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PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE · 2017 ·Vol. 214 ·期 11 ·1700538 · IF 1.775

Solution-Processable Methyl Ammonium Lead Iodide Single Crystal Photodetectors for Visible Light and X-Ray

Peihua Wangyang,Hui Sun,Xinghua Zhu,Dingyu Yang,Xiuying Gao,Wenyi Liu,Yan Chen,Haibo Tian,Sibo Huanglong

A promising photodetector based on CH 3 NH 3 PbI 3 single crystal under visible light and X-ray irradiation is reported. The CH 3 NH 3 PbI 3 crystal grown by inverse temperature crystallization acts as the absorber material directly converting visible light and the impinging X-ray photons to electron hole pairs, respectively. The underlying photoelectric response mechanism behind the observation under visible light and X-ray irradiation is carefully discussed. Remarkably, the perovskite detectors demonstrate a good air-exposure stability for more than 2 months with encapsulation. The results demonstrate that the CH 3 NH 3 PbI 3 single crystal has a great potential for application in the visible light and X-ray detection.

研究领域: 材料科学 · 凝聚态物理 · 核医学 · 生物医学工程 · 辐射检测 · 半导体器件
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Advanced Intelligent Systems · 2019 ·Vol. 1 ·期 3 ·1900022 · IF 0

Solution-Processed Polymer Thin-Film Memristors with an Electrochromic Feature and Frequency-Dependent Synaptic Plasticity

Yang Feng,Xu Gao,Ya-Nan Zhong,Jia-Ling Wu,Jian-Long Xu,Sui-Dong Wang

Emerging organic synaptic devices are promising in exploring soft and biocompatible neuromorphic computing systems. By means of a simple and low-cost solution process, the polymer thin-film memristors are designed and characterized. The polymer memristors have a bilayer structure composed of an ion-rich semiconducting layer and an ion-collecting conducting layer, where the ion redistribution depending on device operation history has an impact on carrier concentration and results in the memristive characteristics. A visible electrochromic feature is observed during the electrical measurements, supporting the proposed Li + ion drift/diffusion mechanism. The polymer memristors show the continuous and reversible conductivity tuning with a temporary memory effect, which enables the successful emulation of the frequency-dependent synaptic plasticity. The polymer thin-film memristors may offer a strategy for developing building blocks of organic neuromorphic circuits.

研究领域: 生物电子学 · 神经形态工程 · 有机电子学 · 分子器件 · 生物医学工程
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Small · 2017 ·Vol. 13 ·期 25 ·1700364 · IF 8.643

Low-Voltage Photodetectors with High Responsivity Based on Solution-Processed Micrometer-Scale All-Inorganic Perovskite Nanoplatelets

Xuhai Liu,Dejian Yu,Fei Cao,Xiaoming Li,Jianping Ji,Jun Chen,Xiufeng Song,Haibo Zeng

All-inorganic photodetectors based on scattered CsPbBr 3 nanoplatelets with lateral dimension as large as 10 µm are fabricated, and the CsPbBr 3 nanoplatelets are solution processed governed by a newly developed ion-exchange soldering mechanism. Under illumination of a 442 nm laser, the photoresponsivity of photodetectors based on these scattered CsPbBr 3 nanoplatelets is as high as 34 A W −1 , which is the largest value reported from all-inorganic perovskite photodetectors with an external driven voltage as small as 1.5 V. Moreover, the rise and fall times are 0.6 and 0.9 ms, respectively, which are comparable to most of the state-of-the-art all-inorganic perovskite-based photodetectors. All the material synthesis and device characterization are conducted at room temperature in ambient air. This work demonstrates that the solution-processed large CsPbBr 3 nanoplatelets are attractive candidates to be applied in low-voltage, low-cost, ultra highly integrated optoelectronic devices.

研究领域: 材料科学 · 光电子学 · 纳米科技 · 半导体器件 · 凝聚态物理
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Physica Status Solidi-Rapid Research Letters · 2020 ·Vol. 14 ·期 4 ·1900723 · IF 2.291

Nanowire Junction Induced High Threshold Voltage in Poly(3-hexylthiophene) Mesoscale Crystalline Thin-Film Transistors with Significantly Enhanced Mobility

Yadan Deng,Jingzan Jiang,Jun Sun,Yufeng Hu,Qiuhong Cui,Zhenbo Deng,Zhidong Lou,Yanbing Hou,Feng Teng

Fabrication of nanowires in polymer films can dramatically enhance the mobility of thin-film transistors (TFTs). Unlike the popular method of forming nanowires after spin-coating films, here a water-bath method to fabricate the micrometer-long nanowires in the poly(3-hexylthiophene) (P3HT) solution is introduced, which is suitable for large-area printing electronic application. The resulting transistor exhibits significantly enhanced mobility and excellent device stability. However, the threshold voltage of the device is increased, compared with the amorphous film device. The underlying mechanism of the mesoscale crystalline induced threshold voltage increase has been rarely studied. The temperature-dependent characteristics imply that the activation energy of the device with nanowires is higher than that of the amorphous one, indicating nanowires can introduce deep traps. This suggests that the charge transport is mainly limited by the deep traps at the junctions between the nanowires considering the trap density inside the nanowires is significantly low. The deep traps introduced by the junctions can increase the threshold voltage as the device needs higher voltage to fill these traps in the channel before the device is turned on. This explains why the devices with nanowires have an increased threshold voltage while their mobilities are dramatically enhanced.

研究领域: 材料科学 · 凝聚态物理 · 有机电子学 · 薄膜晶体管 · 半导体器件物理
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