CORROSION
·
2013
·Vol. 69
·期 7
·672-680
·
IF 1.772
Jiang Y.Y.,Chen Y.,Ye Z.Y.,Chen H.,Zhang Z.,Zhang J.Q.,Cao C.N.
N-[2-[(2-aminoethyl) amino] ethyl]-9-octadecenamide (AAOA) has been synthesized in the lab, then tested as an effective and economic acid inhibitor for A3 steel in an acid medium with electrochemical techniques (electrochemical impedance and polarization curve). The results show that AAOA acts as a good mixed-type inhibitor for A3 steel in 1 M hydrochloric acid (HCl) solution, and the inhibition efficiency reaches 94% at the concentration of 200 mg/L. The corrosion current density of A3 steel increases with the increasing temperature from 20°C to 60°C. Meanwhile, Langmuir isotherm is found to provide the description of the adsorption behavior of AAOA, and the value of adsorption free energy (ΔG 0 ) is as low as low as −37.3 kJ/mol. One can assume the adsorption of inhibitor molecules on the metal surface is by chemisorption, which has been understood taking into account some other adsorption parameters (ΔH 0 , ΔS 0 ) and the activation parameters (E a , ΔH * , ΔG * ).
研究领域:
材料科学
·
腐蚀与防护
·
电化学
✓ 已验证
DOI
高影响因子
CARBOHYDRATE POLYMERS
·
2012
·
IF 3.628
Guanghua He,Zi Wang,Hua Zheng,Yihua Yin,Xiong Xiong,Rongye Lin
Aminoethyl chitins (AEC) with different amino contents were synthesized from chitin and 2-chlorethylamine hydrochloride, and the AEC hydrogels were prepared by crosslinking with glutaraldehyde. The microstructures, swelling behaviors and antibacterial activities of the hydrogels were investigated. The results of Fourier transform infrared spectroscopy (FTIR), 1 H nuclear magnetic resonance ( 1 H NMR) spectrum and scanning electron microscopy (SEM) showed that the hydrogels were prepared by forming the Schiff base from AEC and glutaraldehyde. The aminoethyl chitin hydrogels were sensitive to acidic environment. The swelling ratio changed with the amino content of AEC, declined with the increase of the crosslinking agent concentration and increased with the increase of the AEC concentration. In addition, the antibacterial results of the hydrogels against Staphylococcus aureus ( S. aureus ) indicated that the hydrogels had good antibacterial activities, and the antibacterial properties were affected by the amino content of AEC and the crosslinking agent concentration.
研究领域:
生物材料学
·
高分子化学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
CHEMICAL ENGINEERING SCIENCE
·
2017
·
IF 2.895
Liang Shen,Yan Wang
Interfacially synthesized polyamide (PA) thin-film composite (TFC) membranes are widely employed in forward osmosis (FO) applications because of the easy fabrication and excellent separation performance. But they generally suffer from the relative low water permeability and high fouling tendency due to the inherent hydrophobic nature of the PA layer. In this study, an efficient surface modification of nascent TFC membranes is performed by grafting a self-catalyzed tripodal amine—tris(2-aminoethyl)amine (TAEA), in order to improve the membrane performance. This tertiary amine plays a dual role of the reactive amine monomer reacting with acyl chloride groups and the catalyst accelerating the amidation reaction between 1,3,5-trimesoyl chloride (TMC) and TAEA, therefore contributing to an efficient grafting effect to the greatest extent. State-of-the-art characterizations are applied to verify the modification mechanism. The effects of the pH and concentration of the TAEA solution on the overall properties of the resultant TFC membranes are systematically investigated, including the surface chemical composition, surface morphology, hydrophilicity, surface charge, separation performance, and fouling resistance. Compared with the control TFC membrane, TAEA-modified TFC membranes exhibit significantly improved water fluxes, higher antifouling propensity, and comparable reverse salt fluxes.
