ACS Applied Materials & Interfaces
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2022
·
IF 10.383
Guoqiang Lu,Hengda Yuan,Jiulei Zhou,Fuping Chen,Chao Li,Tanlong Xue,Xin Shu,Yingying Zhao,Jun Nie,Xiaoqun Zhu
Liquid conductor-based flexible sensors with high mechanical deformability and reliable electrical reversibility have aroused great interest in electronic skin, soft robotics, environmental monitoring, and other fields. Herein, we develop a novel strategy to fabricate liquid conductor-based flexible sensors by combining ionic liquid-based magnetofluids (IL-MFs), magnetic printing, and photopolymerization techniques. The as-prepared sensors exhibit excellent electromechanical properties, such as a wide detection range, low hysteresis, fast response time, good durability, etc. Moreover, the gauge factors (GFs) of the sensor could be easily adjusted by changing the modulators with different line widths or patterns, and the strain sensors can also be designed for anisotropic monitoring. Apart from serving as strain sensors, the magnetofluid-based flexible sensors can be used to detect external pressure, human activities, and changes in temperature, illumination, and magnetic field as well. This work provides a facile strategy to fabricate liquid conductor-based multifunctional sensors. Such a magnetofluid-based sensor has a great promising future.
研究领域:
材料科学
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电子工程
✓ 已验证
产品关联
DOI
PubMed
高影响因子
SEPARATION AND PURIFICATION TECHNOLOGY
·
2021
·
IF 7.312
Fangfang Su,Xiaoqian Li,Yudeng Wang,Zhongjie He,Ling Fan,Hongni Wang,Jinliang Xie,Yaping Zheng,Dongdong Yao
Porous liquids (PLs) are a type of porous materials that combine the porosity of solids and fluidity of liquids, which has attracted widespread attention. In this paper, we report a new TypeⅠhollow carbon sphere-based porous liquids, which are constituted of hollow carbon sphere (HCS) as the porous host, polymeric ionic liquid (PILs) as the corona and poly(ethylene glycol) 4-nonylphenyl 3-sulfopropyl ether potassium salt (PEGS) as the canopy. The viscosity of PLs is 8900 mPa·s at 50 ℃ (like syrup), which has good fluidity. Under 3 MPa pressure conditions, the best CO 2 adsorption capacity of 450-P[VHIm]Br-PEGS and 450-P[VBBI]Cl-PEGS are 2.06 and 1.90 mmol/g at 25 °C, respectively, higher than PILs-PEGS. Under the same conditions, the CO 2 adsorption capacity of PLs is 10.5 times higher than that of N 2 . Therefore, HCS-based PLs have the potential for CO 2 /N 2 selective gas separation. Not only PILs and the anionic alkyl chain of the outer layer widen the liquid range of PLs, but also is suitable for preparing PLs with other cavity units.
研究领域:
材料科学
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环境科学
✓ 已验证
产品关联
DOI
高影响因子
Journal of Environmental Chemical Engineering
·
2025
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IF 7.2
Zhiwei Dong,Yudong Ding,Hong Wang,Min Cheng,Xun Zhu,Qiang Liao
Combining the fluidity of ionic liquids (ILs) with the permanent porosity of metal-organic frameworks (MOFs), type III porous liquids (type III-PLs) demonstrate exceptional catalytic activity for CO 2 capture and cycloaddition reactions. The ZIF-8-based type III-PLs (ZIF-8/1-methyl-3-propylimidazolium bromide ([PMIm]Br)) catalysts achieved a 50.39 % increase in CO 2 conversion and a styrene carbonate yield of 93.08 % at 80 °C and 1.0 MPa. DFT calculations revealed a synergistic effect of ZIF-8/[PMIm]Br catalysts: The Zn active sites in ZIF-8 lowered the energy barriers for epoxide ring opening and CO 2 insertion, while [PMIm]Br provided nucleophilic sites to facilitate the reaction. Additionally, molecular dynamics simulations showed enhanced CO 2 diffusion at the gas-liquid interface in the ZIF-8/[PMIm]Br system, accelerating the reaction rate. This study offers theoretical insights for designing more efficient type III-PLs catalysts for the industrial utilization of CO 2 as a C1 resource.
