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JOURNAL OF LUMINESCENCE · 2017 · IF 2.686

Low temperature synthesis of CsPbI3 sub-micrometer wires with tailored emission band for flexible X-ray phosphors applications

Junqian Zhao,Huaina Yu,Shusheng Pan,Shang Zhou,Li Zhong,Hua Wang,Yuan Yuan Luo,SiuFung Yu,Guanghai Li

CsPbI 3 sub-micrometer wires were synthesized by one-pot solution method at near room temperature . The wires are single crystalline with [100] orientation. An strong emission band centered at 470   nm was observed under ultraviolet excitation, and the emission intensity and bandwidth are dependent on the molar ratio of CsI/PbI 2 in the wires. A bright green emission with a lifetime of several tens ns was observed when excited with a soft X-ray, and the spectral response range can be modulated by the molar ratio of CsI/PbI 2 in the wires. The growth mechanism of the wires was discussed, and the influences of the cycling strain and X-ray irrigation time on the X-ray excited optical luminescence of the CsI/PbI 2 wires/PET film were analyzed and discussed.

研究领域: 材料科学 · 光学
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ACS Applied Materials & Interfaces · 2025 · IF 8.2

Designing High-Damping, Optically Clear Ionogels through Competitive Binding for Flexible and Impact-Resistant Applications

Xiaoyu Huang,Luofei Li,Haoqi Zhu,Tiancheng Lv,Lei Tang,Zhexian Shentu,Haoyue Li,Tian Gao,Kai Zhang,Juntao Hu,Wei Wang,Bin Xue,Hai Lei,Yi Cao

Developing damping materials that are both optically transparent and mechanically robust, while offering broad frequency damping capacity, is a significant challenge─particularly for devices that require protection without compromising visual clarity. Conventional methods often either fail to maintain transparency or involve complex designs that are difficult to implement. Here, we present an ionogel system that integrates a physically cross-linked elastic copolymer network with a viscous ionic liquid. The competitive interactions between the ionic liquid and the polymer network enable fine-tuning of the mechanical stability and damping capacity. The resulting ionogel is transparent and mechanically robust and exhibits excellent damping over a wide frequency range. Remarkably, a thin layer (0.15 mm) absorbs nearly 60% of the impact force and retains its performance after exposure to extreme conditions. This approach offers a straightforward method for designing advanced damping materials that meet both the aesthetic and functional demands of modern technologies.

研究领域: 材料科学 · 化学工程
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CHEMICAL ENGINEERING JOURNAL · 2025 · IF 13.2

Flexible chemical removing dissolved oxygen from water by nano-palladium hybrid microgel filled membrane

Tangxin Zhang,Hao Zhang,Tiantian Zhu,Yuhua Mao,Jiayuan Wang,Lingyu Zhu,Jianli Wang

In de-oxygen water preparation, it is still a challenge to develop a highly efficient catalyst with less pollution on produced water. Herein, we invented a novel catalytic membrane, in which palladium nanoparticles were well dispersed and exposed sufficiently to the fluid with the help of hydrophilic polymer networks. These catalytic membranes created by dynamic filtration and reversible fixation offer exceptional flexibility in preparation and application. An apparatus for flexible and continuous chemical removal of dissolved oxygen from water was built up and applied to determine the performance of catalytic membranes. When the residence time was 32.3 s, the concentration of DO could be reduced to 10 ppb by a tri-layer catalytic membrane at ambient temperature. This uniquely configured catalytic membrane could be applied in portable and flexible DO requirements, such as experimental setups and pretreatment of instruments.

研究领域: 材料科学 · 环境工程 · 化学工程
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CHEMICAL ENGINEERING JOURNAL · 2021 · IF 13.273

Oil-water self-assembly engineering of Prussian blue/quantum dots decorated graphene film for wearable textile biosensors and photoelectronic unit

Junlin Ma,Yu Jiang,Liuxue Shen,Hongting Ma,Tongrui Sun,Fengjuan Lv,Yuefeng Liu,Junshan Liu,Nan Zhu

Integrating functional components into graphene film is crucial for taking full advantage of graphene and manufacturing film-based devices. However, most graphene film-based system acts specialized property with complicated fabricated process, limiting further application. Herein, a highly compatible graphene nanofilm, decorated by electroactive Prussian blue (PB) and photoelectric responsive quantum dots (QDs), has been prepared via a simple and effective oil-water (O/W) self-assembly engineering. Interestingly, this graphene film could be transferred on various substrates for flexible application. As a result, PB and QDs have played a synergic effect with reduced graphene oxide (rGO) matrix, respectively, acquiring both excellent electrochemical sensing behaviors and extremely enhanced photocurrent generation compared with pure QDs film under simulated solar light. Furthermore, impressive biosensing performance has been obtained by enzyme-modified PB-rGO-QDs film. Additionally, proposed film-based wearable textile H 2 O 2 sensor possesses high sensitivity of 53.8 µA mM −1  cm −2 , while developed wearable glucose biosensor exhibits good performance, with a sensitivity of 37.24 µA mM −1  cm −2 . Significantly, wearable devices of PB-rGO-QDs films on textile have established flexible bending lifetime over thousands of cycles, accompanying with stable sensor and photoelectronic properties. Prospectively, PB-rGO-QDs films would provide an efficient strategy of multi-components self-assembly for broadening the application of graphene and developing wearable biosensing/photoelectronic devices.

研究领域: 材料科学 · 生物医学工程 · 传感器技术
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