研究领域:
材料科学
·
环境工程
✓ 已验证
产品关联
DOI
高影响因子
ACS Applied Materials & Interfaces
·
2024
·
IF 8.3
Xiguang Li,Chunya Wu,Jiahao Wu,Ruijiang Sun,Bo Hou,Chang Liu,Mingjun Chen
Polydopamine (PDA) is well known as a mussel-inspired adhesive material composed of oligomeric heteropolymers. However, the conventional eumelanin-like structural assumption of PDA seems deficient in explaining its interfacial adhesion. To determine the decisive mechanism of PDA coating formation, experiments and simulations were performed in this study. 5,6-Dihydroxyindole (DHI), the signature building block of eumelanin, was introduced as the control group. Various typical building blocks in PDA were quantified by physicochemical characterizations, and the polar-group-dominated interfacial interaction was evaluated by classic molecular dynamics and metadynamics methods. Aminoethyl has been proven to be the key functional group inducing the adsorption of PDA on the hydroxylated silica substrates, while DHI shows limited adhesion to the substrate due to the absence of aminoethyl as the catechol-indole structure of DHI exhibits poor affinity to the silica surface. Pyrrole carboxylic acid, as an oxidative product detected from PDA/DHI, is unfavorable for its adhesion to silica substrates. Overall, the coating formation and self-aggregating precipitation of PDA are two competitive aminoethyl-consuming paths; thus, the in situ oxidative coupling of dopamine is indispensable for the PDA coating preparation. The collected PDA precipitates can no longer present satisfactory coating forming behavior, resulting from a shortage of aminoethyl moieties.
研究领域:
材料科学
·
分子生物学
✓ 已验证
DOI
PubMed
高影响因子
TEXTILE RESEARCH JOURNAL
·
2022
·
IF 2.455
Xun Zhang,Sarkodie Bismark,Zhifeng Zhu
Tertiary amine groups can exhibit and lose cationic properties at different pH levels, and this group can be introduced to starch chains to satisfy the demand for sizing and desizing. However, the effect of pH on tertiary amine groups in toughening starch film and improving adhesion is still unclear. Therefore, 2-dimethylaminoethyl starch (DMAES) was prepared via tertiary aminated starch with 2-dimethylaminoethyl chloride hydrochloride. The influences of pH on the mechanical properties of DMAES films and the adhesion to cotton fiber were investigated. In addition, the desizability and biodegradability of DMAES were measured. It was found that introducing the group of 2-dimethylaminoethyl could toughen the starch film and increase the adhesion to cotton fiber. DMAES has a higher zeta potential and the adhesion to cotton fibers in acidic conditions than in alkaline conditions. In addition, it is easy to remove the DMAES from the yarns and obtain higher desizing efficiency with alkali desizing. Tertiary amination of starch with the 2-dimethylaminoethyl group was a good way for starch to improve adhesion and obtain a higher desizing efficiency.
研究领域:
材料科学
·
生物化学
✓ 已验证
DOI
高影响因子
ACS Applied Materials & Interfaces
·
2018
·
IF 8.097
Wen Yang,Fangbing Liu,Ran Li,Xiaoji Wang,Wentao Hao
Multiresponsive fluorescent supramolecular materials are quite interesting, for they combine the multiresponsiveness of supramolecules and the high sensitivity of fluorescent materials. Different from the multiresponsive supramolecular materials based on host–guest interactions, in this report, a supramolecular ionic network was fabricated by 1-(2-aminoethyl)piperazine and citric acids via ionic interactions. Despite the fact that there are no conventional chromophores, the obtained supramolecular ionic material can emit strong fluorescence. Most interestingly, the thin film of this supramolecular ionic material can change its fluorescent intensity in response to four external stimuli, including humidity, triethylamine, acetic acid, and temperature. Beneficial to the supramolecular ionic structure, this multiresponsive fluorescent sensor is self-healable. It is found that a new route has been opened to prepare the multiresponsive fluorescent sensors.
研究领域:
材料科学
·
化学
✓ 已验证
DOI
PubMed
高影响因子
MATERIALS RESEARCH INNOVATIONS
·
2022
·
IF 0
Ying Zhou,Yi Fan,Jingyu Wu,Li Jiang,Hongjun Yang,Qimin Jiang,Wenyan Huang,Xiaoqiang Xue,Bibiao Jiang
Novel reducing emulsifier monomers 2-(dimethylamino)ethyl dodecyl maleate (DMAEDM) and 2-(dimethylamino)ethyl dodecyl itaconate (DMAEDI) containing polymerisable double bonds, tertiary amine and long-chain aliphatic hydrocarbons were creatively designed and synthesised. Reducing emulsifier monomers (REM) were prepared using dodecanol, acid anhydride and 2-dimethylaminoethyl chloride hydrochloride through a two-step reaction process. The optimum reaction temperature and ratio of chemicals were determined to achieve higher yield and purity of REM products. The product purity was above 95% as determined by gas chromatography. The structure of the products was confirmed by infrared spectroscopy (IR) and proton nuclear magnetic resonance (1H-NMR) spectroscopy. The novel reducing emulsifier monomers have been determined to have good emulsifying performance.
