Exploration of the Mn-O coordination regulated reaction stability of manganese oxides in NH3-SCR: Effect of deposited ammonium nitrates
Manganese oxide-based catalysts exhibit excellent low-temperature denitration efficiency, making them potential candidates for application. Herein, the relationship between reaction stability and phase structure for MnO 2 , Mn 2 O 3 and Mn 3 O 4 was disclosed. The NO conversion for Mn 2 O 3 drastically reduced after 120 h reaction, while minor decline was detected for MnO 2 and Mn 3 O 4 . Based on dedicate qualitative and quantitative analyses on the deposits over catalyst surface, deactivation trigged by ammonium nitrate (AN) deposition was confirmed. Different from penta-coordinated Mn 4+ on MnO 2 (110) and tri-coordinated Mn 2+ , penta-coordinated Mn 4+ on Mn 3 O 4 (101), the unique tetra-coordinated Mn 3+ on Mn 2 O 3 (200) could stabilize the nitrates and make it difficult to be removed via decomposition or reaction and accumulate continuously, which resulted in the significant deactivation. This research could not only unveil the poisoning mechanism of MnO x based catalysts, but also provide new insights into the relationship between the catalytic stability and surface Mn-O microstructure.
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