Orange LED and cell fluorescence imaging of Mn2+ doped CsPbCl3 water-soluble nanocrystals with improved stability and optimized luminescence
Water-soluble Mn 2+ doped CsPbCl 3 nanocrystals coating by 6-aminocaproic acid (ACA) ligand were prepared by a simple ligand assisted reprecipitation method at room temperature. The CsPbCl 3 :Mn 2+ /ACA nanocrystals were almost cubic phase and had mean size of about 10 nm. Due to the coating and passivation of ACA, the CsPbCl 3 :Mn 2+ /ACA nanocrystals retained the initial fluorescence intensity of 20% after being dispersed in deionized water for 20 days. The orange LED device based on CsPbCl 3 :Mn 2+ /ACA nanocrystals were prepared with excellent luminescence properties. In the cytotoxicity test, even if the MCF-7 cells were cultured for 24 h at the concentration of CsPbCl 3 :Mn 2+ /ACA nanocrystals as high as 160 μg·ml −1 , the cell survival rate was still 70%. Confocal fluorescent cell imaging results showed that the nanocrystals had remarkable fluorescent cell imaging effect even after 24 h. The synthesized CsPbCl 3 :Mn 2+ /ACA nanocrystals have nice water solubility, good water stability, low cytotoxicity and highly luminescence properties, and have great application potential in the field of orange LED and fluorescent probes .
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