As arable land has become an important sink for cadmium (Cd), soil is being recognized as a major source of metals to the food chain. It becomes, therefore, essential to investigate metal mobility in contaminated soils and to identify suitable remediation strategies. For this, immobilization of Cd was evaluated in contaminated stagnic anthrosol: S1, gleysol : S2 and fluvisol: S3 under flow through conditions. Ten treatments including control were tested alone or in composite form firstly at natural Cd contents (0.58–0.69 mg kg −1 ). Here, T2 (lime), T5 (biochar) and T10 (composite amendment) were found better in reducing the Cd concentration in the soils’ leachates, so, their efficacy was further investigated in the same soils of higher Cd contents (1 and 2 mg kg −1 imposed by soil spiking). Amendments significantly reduced the leachate metal contents especially in 1 mg kg −1 spiked soils. Characterization of T2, T5 and T10 revealed their structural transformations in all the studied soil types, while active functional groups e.g. C–O, C O, O–H, Si–O–Si, ester and alcoholic groups were notably involved in Cd precipitation or adsorption on amendments surface. Variations in Cd speciation in these soils exhibited the exchange of Cd to more stable fractions with tested amendments. These continuous-flow experiments confirmed the strong efficiency of T2, T5 and T10 in reducing the Cd concentration in the leachate of three soils. This study has strong implications in understanding the role of different amendments in controlling the fate, leaching behavior and immobilization of Cd in diverse soil types.
Rapid, convenient, and sensitive detection of Bisphenol A (BPA) in complex environmental samples without the need for tedious pre-treatment is crucial for assessing potential health risks. Herein, we present an electrochemical sensing platform using a simple nanochannel-modified electrode, which enables the direct and sensitive detection of BPA in complex samples. A vertically ordered mesoporous silica-nanochannel film (VMSF) with high-density nanochannels is rapidly and stably grown on the surface of a electrochemically activated glassy carbon electrode (p-GCE) by using the electrochemically assisted self-assembly (EASA) method. The high antifouling capability of the VMSF/p-GCE sensor is proven by investigating the electrochemical behavior of BPA in the presence of model coexisting interfering molecules including amylum, protein, surfactant, and humic acid. The VMSF/p-GCE sensor can sensitively detect BPA ranged from 50 to 1.0 μM and 1.0–10.0 μM, with low detection limits (15 nM). Owing to the electrocatalytic performance and high potential resolution of p-GCE, the sensor exhibits high selectivity for BPA detection in the presence of common environmental pollutants, including bisphenol S (BPS), catechol (CC), hydroquinone (HQ), and 4-nitrophenol (4-NP). In combination with the good antifouling property of the VMSF, direct detection of BPA in environmental water samples and soil leaching solution (SLS) is also realized without separation pretreatment. The developed VMSF/p-GCE sensor demonstrated advantages of simple structure, high sensitivity, good antifouling performance, and great potential in direct electroanalysis of endocrine-disrupting compounds in complex samples.
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