POLYMER ENGINEERING AND SCIENCE
·
2025
·
IF 3.2
Binzhi Wang,Yuewen Huang,Bin Wang,Ruixiang Zhou,Feng Wang,Hui Liu
In this study, an N, N-dimethyl-p-toluidine/benzoyl peroxide redox initiation system was used to synthesize a series of silicone-modified UV-curable acrylic pressure-sensitive adhesives (PSAs) via bulk polymerization. The oxidizing and reducing agents were added separately but simultaneously into a mixture of monomers. The impact of varying monomer content on the PSA's properties, as well as the influence of organosilicon incorporation on water and aging resistance, was evaluated through 180° peel strength and initial adhesion tests. The results demonstrated that the PSA without organosilicon modification exhibited a maximum peel strength of 7.21 N/25 mm and an initial adhesion of 8.41 N/25 mm. Although the introduction of the organosilicon structure reduced both peel strength and initial adhesion, it notably improved the PSA's water resistance and aging resistance. Highlights Synthesis without solvent using redox initiator system. UV-cured system to enhance molecular weight and adhesion. Introduction of silane structure to improve water and aging resistance. Adhesion performance testing on different substrates (PET and BOPP).
研究领域:
材料科学
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化学工程
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF APPLIED POLYMER SCIENCE
·
2023
·Vol. 141
·期 12
·e55123
·
IF 3
Xu Han,Wenke Li,Yumei Ji,Lianfeng Wu,Yike Yang,Feng Liu
Polysulfide adhesives are often subjected to breakage or even fracture caused by highly loaded vibrations and large deformations from the wing, limiting their practical use in aircraft fuel tanks. Inserting polyurethanes into liquid polysulfide systems is a viable approach to strengthening their mechanical properties and avoiding nonuniform dispersion of the curing agent. In this contribution, a series of sulfur-containing curing agents were prepared by liquid polysulfide and trimethylolpropane tris(3-mercapto propionate) (TMPMP) to minimize the effect of the polysulfide-urea (-NHCOS-) groups on water resistance. Subsequently, the two-component polysulfide adhesives were successfully synthesized via the prepolymerization method, and their chemical structure, mechanical properties, and solvent resistance were systematically evaluated. As expected, the large introduction of sulfur linkages and -NHCOS- groups provided excellent oil resistance and strong mechanical properties for polysulfide adhesives. Notably, Samples 2-4 exhibited the highest tensile strength of 1.11 ± 0.02 MPa, the greatest shear strength of 1.87 ± 0.04 MPa, and the best hardness of 81 ± 2 Shore A, with 122.0%, 523.3%, and 170.0% improvement over the control, respectively. Furthermore, the oil absorption rate of all samples was less than 3.0%, and their tensile strength remained almost unchanged after 30 days of immersion than before. We believe our paradigm can provide a valuable guideline for designing high-performance polysulfide adhesives.
研究领域:
材料科学
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化学工程
✓ 已验证
产品关联
DOI
高影响因子
Polymers
·
2024
·Vol. 16
·期 23
·3437
·
IF 4.7
Wei Wang,Ke Zheng,Wenzheng Zhao,Shenglong Zheng,Hui Wan,Jingran Gao
Tung oil pressing generates a substantial amount of tung cake waste rich in protein, which can be used to develop a novel wood protein adhesive. This study determined the optimal alkali treatment parameters based on NaOH concentration, reaction temperature, and reaction time. Potassium permanganate (KMnO4) and methyl trimethoxy silane (MTMS) were then sequentially added for cross-linking modification to achieve the optimal preparation process for the tung cake protein adhesive. Bonding strength was tested on pressed boards, and various characterization techniques, including X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), Thermogravimetric analysis (TG/TGA), differential scanning calorimetry (DSC), and scanning electron microscopy (SEM), were used. The results indicated the following: (1) Optimal preparation conditions: The best preparation process for the adhesive involved 30% NaOH at 50 °C for 50 min, with the addition of 12% KMnO4and 6% MTMS, meeting Class II plywood standards. (2) XRD and FTIR analyses revealed that carbohydrates in the tung cake oxidized and reacted with protein amino groups. The active groups in the protein cross-linked with MTMS, forming a spatial network structure, reducing hydrophilic groups, and enhancing water resistance. (3) TG/TGA and DSC showed that the thermal stability of the modified adhesive improved, thermogravimetric loss was reduced, and curing performance was enhanced. (4) SEM verified the adhesive’s reaction mechanism, demonstrating that MTMS filled the protein structure unfolded by KMnO4, forming a three-dimensional network and improving bonding strength. This study successfully developed a new, formaldehyde-free, environmentally friendly tung cake protein adhesive with excellent performance.
研究领域:
材料科学
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环境科学
·
林产化学加工工程
✓ 已验证
产品关联
DOI
PubMed
高影响因子
JOURNAL OF APPLIED POLYMER SCIENCE
·
2020
·Vol. 137
·期 36
·49047
·
IF 2.52
Hongsheng Qi,Sawen Liu,Xiuling Chen,Chunhui Shen,Shanjun Gao
A novel mono-component intumescent flame retardant(m-IFR), called poly-(spirocyclic pentaerythritol bisphosphonate-1,3,5-triazine-O-bicyclic pentaerythritol phosphate) (PSTBP) was synthesized and characterized. PSTBP was used in polypropylene (PP) to obtain PP/PSTBP mixture whose flame retardancy, thermostability, and water resistance were studied by limiting oxygen index (LOI), vertical burning test (UL-94 V) and thermogravimetric analysis (TGA). In addition, flame-retardant mechanism of the PSTBP was investigated. The results showed that the residue of PSTBP reached 34.58% at 800°C and the volume of the PSTBP increased by dozens of times. When the content of PSTBP was 30.0 wt%, the PP/PSTBP mixture could achieve an LOI value of 32.5% and an UL-94 V-0 rating. Compared with PP/APP/PER system, PP/PSTBP mixture showed better water resistance. The TGA and Fourier transform infrared spectroscopy (FTIR) results showed that PSTBP could generate free radicals and capture the free radicals of the thermal decomposition of PP, and form a dense, strong, and thick intumescent char on the substrate, thus effectively retard the degradation and combustion of PP.
