BIORESOURCE TECHNOLOGY
·
2024
·
IF 9.7
Yingying Feng,Thomas L. Eberhardt,Fanyang Meng,Chen Xu,Hui Pan
Applications of deep eutectic solvent (DES) systems to separate lignocellulosic components are of interest to develop environmentally friendly processes and achieve efficient utilization of biomass. To enhance the performance of a binary neutral DES (glycerol:guanidine hydrochloride), various Lewis acids (e.g., AlCl 3 ·6H 2 O, FeCl 3 ·6H 2 O, etc.) were introduced to synthesize a series of ternary DES systems; these were coupled with microwave heating and applied to moso bamboo. Among the ternary DES systems evaluated, the FeCl 3 -based DES effectively removed lignin (81.17%) and xylan (85.42%), significantly improving enzymatic digestibility of the residual glucan and xylan (90.15% and 99.51%, respectively). Furthermore, 50.74% of the lignin, with high purity and a well-preserved structure, was recovered. A recyclability experiment showed that the pretreatment performance of the FeCl 3 -based DES was still basically maintained after five cycles. Overall, the microwave-assisted ternary DES pretreatment approach proposed in this study appears to be a promising option for sustainable biorefinery operations.
研究领域:
生物化学
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可再生资源工程
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产品关联
DOI
PubMed
高影响因子
BIORESOURCE TECHNOLOGY
·
2023
·
IF 11.4
Meixin Wang,Yawei Zhan,Jiayue Zhao,Zhiqiang Li
Bamboo and its mechanical processing residues have broad prospects for high value-added utilization. In this research, p-toluenesulfonic acid was used for the pretreatment of bamboo to investigate the effects of extraction and depolymerization of hemicellulose. The response and behavior of changes of cell-wall chemical components were investigated after different solvent concentration, time, and temperature pretreatment. Results indicated that the maximum extraction yield of hemicellulose was 95.16 % with 5 % p-toluenesulfonic acid at 140 °C for 30 min. The depolymerized components of hemicellulose in the filtrate were mainly xylose and xylooligosaccharide, with xylobiose accounting for 30.77 %. The extraction of xylose from the filtrate reached a maximum of 90.16 % with 5 % p-toluenesulfonic acid at 150 °C for 30 min pretreatment. This research provided a potential strategy for the industrial production of xylose and xylooligosaccharide from bamboo and for the future conversion and utilization.
研究领域:
生物质利用
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化学工程
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材料科学
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产品关联
DOI
PubMed
高影响因子
Foods
·
2023
·Vol. 12
·期 9
·1758
·
IF 5.2
Xubo Huang,Yalan Zhang,Na Xie,Junwen Cheng,Yanbin Wang,Shaofei Yuan,Qin Li,Rui Shi,Liang He,Min Chen
Dietary carbohydrates are unexploited in the by-products of economically valuablePhyllostachys pracecoxbamboo shoots. A residue-derived polysaccharide (PBSR1) was aqueously extracted from the processing waste of this bamboo shoot species. Its primary structure and advanced conformation were elucidated by a combined analysis of spectroscopy, chromatography, 2D nuclear magnetic resonance, laser light scattering and atomic microscopy. The results indicated PBSR1 was a triple-helix galactan consisting of →6)-β-D-Galpand →3)-β-D-Galpin linear with an 863 KD molecular weight (Mw). The relationship between the radius of gyration (Rg) and intrinsic viscosity ([η]) on Mwwere established as Rg= 1.95 × 10−2Mw0.52±0.03(nm) and [η] = 9.04 × 10−1Mw0.56±0.02(mL/g) for PBSR1 in saline solution at 25 °C, which indicated it adopted a triple-helix chain shape with a height of 1.60 ± 0.12 nm supported by a red shift of λmaxin Congo red analysis. The thermodynamic test (TG) displayed that it had excellent thermal stability for the food industry. Further, those unique structure features furnish PBSR1 on antioxidation with EC50of 0.65 mg/mL on DPPH· and an ORAC value of 329.46 ± 12.1 μmol TE/g. It also possessed pronounced immunostimulation by up-regulating pro-inflammatory signals including NO, IL-6, TNF-α and IL-1β in murine cells. Our studies provided substantial data for the high-valued application of residues and a better understanding of the structure–function relationship of polysaccharide.Keywords:Phyllostachys pracecoxbamboo shoot;valorization;polysaccharide;chain conformation;structure–function;immunomodulation
研究领域:
食品科学
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生物化学
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分子生物学
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生物技术
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DOI
PubMed
高影响因子
Carbon Letters
·
2024
·Vol. 34
·期 6
·1723-1736
·
IF 5.5
Liu Huan,Miao Yu,Tian Huayu,Chen Yishan,Wang Enfu,Huang Jingda,Zhang Wenbiao
Moso bamboo, as a kind of renewable functional material, exhibits outstanding development potential. It is promising to prepare activated carbon with good mechanical strength and high specific surface area using moso bamboo as raw material. In this work, we employed a hydraulic extruder to extrude the bamboo charcoal and the adhesive to obtain the moso bamboo activated carbon, and improved the specific surface area of the columnar activated carbon through high-temperature water vapor activation. Through the catalytic role of the water vapor activation process, the formation and expansion of the pores were promoted and the internal pores were greatly increased. The obtained columnar activated carbon shows excellent mechanical strength (93%) and high specific surface area (791.54 m 2 /g). Polyacrylamide@asphalt is one of the most effective adhesives in the high-temperature water vapor activation. The average pore size (22.99 nm) and pore volume (0.36 cm 3 /g) of the prepared columnar activated carbon showed a high mesoporous ratio (83%). Based on the excellent pore structure brought by the activation process, the adsorption capacity of iodine (1135.75 mg/g), methylene blue (230 mg/g) and carbon tetrachloride (64.03 mg/g) were greatly improved. The resultant moso bamboo columnar activated carbon with high specific surface area, excellent mechanical properties, and outstanding adsorption capacity possesses a wide range of industrial applications and environmental protection potential.
