- under ground/excited state can be adjusted through doping Zn into the Cu1 site, the formation barrier of self-trapped excitons is reduced, and the luminous efficiency of Cs 3 Cu 2 I 5 is significantly improved. Subsequently, using the simple hot-pressing method, the representative Cs 3 Cu 2 I 5 :1.0Zn sample was combined with commercially available polypropylene to fabricate Cs 3 Cu 2 I 5 :1.0Zn@PP film. Finally, the potential applications of the newly-developed film in portable and customizable WLED and scintillation fields were explored.
研究领域:
材料科学
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光学
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环境科学
✓ 已验证
产品关联
DOI
高影响因子
RSC Advances
·
2016
·Vol. 6
·期 80
·76867-76873
·
IF 3.289
Yunfei Zhang,Bo Yang,Jinhong Fan,Luming Ma
In this study, abrasives-reinforced metal matrix composites (MMCs) with a microscale size synthesized by ball milling (BM) could achieve highly active and stable dechlorination efficiency for aqueous 2-chlorophenol (2-CP). The preparation process of this composite via BM was optimized to obtain a high degradation efficiency, especially for the effect of the abrasives including B4C, SiC, α-Al2O3, SiO2, Fe3O4 and Na2SO4. The results showed that the hardness of the abrasives in the Fe-based MMCs was closely related with their dechlorination performance. Subsequently, the optimal abrasive, i.e. SiO2 was further investigated for its proper milling conditions with zero-valent iron (ZVI) particles including optimal SiO2 size, SiO2 loading, milling time, and the dosage of the process control agent (PCA). Additionally, the influence of other metal categories including Al and Si was also investigated for dechlorination; and their low reaction efficiencies were closely related with their passivating film. Finally, the longevity test suggested that the decreased reactivity of the SiO2–Fe MMC during the storage in air could be recovered when consecutively used, mainly due to the promoting effects of the inherent structure of SiO2–Fe MMC with the Fe/C and Fe/SiO2 interfaces, as well as the effective regeneration of the reactive sites by continuous iron dissolution.
研究领域:
环境科学
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材料科学
✓ 已验证
产品关联
DOI
高影响因子
CRYSTENGCOMM
·
2025
·
IF 2.6
Siyu Li,Jiali Yao,Dayang Wang,Keke Huang,Wensheng Yang,Renguo Xie
Metal halides (MHs), specifically CsPbX3 (where X = Cl and Br), have garnered significant research interest due to excellent optoelectronic properties. However, most of these metal halides exhibit no red emission in the visible region. In this study, Cs2ZnCl4 powders in the presence of hydrochloric acid were synthesized through mechanical milling. X-ray diffraction (XRD) analyses revealed no detectable diffraction signals before or after acid treatment, suggesting a uniform crystal structure. The initial Cs2ZnCl4 powders displayed intrinsic blue emission centered at 486 nm, with a Photoluminescence Quantum Yield (PLQY) of approximately 5.07%. In contrast, the hydrochloric acid-treated Cs2ZnCl4 powder exhibited bright red emission centered at 645 nm, with a PLQY of about 12.78%. The broad emission, characterized by a full width at half maximum (FWHM) of 135 nm, was attributed to self-trapped exciton (STE) emission. X-ray photoelectron spectroscopy (XPS) analysis of Cs2ZnCl4 before and after acid treatment suggests that hydrochloric acid introduction may have induced distortions or defects in the coordination environment of Zn2+ ions. This provides a valuable route for further investigation into the optical properties of other metal halides.
研究领域:
材料科学
·
光学
✓ 已验证
产品关联
DOI
高影响因子
INORGANIC CHEMISTRY
·
2025
·
IF 4.7
Yong Song,Wenjia Hao,Jinsong Li,Bo Jin,Rufang Peng
Hierarchical porous metal–organic frameworks (HP-MOFs) have attracted considerable attention because of their hierarchical pores, which can address the slow mass transfer and less exposure of active sites in pristine microporous MOFs. Although several preparation methods have been developed to date, a large-scale technique for the synthesis of HP-MOFs is still lacking. In this study, we report a novel method for the large-scale synthesis of HP-HKUST-1 based on liquid-assisted spiral gas–solid two-phase flow (LA-S-GSF). This method ingeniously uses a nebulizer to promote the rapid synthesis of nano-HKUST-1 by introducing trace amounts of water during the S-GSF reaction. During the washing and drying process, these nanoparticles were fully fused to form nanocrystalline aggregates, resulting in a hierarchical porous structure with a large number of micropores, mesopores, and macropores. The pore size distribution can be regulated by changing the drying temperature to obtain HP products with combinations of micropores and mesopores, micropores and macropores, and the formation mechanism of the HP structure was also explored. This method required only 11 min of reaction time to obtain 25.2 g of HP-HKUST-1 in 96% yield, with a corresponding space-time yield (STY) of 6.9 × 104 kg m–3 day–1.
研究领域:
材料科学
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化学工程
✓ 已验证
产品关联
DOI
PubMed
高影响因子
JOURNAL OF ALLOYS AND COMPOUNDS
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2019
·
IF 4.175
Qian Liu
Although Mn-doped lead halide perovskites could alleviate the environmental burden of Pb, their synthesis process suffers from intricate operations, high operating temperature, low production, or toxic strong polar solvents. Developing a simple and green route for Mn-doped halide perovskites with mass production is highly desirable for perovskite-derived applications. In this work, we developed a facile and environmental-benign synthesis strategy for large-scale preparation of Mn-doped lead halide perovskite nanocrystals . The nanocrystals were prepared via a mechano-synthesis process without organic solvents . We investigated the influence of atomic composition on their morphology, crystal structure and optical performance. Our results show that the perovskite nanocrystals have dual-emissions from the 4 T 1 to 6 A 1 transition of Mn 2+ and the excitonic recombination of perovskite hosts, respectively. The achieved Mn:CsPbX 3 nanocrystals show well-tailored color rendering when used as LED phosphors. This work presents a scalable and facile strategy for Mn-doped perovskite production without organic solvents, which promises low-cost and eco-friendly LEDs.
研究领域:
材料科学
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纳米技术
·
化学
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光电技术
✓ 已验证
产品关联
DOI
高影响因子
危险品化学品经营许可证（带存储）