NEW JOURNAL OF CHEMISTRY
·
2024
·Vol. 48
·期 20
·9196-9207
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IF 2.7
Yaowei Hao,Qiaojun Nie,Xiaocao Cao,Jiafan Zheng,Kai Zhang,Jun Zheng,Haodong Wang,Yafang Zhao,Jiayi Liu,Zhiguang Lin,Ming Zhang,Zhongrong Shen
All-solid-state fluoride-ion batteries (FIBs) with a high theoretical energy density have attracted considerable attention due to their enhanced safety features and superior capacity. The selection of solid electrolyte materials with enhanced fluoride-ion conductivity is crucial for the successful implementation of high fluoride-ion energy storage in realistic scenarios. In this study, heterogeneous solid fluoride-ion electrolytes with different ratios of (LaF3)1−x(PbF2)x are investigated. In contrast to other research efforts focusing on the development of single-phase, single-lattice-defect solid-state electrolytes, the (LaF3)1−x(PbF2)x material incorporates two phases with different defects, namely fluoride vacancies and mobile fluoride ions. This unique combination of defects results in a significant enhancement in conductivity while maintaining their coexistence. The crystal gaps are filled by the orthorhombic phase, which is conductive, resulting in a reduction of the contact resistance due to the uniform distribution of the three crystal phases and the heterointerface between the hexagonal phase and the cubic phase. The multi-component electrolyte (LaF3)0.4(PbF2)0.6 exhibits the best performance among the samples tested. The electrolyte exhibits a high fluoride-ion conductivity, with a value of 2.78 × 10−4 S cm−1 at 120 °C and 6.37 × 10−6 S cm−1 at room temperature. The electronic conductivity is negligible with a value of 5.48 × 10−8 S cm−1. Furthermore, the electrolyte has an electrochemical stability window of 1.85 V vs. Sn/Sn2+. Due to its favorable electrochemical properties, this material has considerable potential as a solid-state fluoride-ion electrolyte.
研究领域:
材料科学
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电化学
·
固态离子学
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能源存储
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无机非金属材料
✓ 已验证
DOI
高影响因子
Small
·
2021
·Vol. 18
·期 5
·2104508
·
IF 13.281
Jinzhu Wang,Jipeng Hao,Chaomin Duan,Xinchao Wang,Kai Wang,Cheng Ma
Solid-state fluoride-ion batteries (FIBs) circumvent multiple formidable bottlenecks of lithium-ion batteries, but their overall performance remains inferior due to the absence of appropriate solid electrolytes. Presently the conductivity of most solid electrolytes for FIBs is too low to enable room-temperature cycling, while the few sufficiently conductive ones only allow for very low discharge voltages because of the narrow electrochemical stability window (ESW). Here, high room-temperature conductivity and a decent ESW are simultaneously achieved by designing a solid electrolyte CsPb 0.9 K 0.1 F 2.9 . Its room-temperature conductivity is 1.23 × 10 −3 S cm −1 , comparable to the most conductive system reported so far (PbSnF 4 , 5.44 × 10 −4 –1.6 × 10 −3 S cm −1 ), but the ESW is several times broader. With these appealing characteristics simultaneously achieved in the solid electrolyte, a cell with much higher voltages than other room-temperature-operable solid-state FIBs in literature is successfully constructed, and stably cycled at 25 °C for 4581 h without considerable capacity fade.