研究领域:
材料科学
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环境科学
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产品关联
DOI
高影响因子
Journal of Bioresources and Bioproducts
·
2025
·Vol. 10
·期 4
·660-675
·
IF 13
Hao Jia,Wenhui Su,Bin Huang,Xianxian He,Shaohui Fan,Zhoubin Huang,Chuanxia Pan,Chenye Liu
The fluctuations of storage temperature and humidity detrimentally affect the bamboo quality and longevity, making it crucial to investigate. Herein, we explored the physical and mechanical properties of moso bamboo ( Phyllostachys edulis ) subjected to 100-day moist heat cycling aging (MHCA-1: transitioning from low-temperature/high-humidity to high-temperature/low-humidity; MHCA-2: transitioning from low-temperature/low-humidity to high-temperature/high-humidity; CHT: 25 °C-constant temperature and 60% relative humidity) alongside a control group. Employing a multiscale characterization and Random Forest (RF) modeling, we evaluated the impacts of temperature and humidity fluctuations on the bamboo quality, and the influence mechanism of storage conditions on its physical and mechanical properties were elucidated. Results indicated that elevated temperature and humidity led to remarkable fluctuation in bamboo moisture (from −20.36% to 32.99%), weight gain (from −32.69% to 6.19%), and dimensional expansion (from −5.37% to 2.38%). Conversely, high-temperature and low-humidity drying conditions resulted in moisture loss and dimensional shrinkage. Total color difference (TCD) of bamboo cortex followed the order: MHCA-2 (7.46) < CHT (12.24) < MHCA-1 (20.10) < control (22.63). The TCD of bamboo pith positively was related with storage temperature. Periodic moist heat aging induced the permanent deformation in bamboo, reducing its elastic modulus by 30.05%–43.79%. Under moist heat aging conditions, the characteristic hemicellulose functional groups, including hydroxyl (−OH), carbonyl ( C = O ), ether (C–O–C), and aromatic C = C moieties exhibited remarkable structural modifications, i.e., peak weakening, shifting, or morphological alterations in Fourier transform infrared (FT-IR) spectra. Additionally, these conditions elevated the thermal decomposition onset temperature of cellulose while decreasing its peak intensity. Overall, the RF modeling approach demonstrated a high accuracy in predicting bamboo behavior under varying moisture-heat conditions. It improved bamboo storage and recycling by supporting sorting and grading with reliable long-term data.
研究领域:
材料科学
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林产化工
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高分子材料
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环境因素影响
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生物基材料耐久性
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产品关联
DOI
高影响因子
Food Chemistry-X
·
2022
·
IF 6.443
Yanbin Wang,Yalan Zhang,Junwen Cheng,Jiancheng Zhao,Rui Shi,Liang He,Qin Li,Yongjian Chen
The adsorption/desorption process of flavonoids obtained from bamboo shoots residues of Phyllostachys edulis (RPEFs) was established by resin screening, adsorption isotherms, adsorption kinetics and dynamic tests. Results indicated the Langmuir equation fairly fitted the isotherms data and the pseudo-second-order model accurately described its kinetic adsorption on HPD-500 resin. The optimal process was as follows: 2 mg/mL of solution, 2.8 BV feed volume under 2 BV/h flow rate for adsorption; 5 BV volume of 70 % ethanol with a flow rate of 2 BV/h for desorption. After enrichment, the flavonoids in RPEFs increased from 1.39 % to 37.34 %. The analysis of UPLC-TOF-MS/MS uncovered that the purified RPEFs were composed of four major flavonoids. It had potent hypoglycemic activity via PI3K/AKT pathway by upregulating the protein expression of PI3K, AKT, IRS-1, and GLUT4 in a dose-dependent manner based on HepG2-IR cells. Those results provide possible utilization of Phyllostachys edulis by-products in food additives.