研究领域:
化学
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催化材料
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环境科学
✓ 已验证
产品关联
DOI
高影响因子
Petroleum Science
·
2025
·
IF 6.1
Jia-Jun Dai,Kai-He Lv,Jin-Sheng Sun,Han Jia,Xian-Bin Huang,Jian Li
A B S T R A C T Ionic liquids (ILs), recognized for their negligible vapor pressure, thermal stability, and structural tailorability, offer targeted inhibition of clay expansion. Compared to ILs, polyionic liquids (PILs) possess stronger mechanical properties and adsorption capabilities, showing even greater potential in inhibiting clay swelling. In this work, we synthesized and characterized an imidazole-based ionic liquid (IL-NH 2 ), a polyionic liquid (PIL-ABHIm), and a PIL/IL combination. Their inhibitory performance was rigorously evaluated under simulated drilling conditions through immersion tests, linear swelling tests, among others. Additionally, the mechanisms underlying their interaction with clay minerals were elucidated through contact angle measurements, Fourier-transform infrared spectroscopy, X-ray diffraction (XRD), Zeta potential analysis, and molecular electrostatic potential (MEP) analysis. This work demonstrates that IL-NH 2 inhibits osmotic hydration by altering the interlayer structure of the clay, while PIL-ABHIm reduces surface hydration by forming a hydrophobic barrier on the clay surface. PIL/IL combines both mechanisms, significantly enhancing the stability of clay through the dual mechanisms of cation exchange and hydrophobic barriers. These findings reveal an innovative mechanism by which PIL/IL combination inhibits clay hydration and swelling, providing a scientific foundation for their application in drilling fluids.
研究领域:
石油工程
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材料科学
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表面化学
✓ 已验证
产品关联
DOI
高影响因子
CHEMICAL ENGINEERING RESEARCH & DESIGN
·
2023
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IF 3.9
Gongran Ye,Mingxi Ye,Xilei Wu,Yuhao Yan,Hongsheng Ouyang,Xiaohong Han
Reclamation of mixed refrigerants can effectively reduce high global warming potential (GWP) fluorinated gases (F-gases) emissions. Two organic liquids (OLs), Dimethylformamide (DMF) and N, N-Dimethylacetamide (DMAC), were proposed to explore the possibility of separating high GWP and near-azeotropic mixture R410A (50 wt% R32 (difluoromethane) + 50 wt% R125 (pentafluoroethane)) by absorption. Solubilities of R125 in DMF and DMAC were measured from 283.15 to 333.15 K and well correlated with the five-parameter non-random two-liquid (NRTL) activity coefficient model. Ideal selectivity for R32 + R125 of DMAC were higher than that of DMF. Five ionic liquids (ILs) and DMAC on the Pareto front showed good overall performance (integration of capacity and selectivity) for separating R410A, and in the area below the Pareto front, the overall performances of the other solvents were not as good as those from the Pareto front. Subsequently, based on DMAC, 1-butyl-3-methylimidazolium hexafluorophosphate ([BMIM][PF 6 ]), 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)amide ([EMIM][Tf 2 N]) and 1-ethyl-3-methylimidazolium thiocyanate ([EMIM][SCN]), the extractive distillation processes for R410A separation were simulated and evaluated in Aspen Plus. Results showed DMAC was a suitable choice of extractant nowadays due to the lower viscosity and consumption than ILs and the mature corresponding R410A separation process. ILs may be the mainstream extractant for R410A separation in the future, once the price of some ILs such as [BMIM][PF 6 ] can be reduced to $30/kg, the separation process using ILs as extractants will cost less than that of DMAC. Heat pump technology can be further applied for energy integration in the corresponding process of ILs with high ideal selectivity such as [EMIM][SCN]. Thermodynamic and economic analysis of OLs and ILs could provide the key information for the separation of commercial refrigerant R410A, which can also be used as a benchmark to screen more efficient extractants.
研究领域:
化学工程
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环境科学
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
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2016
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IF 2.822
Yaofang Xuan,Lisiqi Xie,Xiao Huang,Bin Su
Liquid/liquid interface electrochemistry has manifested itself as a good approach to study oxygen reduction reaction (ORR) and ORR catalyzed by various catalysts. In this work, we investigated the ORR catalyzed by iron(II) phthalocyanine (FePc), which has a structure similarity to the heme group of O 2 -binding proteins and reducing enzymes, at the polarized water/1,2-dichloroethane interface. Using the four-electrode cyclic voltammetry and the shake-flask biphasic reaction under chemically controlled polarization, it was demonstrated that FePc could catalyze the molecular oxygen reduction by lipophilic electron donors , such as 1,1′-dimethylferrocene (DFc) or tetrathiafulvalene (TTF), at the heterogeneous phase boundary . The overall process essentially can be equivalent to an interfacial proton transfer coupled ORR, which proceeds preferentially via a four electron reduction pathway to produce mainly H 2 O with only minority of H 2 O 2 (less than 5%). The catalytic activity of FePc was compared with all previously studied porphyrins and phthalocyanines. The reaction mechanism was also analyzed, in which a hydroperoxo intermediate was probably involved.
