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Progress in Natural Science-Materials International · 2015 · IF 1.873

Flexible heat pipes with integrated bioinspired design

Chao Yang,Chengyi Song,Wen Shang,Peng Tao,Tao Deng

In this work we report the facile fabrication and performance evaluation of flexible heat pipes that have integrated bioinspired wick structures and flexible polyurethane polymer connector design between the copper condenser and evaporator. Inside the heat pipe, a bioinspired superhydrophilic strong-base-oxidized copper mesh with multi-scale micro/nano-structures was used as the wicking material and deionized water was selected as working fluid. Thermal resistances of the fabricated flexible heat pipes charged with different filling ratios were measured under thermal power inputs ranging from 2   W to 12   W while the device was bent at different angles. The fabricated heat pipes with a 30% filling ratio demonstrated a low thermal resistance less than 0.01   K/W. Compared with the vertically oriented straight heat pipes, bending from 30° up to 120° has negligible influence on the heat-transfer performance. Furthermore, repeated heating tests indicated that the fabricated flexible heat pipes have consistent and reliable heat-transfer performance, thus would have important applications for advanced thermal management in three dimensional and flexible electronic devices.

CAS / MDL: 7727-21-1
研究领域: 材料科学 · 热能工程 · 仿生学
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Scientific Reports · 2021 ·Vol. 11 ·期 1 ·1-8 · IF 4.38

3D printed aluminum flat heat pipes with micro grooves for efficient thermal management of high power LEDs

Chang Chao,Han Zhaoyang,He Xiaoyu,Wang Zongyu,Ji Yulong

As the electronic technology becomes increasingly integrated and miniaturized, thermal management has become a major challenge for electronic device applications. A heat pipe is a highly efficient two-phase heat transfer device. Due to its simple structure, high thermal conductivity and good temperature uniformity, it has been used in many different industrial fields. A novel aluminum flat heat pipe, with micro-grooves, has in the present work been designed and fabricated by using a 3D printing technology. Aluminum powder was used as a raw material, which was selectively melted and solidified to form the shape of the heat pipe. The sintered aluminum powder increased the roughness of the inner surface of the heat pipe, and the designed micro-grooves further enhanced the capillary forces induced by the wick structure. The wettability, for the working fluid (acetone), was excellent and the capillary forces were sufficient for the working fluid to flow back in the pipe. The effects of working fluid filling ratio, on the heat transfer performance of the heat pipe, was also investigated. It was shown that a filling ratio of 10% gave the best heat transfer performance with the lowest thermal resistance. The 3D-printed flat heat pipe was, therefore, also tested for the thermal management of a LED. The temperature of the LED could be kept within 40 °C and its service life became prolonged.

研究领域: 电子工程 · 材料科学 · 热能工程
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CELLULOSE · 2023 ·Vol. 30 ·期 8 ·5171-5185 · IF 5.7

Facile construction of Janus MXene/cellulose/ZnO membrane with EMI shielding property for on-demand personal thermal management

Zhao Bencheng,Li Chengze,Chen Yongfang,Tian Qiong,Yurekli Yılmaz,Qiu Fengxian,Zhang Tao

To handle the increasingly harsh living space caused by extreme temperatures and floods of electromagnetic waves, wearable materials have been attracting much attention for decades due to their good versatile compatibility and precise utility. In this work, a Janus MXene/cellulose/ZnO nanorods membrane for accurate on-demand personal thermal management and electromagnetic interference shielding was fabricated via hydrothermal treatment and vacuum-assisted filtration, followed by a hydrophobization process. The ZnO nanorod side of obtained Janus membrane exhibits a high visible reflectance (96.3%) and infrared emissivity in the atmospheric window band (0.837). The corresponding visible absorption and average infrared reflectivity (5–25 μm in wavelength) of the MXene side are over 90% and 0.7, respectively. Remarkable temperature differences on both sides (7 °C increment on MXene side and 5 °C reduction on ZnO side compared to bare wooden board) were achieved in the validation test under direct sunshine, reflecting to the great optical properties and radiative thermal management performances of the obtained membrane. Moreover, the water contact angles (≥ 120°) indicated the hydrophobicity and associated stain resistance of this membrane. Active Joule heating and electromagnetic interference shielding characteristics have been successfully introduced into the Janus membrane by means of the integration of MXene. A rapid increase in temperature to 75 °C was attained within a 1 min of low voltage (2 V) applying. The effectiveness of the electromagnetic shielding (~ 30 dB) was higher than the commercial shielding materials. The results in general, provide a promising solution to protecting people from temperature extremes and electromagnetic waves interference in modern living space.

