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JOURNAL OF THE EUROPEAN CERAMIC SOCIETY · 2024 · IF 5.8

Water vapor corrosion behaviors of Yb2SiO5-Yb2O3-Si-SiC ceramic fabricated by tape casting and reactive melt infiltration

Liang Zhou,Jianbao Hu,Yunhui Zhang,Le Gao,Wang Yuan,Han Luo,Yanmei Kan,Xiangyu Zhang,Jinshan Yang,Bin Wu,Xiaowu Chen,Shaoming Dong

To reduce the influence of TGO on EBCs performance, the Yb 2 SiO 5 -Yb 2 O 3 -Si-SiC ceramic was prepared by tape casting and reactive melt infiltration in this paper. During high-temperature water vapor corrosion, the ceramic formed a unique layered oxide layer structure to protect the material. On one hand, TGO is consumed by the reaction of Yb 2 O 3 and Yb 2 SiO 5 with SiO 2 ; On the other, the structure makes no TGO layer between the oxidized and unoxidized regions, which means that even if the TGO layer is stripped, the material still has a dense Yb 2 Si 2 O 7 and Yb 2 SiO 5 mixed layer as a protective barrier.

CAS / MDL: 1314-37-0
研究领域: 材料科学 · 腐蚀与防护
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CERAMICS INTERNATIONAL · 2023 · IF 5.2

Effect of counterpart materials on tribological behaviors of copper impregnated carbon/carbon composite under electric current condition

Kejia Kang,Bo Yu,Guanyu Deng,Pei Wang,Jian Yin,Hongbo Zhang,Guoqiang Luo,Hao Song

Copper impregnated carbon/carbon composite (Cu-C/C composite) was fabricated for novel sliding collector material by weaving carbon fiber, heat treatment and Cu alloy impregnation. The effects of counterpart materials (Fe ball and Cu ball) on friction and wear behaviors were investigated and compared with the result of carbon contact strip used in high-speed railway. Morphology, chemical composition, phase and structure of wear surface and tribolayer were characterized to clarify tribological mechanisms. The results show that friction coefficient follows the order: Cu-C/C composite/Cu ball > carbon contact strip/Fe ball > Cu-C/C composite/Fe ball > carbon contact strip/Cu ball. The carbon crystalline of wear surface appears preferred orientation along the sliding orientation, which is benefit for boundary lubrication . When the counterpart material is Fe ball, Cu-C/C composite is superior to pure carbon strip in mechanical strength , electrical conductivity , wear resistance and friction performance.

研究领域: 材料科学 · 摩擦学
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CORROSION SCIENCE · 2024 · IF 7.4

Significantly improved water-oxygen corrosion resistance of SiC/SiC composite modified by Si-B-Mo-Y using reactive melt infiltration

Keda Xiao,Yi Zeng,Xiang Xiong,Jinrun Hu,Shiyan Chen,Tianyou Li

Si-B-Mo-Y modified SiC/SiC composites were prepared by reactive melt infiltration (RMI) process to study their high-temperature water-oxygen corrosion resistance, and to compare them with SiC/SiC composites prepared by RMI using Si. The results show that the corrosion rates of the modified composites are only 1/9, 1/10 and 1/3 of those of the comparison samples at 1200°C, 1300°C and 1400°C, respectively, which is attributed to the higher densification of the modified composites. More importantly, the modified composites were able to form borosilicates, which effectively healed the oxide film defects; meanwhile, yttrium silicate inhibited the reaction between borosilicates and water vapor.

CAS / MDL: 9003-35-4
研究领域: 材料科学 · 腐蚀与防护
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Additive Manufacturing · 2024 · IF 10.3

Vat photopolymerization of large-aperture high performance SiC mirror through multiphase carbon infiltration modification

Wei Li,Congcong Cui,Shan Li,Ge Zhang,Baojie Jin,Jianxun Bao,Conghui Guo,Yubei Zhang,Bingshan Liu,Gong Wang