研究领域:
材料科学
·
电化学
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固态离子学
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能源存储
·
无机功能材料
✓ 已验证
DOI
高影响因子
ACS Applied Nano Materials
·
2022
·
IF 6.14
Chengyan Wang,Yangsai Lyu,Jia Li,Li Li,Tingting Li,Jie Yang,Ningning Xing,Xiaolei Zhang
Excessive fluorine can cause a serious threat to human health. It is significant but challenging to develop a straightforward and rapid way to simultaneously detect and remove excess F– from water. Herein, we presented a three-dimensional (3D) hierarchical UiO-66-NH2 nanoparticle/γ-AlO(OH) nanowire hybrid synthesized by a facile biotemplate route for simultaneous detection and removal of F– from water. We elaborately assembled two kinds of materials in a bioinspired 3D hierarchical structure as a functional unit to achieve detection and removal of dual functions. The outer UiO-66-NH2 nanoparticles served as a fluorescent sensor to detect and capture F– via a strong fluorescence enhancement effect caused by the electron transfer from F– and γ-AlO(OH) and acted as the capture unit of F–. The inner γ-AlO(OH) nanowire layer served as a F– absorbent through ion exchange between F– and γ-AlO(OH). The resulting UiO-66-NH2 nanoparticle/γ-AlO(OH) nanowire hybrid displayed excellent selectivity and sensitivity for F– detection (the detection range was 0–5 mM and the limit of detection was as low as 0.77 μM) and high capacity for F– removal (the maximum equilibrium adsorption capacity qmax was as high as 87.0 mg g–1). This dual-function material provided a strategy for simultaneously selective sensing and efficient removal of anionic pollutants from water.
研究领域:
环境科学
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材料科学
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化学
✓ 已验证
DOI
高影响因子
RSC Advances
·
2014
·Vol. 5
·期 5
·3888-3893
·
IF 3.708
Qian Tang,Hong-Mei Nie,Cheng-Bin Gong,Hua-Dong Liu,Kun Xiao
This study aimed to develop a recyclable, fluorescent, and colorimetric sensor for fluoride anion (F−) in aqueous media with fast response, good selectivity, and high sensitivity. A crosslinked polymer CpA1T5 was designed and synthesized as a sensor using (E)-1-allyl-4-((4-hydroxylphenyl)vinyl) quinolinium bromide as functional monomer, trimethylolpropane trimethacrylate as crosslinker, and azobisisobutyronitrile as initiator. When F− was introduced to the CpA1T5 suspension in deionized water, a change in color from gray to yellow and fluorescence enhancement accompanied with a redshift from 531 nm to 540 nm of fluorescence emission were immediately observed. This F− sensor can be recycled many times, making it cost efficient and beneficial to the environment. Analytical application of CpA1T5 to measure F− concentration in two commercial mouthwash samples was explored with good accuracy.
研究领域:
分析化学
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材料科学
✓ 已验证
产品关联
DOI
高影响因子
MICROCHEMICAL JOURNAL
·
2024
·
IF 4.9
Zengchen Liu,Weijie Yang,Wenping Zhu,Hongyu Chen,Yahong Chen,Ruilan Liu,Yali Cui,Yanxia Li,Baodui Wang
Fluorine is one of the essential trace elements for human body, which is essential for calcification process in living organisms. In the paper, a “off–on” fluorescence sensor for fluorine ion based on aluminium ion and boric acid codoped carbon dots was synthesized and characterized. According to fluorescence analysis, the water-soluble sensor exhibited highly selective and sensitive for fluorine ion. In sensing process, F - could bind to Al 3+ after the addition of fluorine ion, which resulted in the decomposition of Al-BA-CDs system, then intense yellow fluorescence signal appeared. Moreover, the fluorescence sensor exhibited low detecting limit (5.0 nanomolar level) by fluorescence titration spectrum. In addition, according to evaluate the fluorescence sensing properties of F - in HepG2 cell and zebra fish, this job greatly extended the use of F - sensor from aluminium ion and boric acid codoped carbon dots in organism. The work also provided an interesting idea for fabricating water-soluble fluorescence sensor for F - .
研究领域:
分析化学
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生物医学
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环境科学
✓ 已验证
产品关联
DOI
高影响因子
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
·
2018
·
IF 2.88
Xu Tang,Zhi Zhu,Renjie Liu,Liang Ni,Yue Qiu,Juan Han,Yun Wang
A novel fluorescence probe L2 based on coumarin has been designed and synthesized. The probe L2 can be used for relay recognition of metal ions Al 3+ and anion F − in the aqueous HEPES buffer (0.05 M, pH = 7.4), and build a OFF-ON-OFF detection system. The probe showed high selectivity and sensitivity to target ions in the process of relay recognition, and the corresponding detection limit could be as low as 0.014 μM (Al 3+ ) and 0.03 μM (F − ). Besides, the geometry optimizations of probe L2 and [L2 + Al 3+ ] complex were carried out using the Gaussian 16 program based on DFT, and the identification mechanism of the probe was also discussed by the mass spectrometry and theoretical calculations. Moreover, the probe has also been successfully applied to detection of target ions in living cells.