CAS / MDL: 16415-12-6
研究领域: 材料科学 · 环境科学 · 物理学
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Micromachines · 2022 ·Vol. 13 ·期 11 ·1949 · IF 3.523

Heat Transfer Performance of 3D-Printed Aluminium Flat-Plate Oscillating Heat Pipes for the Thermal Management of LEDs

Chao Chang,Yaoguang Yang,Lilin Pei,Zhaoyang Han,Xiu Xiao,Yulong Ji

With the rapid development of electronic technologies towards high integration, high power and miniaturization, thermal management has become an increasingly important issue to guarantee the reliability and service life of electronic devices. The oscillating heat pipe (OHP), which was governed by thermally excited oscillating motion, was considered as a promising technology to dissipate high-density heat and had excellent application prospects in many important industrial processes. A flat-plate OHP, however, was fabricated by traditional welding methods, which were difficult and inefficient, resulting in increasing the cost and wasting the production time. In this work, we adopted a new metal 3D printing technology to develop an aluminum flat-plate OHP, which made it facile to build complex inner channels with high-precision molding at one time. AlSi10Mg powders, as raw materials, were selectively melted and solidified to form the container of the flat-plate OHP. The sintered inner surface presented excellent wettability to the working fluid, which facilitated the evaporation of the working fluid. Acetone was chosen as the working fluid, and the filling ratios with a range of 40–70% were loaded into the flat-plate oscillating heat pipe to analyze its effect on heat transfer performance. It was found that the 3D-printed flat-plate OHP with a 60% filling ratio had a better heat transfer performance and a lower thermal resistance, and it was able to work properly in both vertical and horizontal operation modes. The 3D-printed flat-plate OHP had been successfully applied for the thermal management of high-power LEDs, and the results showed that the temperature of LEDs was maintained within 60 °C, and its service life was prolonged.Keywords:3D printing;oscillating heat pipe;thermal resistance;heat transfer performance

CAS / MDL: 67-64-1
研究领域: 电子工程 · 热管理技术
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Journal of Energy Storage · 2025 · IF 9.8

Photo-induced rapid polymerization of cellulose-based composite phase change materials for thermal management

He Jiang,Jiajun Hu,Pengju Yang,Yian Qian,Tonghua Ma,Renzhong Wei,Yi Zhang,Weisheng Sun,Xi Guo

Phase change materials (PCMs) have demonstrated significant potential in thermal management owing to their substantial thermal energy storage capacity and no need for additional energy consumption. Nevertheless, achieving efficient manufacturing of PCMs with high latent heat storage and superior shape stability remains a formidable challenge. In order to achieve rapid preparation of stabilized phase change material, we design a photo initiated copolymerization crosslinking strategy inside phase change material which combine encapsulation methods of graft copolymerization and porous material adsorption. Compared to traditional thermal polymerization reactions that require heating for several hours, this strategy only requires 20 min of ultraviolet light irradiation. The composite shows excellent enthalpy of 152.64 J/g benefited by the solid-solid phase change material matrix and absorbed octadecane (ODA). Addition of nickel foam (NF) provided a thermal conductivity of 1.094 W/m·K which was 270 % higher than pure composite phase change material. Due to the superior thermal energy storage capacity and thermal conductivity of composites phase change material, the surface temperature of battery in use decreased 4 °C. This work provides a novel approach for large-scale production of high-performance form-stable phase change materials which shows great applying potential in heat management of battery.

CAS / MDL: 7473-98-5 9004-34-6
研究领域: 材料科学 · 高分子化学 · 热工技术 · 储能 · 化学工程
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Surfaces and Interfaces · 2024 · IF 5.7

Multifunctional PPy/MXene decorated polylactic acid film for thermal management and electromagnetic interference shielding

Fengsen Xie,Yajie Wang,Shixun Zhang,Yamin Pan,Chuntai Liu,Changyu Shen,Xianhu Liu

Composite films composed of biodegradable materials possessing flexibility, thermal regulation capabilities, and electromagnetic interference shielding attributes represent optimal selections for wearable items and the packaging of devices. Here, we employ a simple alternating immersion and spray-coating process to fabricate flexible multifunctional films by combining hydrophobic PLA electrospun film with PPy and MXene , and investigate the thermal management and electromagnetic interference shielding properties of the films. Through alternating immersion, PPy can be rapidly in-situ polymerized on the PLA film, enhancing the surface roughness of the fibers, enabling firm integration of MXene with the film. Benefiting from the broad wavelength absorption characteristics of PPy, the solar absorption capacity of the film is significantly enhanced (97.16 %), endowing it with excellent photothermal conversion capability. Meanwhile, the high conductivity of MXene imparts the composite film with controllable and stable active heating ability, meeting heating demands under complex weather conditions. Finally, inspired by origami techniques the electromagnetic interference shielding performance of films with different folding frequencies was compared. It was found that attributed to the increased reflection paths, the film exhibited a significant improvement in electromagnetic interference shielding performance (32.58 dB to 51.96 dB) after folding. In brief, this biodegradable multifunctional composite film is an attractive candidate for future wearable products or devices packaging.

