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氯oplast
Nature Communications · 2019 ·Vol. 10 ·期 1 ·1-10 · IF 11.878

A chloroplast structured photocatalyst enabled by microwave synthesis

Xiao Shuning,Zhang Dieqing,Pan Donglai,Zhu Wei,Liu Peijue,Cai Yong,Li Guisheng,Li Hexing

Photosynthesis occurs through the synergistic effects of the non-ncontinuously distributed components in the chloroplast. Inspired by nature, we mimic chloroplast and develop a generic approach to synthesize non-continuously distributed semiconductors threaded by carbon nanotubes. In the synthesis, carbon nanotubes serve as microwave antennas to produce local super-hot dots on the surface, which might induce and accelerate various organic/inorganic semiconductors assembly. With the unique nanoscale designed bionic architecture, a chloroplast structured photocatalyst with 3−dimentional dual electron transfer pathways facilitate enhanced photocatalytic performance. The as-synthesized carbon nanotubes-titanium oxide achieves a record-breaking efficiency of 86% for nitric oxide treatment under ultraviolet light irradiation. As a general strategy, a wide variety of carbon nanotubes threaded chloroplast structured nanomaterials can be synthesized and these nanomaterials could find applications in energy chemistry, environmental science and human health.

研究领域: 材料科学 · 环境科学 · 生物仿生学
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