Neonicotinoids (NEOs) pesticides are widely used around the world, especially in the tropics with greater frequency and intensity. However, little is known about NEOs residue in drinking water of tropics. In this study, a highly efficient method using ultra-performance liquid chromatography-tandem mass spectrometry (UPLC-MS/MS) was established for determining eight NEOs in source water and tap water of Hainan Island, China. The method adopted a high-throughput direct aqueous injection without sample concentration steps, with a rapid analyzing period of 5.0 min, method detection limits (MDLs) in the range of 0.84–1.82 ng/L and the average recoveries ranged from 83% to 116%. NEOs were detected in all source water samples and at an upper level as compared with other parts of China. The most frequently detected NEO was imidacloprid with a detection frequency of 94%, followed by clothianidin (88%) and thiamethoxam (78%), with maximum concentrations of 86.4, 164, and 188 ng/L, respectively. Moreover, seasonal and spatial variations had remarkable impacts on NEO contamination in source water. Drinking water treatment processes removed approximately 20% of NEOs from surface water. However, 90% of tap water samples contained at least one NEO, With 3 samples’ concentration of single NEO exceeding the acceptable value recommended by the European Union (100 ng/L). Therefore, the risk of human exposure through drinking water was evaluated for 4 age group and 2 genders. Young children aged 9 months to 3 years old were found to have the highest risk, with the median exposure up to 4 times greater than teenagers and adults. Next, water intake is likely only a small part of the daily intake of these individuals, thus the potential health problems caused by NEOs present in the tap water of Hainan should not be ignored.
Organic ultraviolet filters (OUVFs) are extensively incorporated into both cosmetic items and industrial products and have been commonly found in water ecosystems. This study aims to examine the environmental levels, sources, ecological and human health risks of 14 commonly used OUVFs both in coastal water and beach deposit samples collected from the nearshore regions of Hainan Island and the South China Sea. This is first study highlighting the contamination of OUVFs in Hainan Island and utilizing economic and tourism data to confirm the potential source of OUVF pollution in costal aquatic and coastal ecosystem. Along the coastal tourist regions of Hainan Island, the median concentrations in coastal waters and beach deposits of these OUVFs fall within the range from 1.2 to 53.2 ng/L and 0.2–17.0 ng/g dw, respectively. In coastal water and beach deposit, the concentration of BP-3 was the highest, with median concentrations of 53.2 ng/L and 17.0 ng/g dw, respectively. Regarding human health risks, the daily intake of all 14 OUVFs through swimming was found to be 40–48 ng/kg/day. Ecological risk assessment indicates that BP-3 presents a medium risk for marine microalgae with a concurrent low risk for corals. The correlation analysis underscores a substantial interrelation of OUVFs in both coastal waters and beach deposits with various economic indicators, including annual rainfall, overnight tourists, total hotel rooms (unit), room occupancy rate, and sewage treatment capacity.
危险品化学品经营许可证（带存储）