Nanomaterials
·
2019
·Vol. 9
·期 7
·1051
·
IF 4.034
Xiu Wang,Zhihuai Yu,Liang Jiao,Huiyang Bian,Weisheng Yang,Weibing Wu,Huining Xiao,Hongqi Dai
Hexagonal boron nitride (h-BN)-based heat-spreading materials have drawn considerable attention in electronic diaphragm and packaging fields because of their high thermal conductivity and desired electrical insulation properties. However, the traditional approach to fabricate thermally conductive composites usually suffers from low thermal conductivity, and cannot meet the requirement of thermal management. In this work, novel h-BN/cellulose-nano fiber (CNF) composite films with excellent thermal conductivity in through plane and electrical insulation properties are fabricated via an innovative process, i.e., the perfusion of h-BN into porous three dimensional (3D) CNF aerogel skeleton to form the h-BN thermally conductive pathways by filling the CNF aerogel voids. When at an h-BN loading of 9.51 vol %, the thermal conductivity of h-BN/CNF aerogel perfusion composite film is 1.488 W·m−1·K−1at through plane, an increase by 260.3%. The volume resistivity is 3.83 × 1014Ω·cm, superior to that of synthetic polymer materials (about 109~1013Ω·cm). Therefore, the resulting h-BN/CNF film is very promising to replace the traditional synthetic polymer materials for a broad spectrum of applications, including the field of electronics.Keywords:CNF aerogel;perfusion;h-BN;thermal conductivity;electrical insulation
研究领域:
材料科学
·
电子工程
✓ 已验证
产品关联
DOI
PubMed
高影响因子
JOURNAL OF ALLOYS AND COMPOUNDS
·
2018
·
IF 3.779
Jian-Zheng Zhen,Jian-Xiong Liu,Tian-You Chen,Feng Shi,Yong-Nian Dai,Bin Yang,Yun-Fei Li,Xiao Wang,Ting-Gu Nong,Yu-Qi Hu,Jin Shi
Developing of high efficient electrode materials for CO 2 reduction is very important in CO 2 conversion and recycling utilization. In this work, we have fabricated ZnS/Zn electrode using sulphur infiltration method. This method is a well-developed technology in surface treatment. ZnS/Zn electrode fabricated via sulphur infiltration method has a crucial advantage: because sulfur atomic is infiltrated into Zn substrate, a translation layer is formed and sandwiches between ZnS layer and Zn substrate. As a result, ZnS connects with Zn substrate firmly, and the exfoliation of ZnS layer from Zn substrate is avoided. The ZnS/Zn has been investigated as the cathode for CO 2 electro-reduction in propylene carbonate/tetrabutylammonium perchlorate (PC/TBAP) in membrane electrolysis cell. The current density of potentiostatic electrolysis remains stable at 6.72 mA/cm 2 at voltage −2.4 V and the faradaic efficiency of CO formation reaches to 92%. Comparing with Zn electrode, ZnS/Zn exhibits higher catalytic activity.
研究领域:
材料科学
·
电化学
✓ 已验证
DOI
高影响因子
Journal of Materials Chemistry C
·
2018
·Vol. 6
·期 24
·6494-6501
·
IF 5.976
Yuming Wu,Kai Ye,Zhiduo Liu,Mengjie Wang,Kuan W. A. Chee,Cheng-Te Lin,Nan Jiang,Jinhong Yu
Materials with superior thermal conduction, stable electrical insulation, and excellent mechanical strength that can be obtained at low cost are desirable for electronic packaging and thermal management in electrical engineering systems. There is therefore relentless interest in developing highly robust thermally conductive and electrically insulating polymer-based composites. Herein, a facile and environmentally friendly method to construct three-dimensional thermal transport channels in a poly(vinyl alcohol) (PVA) matrix composite is reported. The formation of thermal transport highways improves the thermal conductivity up to 4.79 W m−1 K−1 for alumina (Al2O3) loading of 45.4 vol% in the composites. The thermal conductivity achieved is the highest value for this Al2O3 content range compared with reported work, and is 1700% compared with that of pure PVA. In the meantime, the composites still retain outstanding electrical insulation properties and excellent mechanical strength. The heat-conducting and electrically insulating composites not only have promising applications in electronic packaging and electrical engineering systems, but the technically facile vacuum-assisted infiltration method is a new avenue for the mass production of spherical filler/polymer composites.
研究领域:
材料科学
·
电子工程
✓ 已验证
DOI
高影响因子
CERAMICS INTERNATIONAL
·
2024
·
IF 5.1
Kai Sun,Lin Wang,Guoliang Wei,Qiang Zhang,Zengyan Wei,Hang Su,Jiayi Geng,S.V. Shil'ko,Gaohui Wu
In this study, one-piece glass cenospheres/aluminum core sandwich is prepared using a pressure infiltration method. In comparison to adhesive bonding, the layers combined by metallurgical bonding are straight and smooth, and the sandwich shows high shear stress of 80.4 MPa. The failure mode is analyzed through a combination of mises stress distribution simulated using the finite element analysis and in-situ strain distribution obtained from a digital image correlation system. After cracks initiated at interfaces, they propagate to nearby layers in the sandwich structure, which can delay the shear failure by avoiding significant damage of core layer.