研究领域:
食品科学
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药理学
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生物技术
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产品关联
DOI
PubMed
高影响因子
Food Chemistry-X
·
2021
·
IF 5.182
Qi Li,Weijie Wu,Hangjun Chen,Xiangjun Fang,Yanchao Han,Mingyong Xie,Haiyan Gao
The effects of Moso bamboo ( Phyllostachys edulis ) shoot polysaccharide (BSP) on the human gut microbiota composition and volatile metabolite components were investigated by in vitro fermentation. After fermentation for 48 h, BSP utilization reached 40.29% and the pH of the fermentation solution decreased from 6.89 to 4.57. Moreover, the total short-chain fatty acid concentration significantly ( P < 0.05) increased from 13.46 mM (0 h) to 43.20 mM (48 h). 16S rRNA analysis revealed several differences in the gut microbiota community structure of the BSP-treated and water-treated (control) cultures. In the BSP group, the abundance of Firmicutes , Actinobacteria , and Proteobacteria was significantly increased, while that of Bacteroidetes and Fusobacteria significantly decreased. Moreover, the concentrations of benzene, its substituted derivatives, and carbonyl compounds in the volatile metabolites of the BSP-treated group decreased, while that of organic acids significantly increased after 48 h of fermentation. These results demonstrate that BSP improves gastrointestinal health.
研究领域:
胃肠健康
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微生物学
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营养学
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食品科学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
Frontiers in Bioengineering and Biotechnology
·
2021
·
IF 5.89
Wu Yan,Zhao Wanying,Wu Xinyu,Gan Jian,Zhang Haiqiao,Cai Yijing
The moso bamboo fiber powder was used as raw material to prepare cellulose nano-fibril films, 5% of polyvinyl alcohol solution was used as a structural reinforcement agent, dopamine hydrochloride (DA) was used as a surface adhesive, and hexadecyl trimethoxy silane was used as a surface modifier. The superhydrophobic films were prepared by vacuum filtration and impregnation. The results showed that the water contact angle on the surface of the film could reach 156°. The microstructure and chemical composition of the film surface was further studied by scanning electron microscopy (SEM), Fourier transforms infrared spectroscopy (FTIR), and roughness measurement The scanning electron microscopy images showed that the nanofibers on the surface of Cellulose nanofibers film were arranged and randomly distributed, thus forming a dense network interwoven structure. In PDA hydrophobic modification solution, an Hexadecyltrimethoxysilane was hydrolyzed to a hexadecyl silanol to obtain the polar terminal hydroxyl of Hexadecyl silanol molecule. The -OCH3 terminal group of HDTMS reacted with hydroxyl/H2O to form a silanol (Si-OH) bond and further condensed to form a Si-O-Si network. In addition, due to the hydrophilicity of the surface of the nano cellulose film, a large amount of—OH was adsorbed on the surface of the nano cellulose film, resulted in the chemical connection between cetyl groups, thus realized the grafting of cetyl long-chain alkyl groups onto the fibers of the nano cellulose film.The film showed good self-cleaning and waterproof properties, which can be widely used in wet environment packaging and building.
研究领域:
材料科学
·
表面化学
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产品关联
DOI
PubMed
高影响因子
FOOD RESEARCH INTERNATIONAL
·
2021
·
IF 6.475
Dong-Yu Shen,Huan-Lu Song,Ting-Ting Zou,Su-Yan Wan,Meng-Ke Li
The leaf of moso bamboo ( Phyllostachys pubescens Mazel ) is rich in odorant compounds, which is important natural materials for the production of flavor. It also contains phenolic acids, amino acids and peptides, which is a potential source of natural bioactive compounds. The study of odor-active compounds in bamboo leaves can provide a basis for the discovery of natural flavor. The leaf, stem, and powder of moso bamboo were analyzed by gas chromatography-ion mobility spectrometry (GC-IMS). Main odor-active compounds in moso bamboo leaf were analyzed and characterized by (1) a gas chromatography olfactory mass spectrometry (GC-O-MS), (2) two-dimensional gas chromatography olfactory mass spectrometry (GC × GC-O-MS) and (3) electronic nose (E-nose). Based on aroma extract dilution analysis (AEDA), 13 key odor-active compounds with high flavor dilution (FD) factor (≥27), including 3-methyl-1-butanol, ( E )-2-hexenal, ethyl hexanoate, ( Z )-4-heptenenal, 6-methyl-5-hepten-2-one, octanal, ethyl ( Z )-3-hexenoate, 1-hexanol, ( Z )-3-hexen-1-ol, ( E, E )-2,4-heptadienal, ( Z )-2-hexen-1-ol, 1-octen-3-ol and benzaldehyde, were further analyzed. The compounds detected by the above four methods were ( E )-2-hexenal, 6-methyl-5-hepten-2-one, octanal, ( E, E )-2,4-heptadienal, 1-octen-3-ol and benzaldehyde, and all of which were the main and potential odorants of moso bamboo leaf.
研究领域:
植物学
·
分析化学
·
食品科学
·
风味化学
✓ 已验证
DOI
PubMed
高影响因子
危险品化学品经营许可证（带存储）