研究领域: 材料科学 · 纳米技术
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CHEMICAL ENGINEERING JOURNAL · 2024 · IF 13.3

A flexible and superhydrophobic PVDF-HFP@PVA bilayer enables high-performance radiative cooling and thermal management

Jun-Heng Fu,Qigong Zhang,Minglei Yan,Wei Tang,Yun Zeng,Yuntao Cui,Mingkuan Zhang,Hongwei Deng,Hao Kang,Xinlong Sun,Liang Qiao,Hongzhang Wang,Yang Zhao

Passive radiative cooling which dissipates heat from surfaces by reflecting sunlight and emitting radiation towards outer space, has garnered growing attention as an eco-friendly cooling strategy with zero-energy consumption. However, few studies focus on low-cost and multifunctional composite film fabricated by a straightforward and environmentally friendly method that is crucial for their large-scale applications. Herein, we introduce a facile, efficient, and scalable approach to fabricate a hydrophobic and polymer-dielectric poly (vinylidene fluoride)-hexafluoropropylene (P(VDF-HFP)@PVA hydrogel Janus film (DPP), exhibiting exceptional radiative cooling and thermal management capabilities for diverse practical applications. With the introduction of ZnO, DPP showcases the optical capability with a solar reflectance of ≈93 % and an infrared emittance of ≈96 %, endowing it with remarkable radiative cooling performance. The synergistic integration of hydrogel phase change and radiation cooling capabilities offered by the P(VDF-HFP) layer enables the DPP to achieve a subambient cooling of 8.62 °C under direct sunlight. Moreover, when applied to the thermal management of electronic devices and fruit preservation due to the phase change property, the DPP effectively reduced surface temperatures by 10 °C and 15.5 °C respectively. Its simplicity and versatility suggest that it could be widely adopted for daytime passive radiation cooling, thereby expanding its practical applications across various fields.

研究领域: 材料科学 · 能源与环境科学
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Polymers · 2023 ·Vol. 15 ·期 2 ·414 · IF 5

Fabrication and Thermal Performance of a Polymer-Based Flexible Oscillating Heat Pipe via 3D Printing Technology

Zhaoyang Han,Chao Chang

As flexible electronic technologies rapidly developed with a requirement for multifunction, miniaturization, and high power density, effective thermal management has become an increasingly important issue. The oscillating heat pipe, as a promising technology, was used to dissipate high heat fluxes and had a wide range of applications. In this paper, we reported the fabrication and heat transfer performance evaluation of a polymer-based flexible oscillating heat pipe (FOHP) prepared using 3D printing technology. The 3D-printed inner surface presented excellent wettability to the working fluid, which was beneficial for the evaporation of the working fluid. Ethanol was selected as the working fluid, and the influence of the filling ratios range of 30–60% on heat transfer performance was analyzed. It was found that a 3D-printed FOHP with a filling ratio of 40% presented the best heat transfer performance with the lowest thermal resistance, and the fabricated heat pipes could be easily bent from 0° to 90°. With the best filling ratio, the thermal resistance of the FOHPs increased with larger bending angles. In addition, the 3D-printed FOHP was successfully applied for the thermal management of flexible printed circuits, and the results showed that the temperature of flexible printed circuits was kept within 72 °C, and its service life was guaranteed.Keywords:3D printing;flexible oscillating heat pipe;thermal resistance;thermal performance

CAS / MDL: 64-17-5
研究领域: 热管理技术 · 材料科学与工程
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Energy Storage Materials · 2025 · IF 20.2

Intrinsic flame-retardant phase change materials for battery thermal management during rapid cycling and thermal runaway

Haiwei Han,Feng Xiong,Mulin Qin,Yongkang Jin,Hsing Kai Chu,Shenghui Han,Kaihang Jia,Ali Usman,Song Gao,Ruiqin Zhong,Zhenghui Shen,Ruqiang Zou

The safety of high-energy density batteries remains a significant challenge due to the risk of thermal runaway, which can result in catastrophic damage. Phase change materials (PCMs) can absorb heat and regulate temperature through reversible phase transitions, effectively mitigating the risk of thermal runaway and offering a reliable solution for battery thermal management. However, achieving effective flame retardancy in PCMs, particularly under thermal runaway conditions, remains a challenge. In this work, we report a solid-solid PCM with high flame retardancy. Phosphorus-based flame retardant groups are grafted onto a polyurethane skeleton via a straightforward and cost-effective synthesis process, achieving an intrinsic flame retardancy (LOI = 30.2 %) and a high phase change enthalpy (78.7 J/g), along with good mechanical flexibility and strength (6 MPa) with only 5 wt.% flame retardant. These advanced properties enable the material to maintain the working temperature of 18,650 batteries below 55 °C during high current operation, reduce the peak runaway temperature by 405 °C during thermal runaway, and delay ignition by 59 s. These improvements significantly enhance the safety of batteries and protect people and property.

