Deep ultraviolet (UV) mechanoluminescence (ML) materials hold broad application prospects in bright-field visualization detection, solid-blind imaging, and information storage due to their shorter emission wavelengths. However, current research on deep UV ML materials primarily focuses on trap control to suppress their reuse. Here, we enhance the deep UV ML of Gd 3+ ions by constructing a 4f-5d coupling between Pr 3+ ions and the 6 P 7/2 energy level of Gd 3+ ions in the wide-bandgap Lu 3 Al 2 Ga 3 O 12 with a garnet structure. The results suggest that the deep UV ML in Lu 3 Al 2 Ga 3 O 12 : Pr 3+ , Gd 3+ is trap-independent, and its self-recovery property originates from the continuous triboelectric charge transfer between polydimethylsiloxane and the ML particles. Sterilization experiments using deep UV ML against pathogenic E. coli highlight the potential of deep UV ML materials for continuous sterilization applications.
Yi Zhang,Shao Yan,Fang Xiao,Xihui Shan,Xulong Lv,Weili Wang,Yanjie Liang
With the occurrence of global health events such as COVID-19, the development of high-performance ultraviolet-C (UVC) light sources for efficient and convenient sterilization applications holds promising scientific and engineering prospects. However, discovering reliable and stable luminescent materials capable of converting incident excitation energy to UVC radiation remains a challenge. Herein, we report a new Sr2P2O7:Pr3+ phosphor that exhibits exceptional capabilities in X-ray energy absorption, storage, UVC-light conversion, and persistent UVC light emission. Specifically, minutes of X-ray excitation can result in more than 24 h of continuous UVC persistent luminescence when monitored at 222 nm emission, realizing far-UVC afterglow for the first time. Intense UVC persistent light emission could be detected by a UVC corona camera in bright indoor and outdoor environments without interference from artificial light or natural sunlight, in consideration of the avoidance of the spectral overlap with ambient light. The self-sustained UVC persistent luminescence form was demonstrated as an optical-conversion strategy for sterilization application, whereby the charged Sr2P2O7:Pr3+ persistent phosphor could effectively inactivate infectious methicillin-resistant Staphylococcus aureus (MRSA) within 30 min in an excitation-free manner, offering new insights into developing UVC light sources for sterilization applications. This work expands the field of UV persistent luminescence research to the far-UVC spectral region and is expected to bring new and power-free solutions to some important applications where far-UVC light is needed, such as sterilization and photodynamic therapy.
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