JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
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2021
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IF 5.302
Xiaohui Li,Xiaoyi Chen,Bo Gao,Yanwei Fan,Yige Wang,Xin Kang,Wenwen Kong,Aimin Chang
A series of novel negative temperature coefficient thermistor materials based on SrCe x Nb x WO 4+4x (0.1 ≤ x ≤ 0.8) ceramics was synthesized by the solid-state route. X-ray diffraction, scanning electron microscopy, and X-ray photoelectron spectroscopy revealed that the SrCe x Nb x WO 4+4x ceramics were composed of scheelite structural solid solution based on the SrWO 4 phase and a CeNbO 4.08 secondary phase that exhibited a fergusonite structure. The resistance-temperature analysis demonstrated that the resistivity ρ 800 of the SrCe x Nb x WO 4+4x ceramics decreased from 8.25 ± 0.08 × 10 6 to 2.52 ± 0.11 × 10 2 with the increase of x value, along with a decrease in the thermal constant B from 11,102 ± 97–4137 ± 37 K. It was observed that the SrCe x Nb x WO 4+4x ceramics exhibited high resistivity and excellent aging characteristics as well as suitable B values at elevated temperatures, making it a promising candidate that can be used for the fabrication of high-temperature NTC thermistors with a wide operating temperature range.
研究领域:
材料科学
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电子工程
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
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2021
·
IF 5.302
Xiaoyi Chen,Xiaohui Li,Bo Gao,Wenwen Kong,Pengjun Zhao,Aimin Chang
A novel negative temperature coefficient material based on lanthanum zirconate ceramics was proposed for high-temperature applications. This material was synthesized through a solid-state reaction by sintering at 1923 K for 10 h in air. The X-ray diffraction and scanning electron microscopy results confirmed that La 2 Zr 2 O 7 ceramics exhibited a pyrochlore phase with a relative density of 98.2 %. The resistance–temperature characteristics of the material revealed that La 2 Zr 2 O 7 ceramics exhibited an NTC feature within the broad temperature range of 973–1773 K in addition to maintaining high thermal constant B , and resistivity to ensure good sensitivity at high temperatures. These properties, along with high ceiling temperature, unique oxygen insensitivity, and excellent ageing coefficient of <0.7 % at 1773 K, render La 2 Zr 2 O 7 ceramics a promising candidate as thermistor materials with high-temperature NTC.
研究领域:
材料科学
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热电学
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF ALLOYS AND COMPOUNDS
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2020
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IF 4.65
Ting Liu,Xuan Chen,Huimin Zhang,Aimin Chang,Yiquan Wu
High density negative temperature coefficient (NTC) thermistor ceramics Bi 0.2-x Ce x Sr 0.5 La 0.3 TiO 3 (0 < x < 0.05) (BCSLTO) were synthesized by the Pechini method. This work is the first to characterization analysis the excellent NTC characteristics of BCSLTO ceramics at high temperatures. BCSLTO NTC thermistor ceramics have wide operating temperature is 300 °C-1000 °C, and mild sintering conditions with the conventional sintering at 1250 °C. The important electrical performance parameters of BCSLTO ceramics are as follows: the resistivities at 300 °C, 700 °C, and 1000 °C are 3.26 × 10 9 –8.99 × 10 7 Ω cm, 2.21 × 10 5 –1.05 × 10 5 Ω cm, and 1.18 × 10 3 –1.13 × 10 3 Ω cm, respectively; the thermal constant B 300/700 is 13385.9–9408.8 K; the activity energy Ea 300/700 is 1.15–0.81 eV. The resistivity and the thermal constant B can be widely control by doping Ce. In addition, the resistivity drift improves as the Ce doping content increases (below 5%). The new high-temperature Bi 0.2-x Ce x Sr 0.5 La 0.3 TiO 3 ceramic materials with mild sintering conditions, wide operating temperature and high-temperature stability can be used as potential candidates for high temperatures and harsh environments.
研究领域:
材料科学
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无机非金属材料
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电子陶瓷
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热敏器件
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高温传感
✓ 已验证
DOI
高影响因子
CERAMICS INTERNATIONAL
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2022
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IF 5.532
Yuyu Liu,Wenye Deng,Xianghui Chen,Yan Xue,Xuelian Bai,Pengjun Zhao,Huimin Zhang,Aimin Chang,Yongxin Xie
The perovskite CaMn x Zr (1- x ) O 3 ( x = 0, 0.05, 0.10, 0.15) (CMZO) NTC (Negative Thermal Coefficient) thermo-sensitive ceramic were prepared by the solid phase method that can be used as high temperature thermistor materials in the range of 200–1200 °C.The XRD pattern showed that CMZO is a finite solid solution and that a second phase, CaMnO 3 , will be formed after exceeding the solid solution limit (i.e., at x = 0.1). The thermal constant B value was found to decrease from 19521 K to 9217–9535 K, with a corresponding decrease in activation energy , E a , from 1.69 eV to 0.82 eV. The Nyquist plot indicates that the grain boundary resistance determines the overall complex impedance. Moreover, the aging drift rate (ΔR/R 0 ) was found to be lower than 4.3%, which is an indication of an excellent high temperature stability of the CMZO ceramic material.
研究领域:
材料科学
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无机非金属材料
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热敏材料
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高温电子器件
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功能陶瓷
✓ 已验证
DOI
高影响因子