研究领域:
电化学
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催化化学
✓ 已验证
DOI
高影响因子
Science China-Chemistry
·
2013
·Vol. 57
·期 3
·397-401
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IF 1.327
Zhang QiBo,Hua YiXin,Wang Rui
Direct electroreduction of solid cuprous chloride to prepare copper powder in a “neutral” ambient-temperature ionic liquid, 1-butyl-3-methylimidazolium tetrafluoroborate ionic liquid (BMIMBF 4 ) was investigated. Cyclic voltammetry of the CuCl powder in a Pt-powder cavity microelectrode exhibited that solid CuCl can be electrochemical reduced in the ionic liquid. Chronoamperometry of the salt powder filled Mo-cavity electrode (current collector) in the ionic liquid further demonstrated the conversion of chloride-to metal inside the cavity, as confirmed by scanning electron microscopy, energy-dispersive X-ray, and X-ray diffraction spectra.
研究领域:
电化学
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材料科学
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无机化学
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绿色化学
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冶金工程
✓ 已验证
DOI
高影响因子
CHEMICAL ENGINEERING JOURNAL
·
2019
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IF 8.355
Shaojuan Zeng,Junli Wang,Pengfei Li,Haifeng Dong,Hui Wang,Xiaochun Zhang,Xiangping Zhang
The emerging of ionic liquids (ILs) provides a promising way to efficiently separate ammonia (NH 3 ) and simultaneously recover NH 3 due to their negligible volatility, good affinity with NH 3 and designable structures. However, the relatively high viscosities of ILs and the limited gas-liquid interface severely affect gas diffusion in ILs, which hinders their practical use in industries. In this work, in order to overcome the mass-transfer limitations of ILs in gas separation, three metal ILs (MILs), [Bmim] 2 [CuCl 4 ], [Bmim] 2 [NiCl 4 ] and [Bmim] 2 [Co(NCS) 4 ], with good affinity toward NH 3 were incorporated into porous silica gels with large surface area and abundant hydroxyl groups, by an impregnation-vaporization method to form novel MIL@silica gel composites for rapid, efficient and reversible adsorption of NH 3 . The FT-IR and BET results indicated that the prepared adsorbents with different loadings of MILs are mesoporous composites. The [Bmim] 2 [Co(NCS) 4 ]@silica gel composites not only show much higher NH 3 capacity and NH 3 selectivity than pristine silica gel and faster adsorption rate than the corresponding pure MILs, but also exhibit excellent reversibility. The highest capacity of NH 3 adsorption up to 99.808 mg NH 3 ·(g adsorbent) −1 in 15 min was obtained when the loading of [Bmim] 2 [Co(NCS) 4 ] in the MIL@silica gel composite was 48.89 wt%, which could be attributed to the synergistic interaction of the complexation and hydrogen bonding between cobalt coordinated anion and NH 3 as well as mesoporous structures. Moreover, the NH 3 absorbed by the [Bmim] 2 [Co(SCN) 4 ]@silica gel can be completely released in 15 min, and no obvious losses in NH 3 capacity were detected during five adsorption and regeneration cycles, indicating great potentials as adsorbents for NH 3 separation applications.
研究领域:
化学工程
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材料科学
✓ 已验证
DOI
高影响因子
IONICS
·
2015
·Vol. 21
·期 9
·2567-2574
·
IF 1.754
Liu Guishen,Ma Yanhui,Hou Xiaodong,huang Yina,Chen Jianpeng,Zhan Guoqing,Li Chunya
1-[3-(N-Pyrrole)propyl]-3-[1-tert-butoxy-carbonylamino-propyl]imidazolium tetrafluoroborate ionic liquid was successfully synthesized and characterized. The ionic liquid was electrochemically polymerized onto a glassy carbon electrode surface using a multi-potential step technique. Morphology and electrochemical properties of the polymerized ionic liquid film electrode were studied with scanning electronic microscopy and electrochemical impedance spectroscopy. Using the polymerized ionic liquid film as a sensing platform, electrochemical behaviors of magnolol were investigated by voltammetry. Under optimal experimental conditions, the oxidation peak currents were linearly related to magnolol concentrations in the range from 5.0 × 10 −8 to 1.0 × 10 −5 mol L −1 . The detection limit calculated from the standard deviation of the intercept was 2.3 × 10 −7 mol L −1 . Practical application of the polymerized ionic liquid film electrode was demonstrated by determining magnolol in the traditional Chinese medicine. The result is consistent with that obtained using high performance liquid chromatography.