研究领域:
材料科学
·
高分子化学
✓ 已验证
DOI
高影响因子
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
·
2018
·
IF 3.909
Xuechuan Wang,Ke Chen,Wei Li,Dongyan Hao,Peiying Guo
In this research, collagen hydrolysates with different average molecular weights ( Mn ¯ ) from leather collagen were chosen as raw materials. Five environmental-friendly sizing agents (SA) were prepared by cross-linking collagen hydrolysates with glycol diglycidyl ether (GDE) and further grafting them with butyl acrylate (BA) and styrene (St). Then the compound sizing agents (SGDESA-x, x = 1, 2, 3 and 4) were obtained by simple physical mixing of GDESA and starch. The surface sizing performance of GDESA and compound sizing agents were studied. The research result shows that both physical, mechanical properties and water resistance of the corrugated paper coated by GDESA were significantly improved when Mn ¯ of collagen hydrolysate was about 10,000, and its emulsion exhibited robust stability in long standing time. Furthermore, when the SGDESA-2 was used as a sizing agent, the coated corrugated paper exhibited strong water resistance, good physical and mechanical properties even after refolded for 20 times.
研究领域:
材料科学
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化学工程
✓ 已验证
产品关联
DOI
PubMed
高影响因子
CARBOHYDRATE POLYMERS
·
2021
·
IF 9.381
Lei Chen,Zia-ud Din,Dan Yang,Chun Hu,Jie Cai,Hanguo Xiong
Sustainable bio-based adhesive is a promising substitute for petroleum-based adhesives to alleviate serious environmental and health problems. In this work, a nanoengineered starch-based adhesive was fabricated by grafting vinyl acetate (VAc) onto starch molecule and subsequently incorporating the functional nanoparticle [TiO 2 -coupling-poly(butyl acrylate, BA), TKB] to overcome the drawbacks present in conventional nanocomposite adhesive. Results showed that the presence of BA altered the surface property of TKB, leading to improved dispersion. In the adhesive with 4% (mass ratio to starch) TKB, TKB aggregates played the role as a sliding bridge, which significantly promoted the storage stability and shear strength in both dry and wet states. Additionally, the latex film with 4% TKB exhibited high compatibility and water resistance due to the promoted hydrophobicity . This study provides a fundamental insight into the improvement of functional nanoparticles on the performance of starch-based adhesive, suggesting a novel strategy for designing high-performance bio-adhesive.
研究领域:
材料科学
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环境科学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
·
2015
·Vol. 120
·期 2
·1327-1335
·
IF 2.042
Luo Fubin,Wu Kun,Lu Mangeng,Nie Shibin,Li Xiaoya,Guan Xiaoxiao
Microencapsulated ammonium polyphosphate MFAPP or VMFAPP with shell of melamine–formaldehyde or poly (vinyl alcohol)–melamine–formaldehyde resin was prepared by in situ polymerization, respectively. The flame-retardant performance of rigid polyurethane foam (PU) containing MFAPP or VMFAPP was analyzed by limiting oxygen index and UL-94 test. Thermal degradation behaviors of PUAPP, PUMFAPP and PUVMFAPP were studied using TG and TG–FTIR. Above results indicated that VMFAPP and MFAPP have better water resistance and flame retardancy compared with ammonium polyphosphate (APP) in PU composites. Flame-retardant properties of PUMFAPP and PUVMFAPP composites were rarely changed after hot water treatment. Due to better compatibility and the presence of active groups on the surface of APP, microencapsulation demonstrated a positive effect on the mechanical property of PU composites.
研究领域:
材料科学
·
化学工程
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF FLUORINE CHEMISTRY
·
2016
·
IF 2.213
Cheng Fang,Yi Jing,Yajun Zong,Zhongxiang Lin
Fluorinated acrylic pressure sensitive adhesive (PSA) latexes based on butyl acrylate (BA), acrylic acid (AA), 2-hydroxyethyl acrylate (HEA) and 2,2,2-trifluoroethyl methacrylate (TFMA) were synthesized via a monomer-starved seeded semi-continuous emulsion polymerization process using a reactive emulsifier. Effects of TFMA on the resultant PSA properties were comprehensively investigated. IR analysis indicated that TFMA can be introduced into the latex particles successfully through emulsion polymerization. Gel content and sol molecular weight of the PSA were not significantly affected by the addition of TFMA. It was also found that T g and thermal stability of the PSA were both improved remarkably as TFMA content increased. Water resistance of the PSA was enhanced, while surface energy of the PSA was decreased with TFMA concentration increased, which were confirmed by XPS analysis. Moreover, the storage modulus (G’) and loss modulus (G”) of the PSA increased with TFMA content. Peel strength of the PSA on PP surface was not affected by the presence of TFMA, while peel strength of the PSA on SS and PC surfaces were first decreased and then increased with the TFMA content. Besides, the influences of reactive surfactant SR-10 and conventional surfactant CO-436 on the acrylic latex PSA were also compared.
研究领域:
材料科学
·
化学工程
✓ 已验证
产品关联
DOI
高影响因子
危险品化学品经营许可证（带存储）