研究领域:
分析化学
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生物医学
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材料科学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
RSC Advances
·
2023
·Vol. 13
·期 43
·30176-30189
·
IF 3.9
Wei Yang,Lei Zhang,Meng Li,Ting Zhang,Yue Liu,Juan Liu
In this work, bamboo charcoal (BC) is prepared by pyrolysis of bamboo. Then, KOH modification and surface deposition of Goethite (α-FeOOH) are performed to obtain a new KOH-modified BC loaded with α-FeOOH (FKBC) adsorbent for copper (Cu2+) and fluoride (F−) ion adsorption from aqueous solution. Surface morphology and physiochemical properties of the prepared adsorbent are characterized by scanning electron microscopy-energy dispersive spectrometer, X-ray diffraction, and N2 adsorption–desorption. The effect of pH, contact time, adsorbent dosage, and initial concentration on Cu2+ and F− adsorption is also investigated. In addition, adsorption kinetics and isotherms are fitted to pseudo-second-order kinetics and Langmuir model, respectively. Thermodynamic parameters suggest that the adsorption process is spontaneous and endothermic. The adsorption mechanism is further characterized by Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy. The Cu2+ absorption mainly occurs through ion exchange, coordination reactions, and surface precipitation, while the F− adsorption mainly occurs via ion exchange and hydrogen bonding. The selective adsorption experiments reveal that FKBC has good selectivity for Cu2+ and F−. The adsorption–desorption experimental results indicate that FKBC can be reused for Cu2+ and F− adsorption after regeneration. Results indicate that FKBC can be a promising adsorbent for Cu2+ and F− removal from aqueous solutions.
研究领域:
环境科学
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材料科学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
JOURNAL OF SOLID STATE ELECTROCHEMISTRY
·
2021
·Vol. 26
·期 2
·449-456
·
IF 2.647
Liu Shanshan,Li Chenyao,Wang Dongxin,Li Junyi,Yuan Rui,Che Yusi,He Jilin,Song Jianxun
In this research, the reduction mechanism of Nb(V) under various [F − ]/[Nb n+ ] ratios ( α ) was investigated by a series of electrochemical techniques, such as square wave voltammetry (SWV) and chronopotentiometry (CP). We previously studied the electrode reduction process of Nb(V) and revealed that was Nb(V) → Nb(III) → Nb(I) → Nb in NaCl-KCl molten salt. It was found in this research that the electrode reduction process of Nb(V) ion was shortened to Nb(V) → Nb(III) → Nb when α was equal to 1.0; furthermore, the electrode reduction process of Nb(V) ion transforms to Nb(V) → Nb(IV) → Nb when α was greater than or equal to 5.0. Moreover, the reaction mechanism was also discussed in this work. Metallic niobium was collected on a molybdenum electrode under the condition of higher fluoride content after electrolysis in the melt.
研究领域:
材料科学
·
电化学
✓ 已验证
DOI
高影响因子
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
·
2018
·
IF 2.88
Xiang-yu Kong,Ling-Jie Hou,Xiu-qing Shao,Shao-Min Shuang,Yu Wang,Chuan Dong
A novel fluorescent probe , phenolphthalein‑dialdehyde‑(2‑pyridyl) hydrazone (L), for sequentially detecting Al 3+ and F − in almost 100% aqueous medium was successfully designed and synthesized. The probe offers two binding pockets for Al 3+ to form a 1: 2 ligand/metal complex, leading to a significant fluorescence enhancement at 465 nm. Further, the in-situ formed L-Al complex acts as a secondary fluorescent chemosensor for F − by quenching the fluorescence of the complex with high selectivity. The detection limit for Al 3+ and F − sensing is 2.28 nM and 0.13 μM, respectively, which are far below the World Health Organization (WHO) acceptable limits (7.41 μM for Al 3+ ion and 79 μM for F − ) in drinking water . The probe L was successfully applied to the detection of Al 3+ and F − in cells using fluorescence microscopy .