CAS / MDL: 1571-33-1
研究领域: 材料科学 · 能源工程
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CERAMICS INTERNATIONAL · 2025 · IF 5.6

3D printing Si3N4 reinforced phase change composites with superior electrical insulation properties for thermal management

Houbao Liu,Wei Wang,Zhenbang Cheng

Effective thermal management materials are crucial for modern electronics, aerospace, and energy applications. This study investigates a novel approach by constructing a Si₃N₄ skeleton with a triply periodic minimal surface (TPMS) structure and reinforcing phase change materials (PCM) with boron nitride (BN) to develop Si₃N₄@BN/PCM composites that exhibit enhanced thermal conductivity, thermal stability and electrical insulation. Utilizing digital light processing 3D printing, a Si₃N₄ TPMS structure was prepared and subsequently reinforced with BN via vacuum-assisted infiltration into PCM. The incorporation of 3D Si₃N₄ skeleton and 2D BN flakes created a dual-scale network within the PCM, significantly increasing thermal conductivity from 0.24 W/m·K to 2.04 W/m·K. The presence of Si₃N₄ and BN notably improved thermal stability and reduced the coefficient of thermal expansion. Additionally, electrical insulation properties improved with an increase in volume resistivity and breakdown strength to 5.1 × 10 1 ⁴ Ω·cm and 62.4 kV/mm, respectively. This work demonstrates that Si₃N₄@BN/PCM composites effectively integrate high thermal conductivity, stability, and electrical insulation, thereby meeting the stringent demands of thermal management applications.

CAS / MDL: 13048-33-4 85073-19-4
研究领域: 材料科学 · 热能工程
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ACS Applied Materials & Interfaces · 2022 · IF 10.383

Leakage-Proof Flexible Phase Change Gels with Salient Thermal Conductivity for Efficient Thermal Management

Hong Cao,Yuan Li,Weidi Xu,Jie Yang,Zhengying Liu,Lu Bai,Wei Yang,Mingbo Yang

Phase change materials (PCMs) as one of the most potential latent heat storage techniques have been widely used for thermal management and energy storage. However, simultaneously imparting flexibility, high thermal conductivity, and considerable energy storage density to organic PCMs remains challenging. In this work, a coupling strategy combining substance exchange and magnetic orientation has been proposed to fabricate phase change gels (PCGs) with thermally induced flexibility and high through-plane thermal conductivity. In the PCGs, synthesized boron nitride/ferroferric oxide (BN@Fe3O4) particles and polyacrylic acid (PAA) precursor liquid are introduced to polyethylene glycol (PEG) aqueous solution, and a magnetic field is applied in the process of PAA network construction to promote ordered arrangement of BN@Fe3O4 along the direction of the magnetic field. Consequently, PEG is wrapped by the cross-linked PAA supporting network, forming PCGs with excellent shape stability and thermally induced flexibility. The vertical orientation structure of BN@Fe3O4 endows the PCGs with an enhanced through-plane thermal conductivity of up to 1.07 W m–1 K–1 at a BN@Fe3O4 loading of 25.6 wt % with an additional enhancement of 215% compared to the composite without BN. The thermally conductive leakage-proof PCGs present great application potential in heat storage and management.

研究领域: 材料科学 · 能源工程
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Gels · 2023 ·Vol. 9 ·期 4 ·317 · IF 4.6

Encapsulation of Paraffin Phase-Change Materials within Monolithic MTMS-Based Silica Aerogels

Linlin Xie,Xiaoxu Wu,Guichao Wang,Yury M. Shulga,Qiong Liu,Ming Li,Zhi Li

To address the leakage issue of paraffin phase-change materials in thermal management, a monolithic MTMS-based silica aerogel (MSA) is employed to encapsulate paraffin through a facile impregnation process. We find that the paraffin and MSA form a physical combination, with little interaction occurring between them. The prepared no-leakage paraffin/MSA composites have a density of 0.70 g/cm3and exhibit good mechanical properties and nice hydrophobicity, with a contact angle of 122°. Furthermore, the average latent heat of the paraffin/MSA composites is found to reach up to 209.3 J/g, about 85% of the pure paraffin’s latent heat, which is significantly larger than other paraffin/silica aerogel phase-change composite materials. The thermal conductivity of the paraffin/MSA remains almost the same as that of the pure paraffin (~250 mW/m/K), without any heat transfer interference from the MSA skeletons. All these results indicate that MSA can effectively serve as a carrier material for encapsulating paraffin, which is beneficial for expanding the applications of MSAs in thermal management and energy storage.

研究领域: 材料科学 · 能源工程
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