研究领域:
化学
·
材料科学
·
高分子科学
✓ 已验证
产品关联
DOI
Journal of Environmental Sciences
·
2023
·
IF 6.9
Xiaobin Zhou,Dan Wang,Chao Liu,Guohua Jing,Bihong Lv,Dunqiu Wang
Non-aqueous absorbents (NAAs) have attracted increasing attention for CO 2 capture because of their great energy-saving potential. Primary diamines which can provide high CO 2 absorption loading are promising candidates for formulating NAAs but suffer disadvantages in regenerability. In this study, a promising strategy that using tertiary amines (TAs) as proton-transfer mediators was proposed to enhance the regenerability of an aminoethylethanolamine (AEEA, diamine)/dimethyl sulfoxide (DMSO) (A/D) NAA. Surprisingly, some employed TAs such as N,N -diethylaminoethanol (DEEA), N,N,N',N'',N'' -pentamethyldiethylenetriamine (PMDETA), 3-dimethylamino-1-propanol (3DMA1P), and N,N -dimethylethanolamine (DMEA) enhanced not only the regenerability of the A/D NAA but also the CO 2 absorption performance. Specifically, the CO 2 absorption loading and cyclic loading were increased by about 12.7% and 15.5%–22.7%, respectively. The TA-enhanced CO 2 capture mechanism was comprehensively explored via nuclear magnetic resonance technique and quantum chemical calculations. During CO 2 absorption, the TA acted as an ultimate proton acceptor for AEEA-zwitterion and enabled more AEEA to form carbamate species (AEEACOO − ) to store CO 2 , thus enhancing CO 2 absorption. For CO 2 desorption, the TA first provided protons directly to AEEACOO − as a proton donor; moreover, it functioned as a proton carrier and facilitated the low-energy step-wise proton transfer from protonated AEEA to AEEACOO − . Consequently, the presence of TA made it easier for AEEACOO − to obtain protons to decompose, resulting in enhanced CO 2 desorption. In a word, introducing the TA as a proton-transfer mediator into the A/D NAA enhanced both the CO 2 absorption performance and the regenerability, which was an efficient way to “kill two birds with one stone”.
研究领域:
化学工程
·
环境科学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
POLYMERS FOR ADVANCED TECHNOLOGIES
·
2018
·Vol. 29
·期 11
·2838-2847
·
IF 2.137
Shuchen Shi,Dongyi Li,Chunxiao Chai,Yufeng Wu,Ying Xu
A novel modified polyaspartic acid polymer, polyaspartic acid/4-(2-aminoethyl) morpholine graft copolymer (PASP/AEM), was prepared through a ring-opening reaction of polysuccinimide and 4-(2-aminoethyl) morpholine and characterized by 1 H NMR. The scale inhibition performance of this copolymer and its ability to disperse Fe 2 O 3 were investigated in static tests. Scanning electron microscopy and X-ray powder diffraction were used to analyze the effects of PASP/AEM on scale formation. The performance and mechanism of corrosion inhibition by the synthesized copolymer were studied via weight loss measurements and electrochemical measurements. The results showed that PASP/AEM possessed outstanding scale and corrosion inhibition efficiencies and had potential for use as a green scale and pickling inhibitor.
研究领域:
材料科学
·
化学工程
✓ 已验证
产品关联
DOI
高影响因子
ELECTROCHIMICA ACTA
·
2019
·
IF 5.383
Fan Yuan,Kai Hao,Shu Sheng,Tadesse Haile Fereja,Xiangui Ma,Feng Liu,Muhammad Nadeem Zafar,Baohua Lou,Huayu Tian,Guobao Xu
A highly efficient co-reactant of Ru(bpy) 3 2+ electrochemiluminescence (ECL), 2-(dibutylamino)ethyl acrylate(DBAEA), was successfully synthesized by a straightforward one-step reaction between dibutylaminoethanol and acrylyl chloride. On account of the interaction between the olefin group of DBAEA and Pt electrode, the ECL intensity utilizing DBAEA as the co-reactant was increased dramatically, nearly as 10 times and 17 times as conventional co-reactants dibutyaminoethanol and tripropylamine . Since cysteine can remove the acrylate group of DBAEA specifically through conjugated addition/cyclization reaction, the ECL intensity of Ru(bpy) 3 2+ /DBAEA was declined selectively. Therefore, cysteine was detected through this novel ECL system with high selectivity towards other amino acids . The linear range was between 10 μM and 200 μM with a limit of detection of 1.15 μM. The cysteine in Dulbecco’s Modified Eagle Medium (DMEM) was detected and satisfying recovery was obtained.