研究领域:
材料科学
·
力学工程
✓ 已验证
DOI
高影响因子
CERAMICS INTERNATIONAL
·
2019
·
IF 3.45
Guoqing An,Hongli Liu,Hongyan Li,Zhong Chen,Jing Li,Yajing Li
The SiBCN ceramic aerogel/graphene composites were synthesized by combining a simple sol-gel infiltration process with CO 2 supercritical drying technology and polymer-derived ceramics route. In order to select the best preceramic sample for sintering, the micromorphology of PSNB aerogel/graphene composites fabricated with different graphene oxide solution concentrations were investigated. The microstructure evolution of the prepared SiBCN ceramic aerogel/graphene composites and phase composition were studied by SEM, TEM and XRD , the pore structure of the preceramic composites pyrolyzed at 1200 °C was tested by specific surface area and pore size analyzer. Furthermore, the compressive strain-stress curve and toughening mechanisms of composites were also investigated in detail. The results showed that all the preceramic composites and obtained ceramic aerogel composites possessed the mesoporous structure. The basic structure of SiBCN aerogel network changed from the initial spherical particles accumulation to the nanowires lapping with the sintering temperature increased from 800 °C to 1200 °C. After pyrolyzing at 1200 °C, the specific surface area and pore volume for the sample were 101.61 m 2 g −1 and 1.43 cm 3 g −1 , respectively, and a small amount of β-SiC crystalline phases were formed in amorphous ceramic matrix and had an relatively uniform distribution. Moreover, the paepared ceramic aerogel composites possessed a certain degree of toughness, the toughening mechanisms of composite samples mainly included the crack deflection, graphene pull-out, graphene bridging and graphene crumpling.
研究领域:
材料科学
·
陶瓷材料
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纳米技术
✓ 已验证
产品关联
DOI
高影响因子
MEASUREMENT SCIENCE and TECHNOLOGY
·
2024
·Vol. 35
·期 4
·045109
·
IF 2.7
Xiaoming Wang,Zhilong Guo,Yifeng Huang,Longbo Xiong,Daojin Yao,Wentao Dong
Strong winds can make a bridge's cable-stayed cables produce violent vibrations, leading to fatigue of the cable-stayed cables and damaging the cable-stayed bridge's structure. Accurately and effectively obtaining data on the wind loads applied to the cable-stayed cables is important for assessing the cable-stayed cables' health. The existing sensing elements for detection include diffusion silicon piezoresistive sensor, strain gauge, and other rigid sensors. However, most of them present such disadvantages as rigidity, difficult to fit the curved surface, high cost and low sensitivity. And it cannot be directly installed on the surface of the cable. In this paper, a conductive hydrogel flexible pressure sensor based on TA/CB@PDMS was developed, using carbon black (CB) as the main conductive medium, with good electrical conductivity, high sensitivity (0.65 kPa−1) and excellent tensile properties (210% tensile breakage). Meanwhile, a salt permeation method (Soak the sensor in LiBr solution) was used to effectively inhibit the sensor's water from being evaporated and frozen. Its substrate incorporates tannic acid to increase the sensor's adhesion so that it adheres well to the diagonal cable's surface. In this paper, the wind speed variation around the diagonal cable and the force distribution on the surface with considering the fluid-structure coupling effect are analyzed by ANSYS WORKBECH finite element simulation. Wind tunnel experiments simulate the sensor's force response when the inclined cable is subjected to different wind speeds, and the detection accuracy reaches 96.17%. The results show the sensor developed in this paper can realize accurate wind pressure detection of the inclined cable. This study provides a new method for wind pressure detection and health inspection of diagonal cables.
研究领域:
土木工程
·
材料科学
·
传感技术
·
结构健康监测
✓ 已验证
DOI
高影响因子
CARBOHYDRATE POLYMERS
·
2024
·
IF 10.7
Xiaochen Zhang,Jiahong Jian,Zisheng Luo,Guo Li,Yifeng Huang,Yue Wu,Dong Li,Li Li
The fabrication of multi-component film with colloidal particles could be inconvenient. A novel “swell-permeate” (SP) strategy was proposed to form homogeneous multi-component films. The SP strategy allows colloidal particles to fit into the polymer network by stretching the polymer chains assisted by water. We demonstrated the strategy by creating films with polysaccharide substrates as β-cyclodextrin grafted chitosan (CS) with nanocellulose. The addition of nanocellulose significantly increased the mechanical properties and the barrier performance of the films. The size of nanocellulose particles in affecting mechanical properties was investigated by applying different length of cellulose nanocrystal (CNC), the longer of which, due to denser physical entanglements, showed a better increase to the film in the elastic modulus and tensile strength to 4.54-fold and 5.71-fold, respectively. The films were also loaded with ethyl- p -coumarate (EpCA) and had an enhanced performance in anti-microbial for Altenaria alternata , Salmonella typhi , and Escherichia coli . The anti-oxidative property was increased as well, and both effects were valid both in vitro and in ready-to-eat apples. The strategy provides a practical and convenient method for fabricating colloidal particle containing films, and the novel idea of “swell-permeate” is potentially regarded as a new solution to the challenge of ready-to-eat food quality maintenance.
研究领域:
材料科学
·
食品科学
·
生物技术
✓ 已验证
产品关联
DOI
PubMed
高影响因子
危险品化学品经营许可证（带存储）