Vat photopolymerization technique (VPP) shows advantages in rapidly preparation of complex structure silicon carbide matrix composites (Si/SiC). However, compared with traditional preparation technology, the properties of Si/SiC prepared via VPP are insufficient due to the presence of residual Si and carbon. Herein, the reaction mechanism of Si and carbon were systematically studied. Multiphase carbon was introduced into porous SiC preform via carbon precursor infiltration pyrolysis (CPIP) and graphitization methods. The content of residual Si was significantly decreased after reactive melt infiltration (RMI), and the residual carbon was eliminated through partial graphitization of the carbon. The influence mechanism of the carbon content and crystallinity on the reaction process of Si and carbon was studied. It suggested that the diameter of capillary channel and crystallinity of carbon are the main factors affecting residual carbon content in the final body after RMI. The sample with multiphase carbon achieved the best performance after RMI. The residual Si content, bulk density, flexural strength and elastic modulus are 11.58%, 3.04 g/cm 3 , 280.09 MPa and 355.48 GPa. In addition, the lowest coefficient of linear expansion was 2.39×10 −6 K −1 . Finally, a large-aperture SiC mirror with a diameter of 500 mm was prepared. Therefore, this research lays a foundation for promoting the application of large-aperture Si/SiC prepared via 3D printing .

研究领域: 材料科学 · 光学工程
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JOURNAL OF RARE EARTHS · 2022 · IF 4.632

Enhancement of ionic conductivity and fracture toughness by infiltrating porous Li0.33La0.56TiO3 pellets

Xiaojuan Lu,Mingyang Duan,Jingyu Xiang,Yuning Liang,Songtao Liu

Although solid-state lithium electrolytes have the potential to reduce the safety issues associated with organic liquid electrolytes , disadvantages such as low total conductivity, large interface impedance, and delamination of the interface due to cyclic stress still need to be addressed. The solid-state lithium-ion conductor Li 0.33 La 0.56 TiO 3 (LLTO) was prepared via a hydrothermal route by using CTAB as templates in this paper. Perovskite LLTO with micro-porous channels was obtained and the total conductivity is comparable to the non-porous LLTO. Porous LLTO pellets are infiltrated with the non-porous LLTO precursor solution, and the total conductivities of the infiltrated porous LLTO are all higher than those without infiltration. After infiltration, the porous LLTO calcined at 600 °C achieves the highest total conductivity, 7.88 × 10 −5  S/cm. The fracture toughness of the infiltrated LLTO is higher than that of the non-porous LLTO. The results demonstrate a new way to prepare solid-state lithium-ion conductors with high ionic conductivity and great tolerance to cyclic stress.

研究领域: 材料科学 · 电化学 · 能源存储
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JOURNAL OF ALLOYS AND COMPOUNDS · 2025 · IF 6.3

High strain rate response of nacre-inspired B4C/2024Al composites created via bidirectional freeze casting combined with pressure infiltration

Tongyuan Meng,Zeen Wang,Gui Wang,Bo Li,Ying Xu,Haiying Zhao,Xinhui Gao,Zhaoxin Zhong,Zhanhong Chen,Yang Wang,Yushi Qi,Futian Liu

Bidirectional freeze casting combined with pressure infiltration has demonstrated significant potential as an effective approach for fabricating bioinspired lamellar composites with excellent strength and toughness. However, their dynamic mechanical response remains underexplored. In this study, B 4 C/2024Al composites with long-range ordered nacre-like architectures were fabricated using bidirectional freeze casting followed by pressure infiltration. The mechanical properties and deformation behavior under both quasi-static and dynamic compression conditions were systematically investigated. The results reveal that dynamic compressive strength and strain were significantly higher than their quasi-static counterparts, largely attributed to strain rate hardening and localized matrix melting. Compared to unidirectionally structured composites, the bidirectionally structured ones exhibited superior mechanical performance, achieving a maximum compressive strength of 1088.6 MPa at a strain rate of 3000 s −1 (40 vol% B 4 C/2024Al composite). A clear dependence of flow stress and energy absorption capability on B 4 C volume fraction was observed. As B 4 C content increased, the compressive strength rose, but dynamic strain energy density showed a decreasing trend beyond 20 vol% due to reduced ductility. Specifically, the energy density peaked at 133.08 MJ/m 3 for the 20 vol% composite and declined with further ceramic addition, indicating a trade-off between strength and impact energy absorption. The enhanced toughness under dynamic loading is primarily attributed to adiabatic shear localization in the aluminum matrix, which facilitates localized softening and strain accommodation. Additional contributions include crack deflection and branching within the hard ceramic layers, as well as plastic deformation and thermal softening-induced toughening mechanisms in the metallic phase. These findings highlight the promise of nacre-inspired B 4 C/Al composites for advanced lightweight armor systems, offering an optimized balance between strength, toughness, and energy absorption under high-strain-rate loading.

CAS / MDL: 75-59-2
研究领域: 材料科学 · 机械工程 · 复合材料 · 仿生材料 · 动态力学行为
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