Water Conservation Science and Engineering
·
2025
·Vol. 10
·期 3
·1-16
·
IF 1.9
Li Zhengjie,Fang Chunxia,Ma Xilong,Liu Yixian,Xie Juan,Li Pengfei,Zhang Zhikun,Zhao Xudong,Sun Hua,Han Jilong
Herein, a facile and rapid preparation method was developed to synthesize Ce-doped UiO-66-NH 2 through a one-pot solvothermal method. This approach simultaneously introduces functional groups onto organic ligands and incorporating a novel metal into metal clusters. The incorporation of Ce ions effectively enlarged the pore size and increased the pore volume, thereby facilitating the diffusion of specific adsorbate molecules into the inner adsorption sites provided by the –NH 2 groups. Due to the favorable pore structures and more exposed adsorption sites, the safranine T (ST) adsorption capacity of Ce-doped UiO-66-NH 2 was ten times higher than the pristine UiO-66-NH 2 and reached 1340 mg/g at optimal adsorption conditions, surpassing most of the reported porous adsorbents. The kinetic and isotherm fitting results showed that the pseudo-second-order and Langmuir models described the adsorption behaviors of ST best, indicating a homogeneous, endothermic, and spontaneous monolayer adsorption process. The adsorption mechanism showed that the hydrogen bonding interaction and pore filling effect are identified as the main mechanism whilst electrostatic attraction interaction further enhances the adsorption capacity at optimal pH. Therefore, Ce-doped UiO-66-NH 2 can serve as a promising adsorbent for the removal of cationic dyes from textile wastewater, and the developed facile and rapid method offers a viable strategy to construct novel MOF-based adsorbents.
研究领域:
环境科学
·
材料科学
·
化学工程
·
纳米技术
✓ 已验证
产品关联
DOI
高影响因子
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
·
2021
·
IF 6.953
Jinming Ma,Meng Zhang,Miaomiao Ji,Lexin Zhang,Zhihui Qin,Yaru Zhang,Lili Gao,Tifeng Jiao
Developing recyclable and efficient adsorbents for cationic dyes removal from wastewater is crucial for ensuring green ecology and drinking water safety. Herein, we demonstrated a novel magnetic gel bead adsorbent that was synthesized by employing graphene oxide (GO) modified Fe 3 O 4 as magnetic nanoparticles doped sodium alginate (SA)/chitosan (CS) gel (SA/GO@Fe 3 O 4 /CS). The GO@Fe 3 O 4 sample was prepared based on GO by the chemical co-precipitation method, which not only reduced the aggregation of Fe 3 O 4 but also increases the specific surface area of the composite gel beads. The prepared gel beads were used to adsorb methylene blue (MB), neutral red (NR), and safranine T (ST). The experimental results showed that the adsorption capacity of SA/GO@Fe 3 O 4 /CS gel beads for MB, NR, and ST reached 21.325 mg/g, 44.654 mg/g and 44.313 mg/g. After five recycles, the removal rates could still reach more than 90% of the original, exhibiting a high recovery rate. Therefore, this paper provides a strategy for the preparation of high efficiency and recyclable cationic dye adsorbents with a large specific surface area.
研究领域:
环境科学
·
材料科学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
NEW JOURNAL OF CHEMISTRY
·
2024
·
IF 2.7
Jun Zhang,Wei Li,Mingxiang Zheng,Jiawei Tan,Xinjuan Zeng,Cailong Zhou,Min Zhang,Lin Wang
The rapid growth of the dye industry and the worsening water resource crisis have drawn significant focus to the treatment of dye wastewater. Membrane separation technology is increasingly being utilized in addressing this issue. However, traditional separation membranes face challenges such as susceptibility to contamination and significant decline in subsequent separation permeance. This work utilizes a straightforward brushing technique to effectively apply a coating comprising titanium dioxide (TiO2) nanoparticles and attapulgite (APT) onto a stainless steel mesh (SSM), equipping it with the capability for dye adsorption and separation. Studies show that coatings with different ratios yield varying degrees of coverage on the SSM. A higher concentration of TiO2/attapulgite results in improved coverage on the SSM, creating a denser coating on the mesh surface and the degree of cross-linking of the coating was as high as 92.22%. The coated meshes exhibited superhydrophilicity uniformly and excellent negatively charged properties. Separation experiments of the meshes with different TiO2/attapulgite ratios were conducted by separating simulated dye wastewater with methylene blue (MB) and safranine T (SaT). The results indicate that the prepared meshes achieved a maximum rejection of over 98.0% for MB and over 96.5% for SaT. In addition, the prepared meshes maintained high dye rejection efficiencies (>96%) even after 10 consecutive separation cycles. The above results indicate that the prepared meshes are promising for application in industrial dye wastewater treatment.
研究领域:
材料科学
·
环境科学
·
化学工程
✓ 已验证
产品关联
DOI
高影响因子
MOLECULES
·
2023
·Vol. 28
·期 5
·2182
·
IF 4.6
Panpan Liu,Jiafei Lyu,Peng Bai
In this study, a series of Al-doped metal-organic frameworks (AlxZr(1−x)-UiO-66) were synthesized through a one-step solvothermal method. Various characterization techniques, including X-ray diffraction, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy, and N2sorption measurement, suggested that the Al doping was uniform and barely influenced the crystallinity, chemical stability, and thermal stability of the materials. Two cationic dyes, safranine T (ST) and methylene blue (MB), were selected for investigating the adsorption performances of Al-doped UiO-66 materials. Al0.3Zr0.7-UiO-66 exhibited 9.63 and 5.54 times higher adsorption capacities than UiO-66, 498 mg/g and 251 mg/g for ST and MB, respectively. The improved adsorption performance can be attributed to π-π interaction, hydrogen bond, and the coordination between the dye and Al-doped MOF. The pseudo-second-order and Langmuir models explained the adsorption process well, which indicated that the dye adsorption on Al0.3Zr0.7-UiO-66 mostly occurred through chemisorption on homogeneous surfaces. A thermodynamic study indicated the adsorption process was spontaneous and endothermic. The adsorption capacity did not decrease significantly after four cycles.Keywords:metal−organic framework;Al-doped;adsorption;organic dyes;mechanism
研究领域:
材料科学
·
环境工程
·
化学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
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