研究领域:
分析化学
·
生物医学
✓ 已验证
产品关联
DOI
高影响因子
FOOD RESEARCH INTERNATIONAL
·
2021
·
IF 6.475
Zheng Hu,Hualin Wang,Linlin Li,Qian Wang,Suwei Jiang,Minmin Chen,Xingjiang Li,Jiang Shaotong
This study demonstrates a pH-responsive antibacterial film based on polyvinyl alcohol/poly (acrylic acid) incorporated with aminoethyl-phloretin (PVA/PAA-AEP) for intelligent food packaging. The thermal, mechanical, barrier and light transmittance properties of PVA/PAA are enhanced by PAA presence of ≤6%. The interactions between PVA and PAA were hydrogen and ester bonds. The pH-responsive characteristic is dependent on the protonation/deprotonation tendency of the carboxylic groups on PAA in acidic/alkaline environment. The PVA/PAA3 is selected for the incorporation of AEP and its pH-responsive swelling follows Ritger-Peppas and Schott second-order models. The AEP is hydrogen bonded with the matrix of PVA/PAA3 and the release of AEP is pH-responsive and a rate-limiting step following the First-order model. With pH decrease, the predominant release control was gradually changing from polymer relaxation to Fick diffusion. The PVA/PAA3-AEP films demonstrate AEP content dependent antioxidant and antimicrobial activities. Furthermore, the antibacterial efficiency against Listeria monocytogenes and Staphylococcus aureus is significantly better than Escherichia coli . The target film PVA/PAA3-AEP3 can effectively prolong the shelf-life of pork (TVB-N < 25 mg/100 g) by 4 days at 25 °C, suggesting its great potential in intelligent food packaging.
研究领域:
食品科学
·
材料科学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
RSC Advances
·
2022
·Vol. 12
·期 38
·24596-24606
·
IF 4.036
Yong-Hong Cai,Jia-Li Zhao,Xin-Yu Guo,Xiao-Juan Zhang,Ran-Ran Zhang,Shao-Rong Ma,Ya-Min Cheng,Zhong-Yan Cao,Ying Xu
Polyaspartic acid (PASP), a well-known green scale inhibitor for industrial water treatment, might be decomposed with prolonged duration, and its anti-scaling performance against CaCO3 and CaSO4 is diminished at a low concentration (<10 mg L−1) and a high temperature. With semi-ethylenediaminetetraacetic acid (EDTA) tetrasodium salt as the mimicking model, novel phosphorus-free PASP-capped 2-aminoethylamino acid (PASP–ED2A) containing side chains bearing multi-functional groups is rationally designed and successfully prepared via the ring-opening reaction of cheap poly(succinimide) under mild reaction conditions with the assistance of readily available 2-aminoethyl amino acid. The static scale inhibition method is used to evaluate the scale inhibition performance of the as-synthesized PASP derivative. Scanning electron microscopy, X-ray diffraction, and X-ray photoelectron spectroscopy are utilized to monitor the crystallization process of calcium carbonate and calcium sulfate scales, and density functional theory calculations are conducted to shed light on the relationship between the molecular structure and scale inhibition mechanism of PASP–ED2A. Results show that the as-prepared PASP–ED2A shows better scale inhibition performance for CaCO3 and CaSO4 than PASP with a low concentration, a high temperature, and an extended duration. Particularly, PASP–ED2A with a concentration of 10 mg L−1 exhibits the best scale inhibition performance for CaCO3; its scale inhibition capacity is about two times as much as that of PASP. The reason lies in that the coordination atoms in the molecular structure of PASP–ED2A can chelate with Ca2+ to inhibit the combination of Ca2+ with anions and prevent the generation of CaCO3 and CaSO4 scales. The PASP–ED2A derivative can more efficiently retard the formation and growth of CaCO3 and CaSO4 crystal nuclei and exerts better inhibition performance against CaCO3 and CaSO4 scales than PASP.
研究领域:
材料科学
·
环境科学
·
化学工程
✓ 已验证
DOI
高影响因子
危险品化学品经营许可证（带存储）