Polymerized ionic liquid film electrode fabricated with potential step technique and application in voltammetric sensing of magnolol
研究领域:
分析化学
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电化学
✓ 已验证
产品关联
DOI
高影响因子
RSC Advances
·
2016
·Vol. 6
·期 43
·37110-37117
·
IF 3.289
Mingjuan Han,Zheng Gu,Chong Chen,Zuowang Wu,Yigen Que,Qiang Wang,Hui Wan,Guofeng Guan
A new, simple and effective strategy to confine dicationic acid ionic liquids (DAILs, 1,4-bis[3-(propyl-3-sulfonate) imidazolium] butane hydrogen sulfate) in the cages of MIL-100(Fe) frameworks was constructed. The target catalyst, defined as MIL-100(Fe)@DAILs, was characterized by XRD, FTIR, SEM, TEM, EA, TGA and N2 adsorption–desorption. Meanwhile, the catalytic activity of the MIL-100(Fe)@DAILs catalyst was evaluated by the esterification reaction with oleic acid and methanol. The results indicated that the DAILs had been effectively encapsulated within the cages of the MIL-100(Fe) frameworks. Moreover, the influence of reaction time, reaction temperature, molar ratio of methanol to oleic acid and catalyst dosage on the conversion of oleic acid was studied by univariate analysis. The conversion of oleic acid decreased from 93.5% to 86.0% when the catalyst was reused five times, which indicated that the target catalyst possessed higher catalytic activity and superior catalytic activity. Finally, an esterification mechanism catalyzed by this novel catalyst was illustrated.
研究领域:
化学工程
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催化材料
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可再生能源
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF CHEMICAL AND ENGINEERING DATA
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2013
·
IF 2.004
Duan-Jian Tao,Zheng Cheng,Feng-Feng Chen,Zhang-Min Li,Na Hu,Xiang-Shu Chen
Nowadays the knowledge of thermodynamic properties for amino acid ionic liquids (AAILs) has been paramount for the design of many chemical processes. In this present work, a series of cholinium-based AAILs ([Ch][AA]) were synthesized by neutralization of choline hydroxide solution with five amino acids and then were characterized by 1H NMR, Fourier transform infrared (FT-IR), elemental analysis, thermogravimetry, and differential scanning calorimetry (DSC) analysis. Physico-chemical properties such as density, viscosity, refractive index, and conductivity were measured and correlated with the empirical equations in a wide temperature range. The thermal expansion coefficient values were also calculated from the acquired experimental density values. From the experimental data, it was found that the density, viscosity, and refractive index decreased while conductivity increased with the increase of temperature. The correlation results were proposed to be in good agreement with the experimental data, and optimal fitting parameters were presented. In addition, the coefficient of thermal expansion was considered to be independent of temperature in the range of (298.15 to 353.15) K.
研究领域:
化学工程
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材料科学
✓ 已验证
产品关联
DOI
高影响因子
AICHE JOURNAL
·
2024
·
IF 3.5
Dongyu Jin,Wenyu Ge,Zhiyong Zhou,Yuming Tu,Chenchan Du,Zhongqi Ren
Porous liquids (PLs) with unique porous frameworks and good flow properties can achieve coupling enhancement for CO 2 capture and conversion. In this paper, a series of novel PLs were designed and synthesized using UiO-66 as the framework and novel bi-cationic ionic liquids (ILs) as an excluded solvent. The prepared PLs showed significant improvement in CO 2 uptake capacity over ILs at different pressures and exhibited excellent CO 2 catalytic conversion performance, exceeding the sum of the effects of ILs and UiO-66. Especially at low pressure, the PLs still showed excellent catalytic performance, but the catalytic performance of the corresponding ILs was significantly reduced, which was due to the rapid adsorption and conversion of CO 2 by the porous framework of UiO-66 to improve the CO 2 uptake and transfer efficiency within the ILs, thus achieving coupling enhancement. It can provide a new way to realize the efficient conversion of CO 2 under milder conditions.
研究领域:
化学工程
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材料科学
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环境科学
✓ 已验证
产品关联
DOI
高影响因子
危险品化学品经营许可证（带存储）