研究领域:
分析化学
·
生物医学
✓ 已验证
DOI
PubMed
高影响因子
RESOURCES CONSERVATION AND RECYCLING
·
2025
·
IF 10.9
Fei Han,Yaohui Xie,Lin Qu,Zhenzhou Wang,Wei Zhang,Guang Yang,Huiqin Hu,Meiting Huang,Haoxuan Yu,Liming Yang,Xubiao Luo
Deep removal of trace aluminum from lithium extraction slag (LES) is key to recovering high-purity battery-grade iron phosphate (FePO 4 ). Existing methods exhibit low aluminum removal due to the close solubility product constants of Al (III) and Fe (III). In this work, we propose a novel strategy for trace aluminum removal based on fluoride ion-mediated differential coordination of Al (III) and Fe (III). Through precise control of fluoride ion concentration in phosphoric acid solution, iron preferentially precipitates while aluminum predominantly forms soluble fluoride complexes. This distinct behavior enables precise elemental separation through fluoride content optimization. The developed separation technology achieved aluminum removal rate of 98.89 %. It is noteworthy that the aluminum content of precipitated FePO 4 is below 30 ppm, which meets the standard of battery-grade. This work provides a viable technical pathway for the industrialization of Al/Fe separation in the lithium extraction slag leachate and the regeneration of low-Al, high-purity FePO 4 .
研究领域:
化学工程
·
材料科学
✓ 已验证
产品关联
DOI
高影响因子
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
·
2018
·
IF 2.88
Xiao Wang,Yanmei Zhou,Chenggong Xu,Haohan Song,Xiaobin Pang,Xiaoqiang Liu
Hydrazine (N 2 H 4 ) and fluoride ion (F − ) are regarded as environmental pollutants and potential carcinogens. A dual-functional fluorescent probe (probe 1 ) was developed for both F − and N 2 H 4 with high selectivity and sensitivity. 1 was based on nucleophilic aromatic substitution reaction for N 2 H 4 detection and selective cleavage of 4-nitrobenzenesulphonyl group for the determination of F − . The limits of detection of probe for F − and N 2 H 4 were 77.82 nM and 29.34 nM, respectively, which are far below the threshold limit value (TLV) of United States Environmental Protection Agency (EPA). The home-made test strips of 1 provided the positive tool for F − and gaseous N 2 H 4 in different system. And the confocal fluorescence images indicated that 1 can quantitatively detect N 2 H 4 in living PC12 cells. Promisingly, 1 has great prospects for N 2 H 4 imaging and determining in living system.
研究领域:
分析化学
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环境科学
·
生物医学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
Advanced Composites and Hybrid Materials
·
2021
·Vol. 4
·期 2
·339-349
·
IF 5.693
Lin Chunling,Liu Boyang,Pu Liuyue,Sun Yan,Xue Yanli,Chang Mulan,Li Xin,Lu Xingyu,Chen Rong,Zhang Jiaoxia
As a highly active photocatalyst, g-C 3 N 4 /TiO 2 heterojunction nanocomposites were in situ synthesized by hydro-thermal method and calcination using melamine as precursors. The morphology and chemical structure of the prepared photocatalysts were characterized by X-ray diffraction, Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), SEM, UV-vis, and photoluminescence analysis (PLA). At last, the photocatalytic activities of g-C 3 N 4 /TiO 2 nanocomposites to remove fluoride under simulated visible light were evaluated. Results showed that the fluoride removal rate of the prepared g-C 3 N 4 /TiO 2 was about three times than pure g-C 3 N 4 due to the rapid charge transfer and the efficient separation of photogenerated electron-hole pairs in heterojunctions between g-C 3 N 4 and TiO 2 . Graphical abstract Heterojunction g-C 3 N 4/ TiO 2 display the excellent fluoride removal rate due to the rapid charge transfer and efficient separation of electron-hole pairs.
研究领域:
环境科学
·
材料科学
✓ 已验证
产品关联
DOI
高影响因子
危险品化学品经营许可证（带存储）