Double-layered hydrogels based on phase change material and pen ink for continuous and efficient solar-driven seawater desalination
A novel double-layered hydrogel based on the polyacrylamide matrix, pen ink, and phase-change microcapsules was developed to construct a hydrogel-based evaporator for efficient and continuous seawater desalination . The n -eicosane (core)@crystalline TiO 2 (shell) phase-change microcapsules were fabricated through interfacial polycondensation , and the resulting phase-change microcapsules obtained a considerably high latent-heat capacity of 187 J·g −1 . The upper layer of the hydrogel exhibits a high solar absorptivity of over 90 % due to the introduction of pen ink as a solar absorber, which helps the hydrogel-based evaporator to gain an excellent photothermal energy conversion capability. A high evaporation efficiency of 93.89 % was obtained for the developed hydrogel-based evaporator along with a high evaporation rate of 1.85 kg·m −2 ·h −1 under one-sun illumination. The phase-change microcapsules dispersed in the lower layer of the hydrogel can act as a latent heat-storage unit to store a great quantity of photothermal energy through melting phase change by the phase change material core. This imparts a consecutive evaporation capability to the developed hydrogel-based evaporator. As a result, its water production was increased by 11 % under 50-min one-sun illumination and 50-min non-illumination.
危险品化学品经营许可证（带存储）