FUEL
·
2020
·
IF 5.578
Gang Chen,Zhichao Zhou,Xiaodan Shi,Xiaolong Zhang,Sanbao Dong,Jie Zhang
Small molecule flow improver for heavy oil recovery has attracted great attention in oilfield chemistry . In this study, 24 alkylbenzenesulfonates were synthesized and evaluated as crude oil flow improvers. The results show that all of the alkylbenzenesulfonates were effective, the chromium alkylbenzenesulfonate (CrDBS) and zinc alkylbenzenesulfonate (ZnDBS) were found to have the best performance with the viscosity reduction rate of higher than 90%. Besides, the CrDBS and ZnDBS can depress the pour point of the crude oil sample by 21.0 °C and 16.0 °C, respectively. The co-crystallization of alkylbenzenesulfonate with the saturated hydrocarbons in the crude oil could disorder the wax crystals and depress the pour point. In addition, DSC was used to reveal the mechanism of viscosity reduction and pour point depressing by alkylbenzenesulfonates. The flow improver can disturb the formation of hydrogen bonds and the π-π interaction bonds among the polycyclic aromatic hydrocarbons and the resin macromolecules . Besides, the field test using ZnDBS confirmed its good performance and promising application potential in enhancing the heavy oil recovery.
研究领域:
石油化学
·
油田开发
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DOI
高影响因子
Polymer Chemistry
·
2025
·Vol. 16
·期 9
·1044-1056
·
IF 3.9
He-Ying Wang,Feng-Yu Zhang,Si-Hao Li,Zi-Yang Song,Yang Wang,Yi-Xian Wu
The controlled/living cationic copolymerizations of isobutylene (IB) with alkenyl styrenes including 4-allylstyrene (AS), p-(3-butenyl)-styrene (BS) and p-(5-hexenyl)-styrene (HS) were carried out in n-hexane/CH2Cl2 (6/4 v/v) at −80 °C using a t-BuCl/FeCl3/iPrOH initiating system. The random copolymers of IB with AS, BS or HS could be obtained without crosslinking and the contents of AS units in the copolymers linearly increased from 0.71 mol% to 14.23 mol% with an increase in the feed ratio of AS. The monomer reactivity ratios (r) were determined to be rAS = 4.16 and rIB = 1.66 by the Fineman–Ross method, respectively. The livingness of cationic copolymerization of IB with AS was confirmed by All Monomer In (AMI) and Incremental Monomer Addition (IMA) techniques at −80 °C. The yields, Mn and Mw/Mn of the resulting copolymers decreased with increasing polymerization temperature (Tp) and the apparent activation energy (Ea) depended on Tp. The pendant vinyl groups in the above poly(IB-co-AS) copolymers can be completely converted into hydroxyl groups, carboxyl groups or epoxy groups via hydroboration/oxidation, thiol–ene click reaction or epoxidation. The hydrophilicity on the film surface of functionalized copolymers with hydroxyl, carboxyl or epoxy pendant groups could be improved by introduction of the functional groups and the water contact angle (WCA) of poly(IB-co-AS) with epoxy pendant groups decreased from 134.9° to 78.7° upon increasing the molar content of epoxy groups from 0 to 3.99%. Therefore, the random isobutylene/alkenyl styrene copolymers containing plentiful pendant vinyl groups and versatile polar groups would have potential applications in highly reactive elastomers, adhesives and amphiphilic materials with inorganic fillers.
研究领域:
材料科学
·
高分子化学
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产品关联
DOI
高影响因子
TENSIDE SURFACTANTS DETERGENTS
·
2022
·Vol. 59
·期 3
·221-230
·
IF 1.058
Fengli Gong,Hong Xu,Jinxiang Dong
Sodium oxalate (Na 2 C 2 O 4 ) is an excellent phosphorus-free agent, but in sodium oxalate-containing detergents with sodium dodecylbenzene sulfonate (SDBS) and sodium carboxymethyl cellulose (CMC), significant ash deposition occurs on cotton fabrics. SDBS is the main anionic surfactant in modern detergents and cotton fiber is the most commonly used textile fiber. In this study, sodium lignosulfonate (LS) was investigated for its ability to prevent redeposition in SDBS-Na 2 C 2 O 4 -CMC-LS formulations. The effects of LS on ash content, whiteness, optimum washing temperature, calcium oxalate morphology, zeta potential and surface tension were carefully analyzed. The results showed that the addition of LS significantly improved the prevention of ash deposits on cotton fibers. The ash content was less than 0.46% and a small amount of particles were scattered on the cotton fibers. LS showed good dispersibility but had little effect on the washing power and zeta-potential.
研究领域:
材料科学
·
纺织工程
·
表面化学
✓ 已验证
DOI
高影响因子
Chemical Engineering and Processing-Process Intensification
·
2023
·
IF 4.3
Hong Shi,Weihua Zhu
Excessive amounts of free acids will significantly reduce the quality of heavy alkylbenzene sulfonic acid and its downstream products. To get rid of the excess free acids in heavy alkylbenzene sulfonic acid, a novel three-step deacidification technique called barium salt neutralization method was developed with the aware of “process intensification” in this work. Various factors affecting the deacidification process were thoroughly studied. Results show that using this deacidification method, the free acids content in heavy alkylbenzene sulfonic acid can be reduced from 1.5% to less than 0.1% at the producing condition of room temperature, atmospheric pressure, reusable green solvent, and short time. The free acids removal rate and recovery rate of feed can reach to 96.7% and 95.3%, respectively. It has been demonstrated that the barium salt neutralization method is an effective way to lower the amount of free acids in heavy alkylbenzene sulfonic acid, and can be readily turned into practical applications.
研究领域:
化学工程
·
环境科学
✓ 已验证
产品关联
DOI
高影响因子
TENSIDE SURFACTANTS DETERGENTS
·
2020
·Vol. 57
·期 2
·129-137
·
IF 1.089
Shanshan Kong,Lei Li,Chen Chen,Xu Li,Lei Liu,Jinxiang Dong
The Fischer-Tropsch synthesis can be used to achieve a high content of α-olefin (C 5 –C 11 ) products using Fe-based catalysts. Herein, C 6 and C 8 α-olefins have been selected as examples for the alkylation of benzene catalyzed by using an acidic ionic liquid (Et 3 NHCl-AlCl 3 ) to obtain a variety of intermediates used to prepare surfactants. A series of alkylbenzenes were synthesized by controlling the reaction conditions and their corresponding alkylbenzene sulfonates were successfully obtained by sulfonation and neutralization. It was found that the single chain alkylbenzene sulfonate derivatives did not display typical surfactant properties due to their short hydrophobic chain length. However, double chain alkylbenzene sulfonates exhibit excellent surfactant properties, and decrease the water surface tension compared to commercially available sodium dodecylbenzene sulfonates. A γ cmc (mN m −1 ) value of 32.70 was observed for sodium di-hexylbenzene sulfonates, 29.98 for sodium di-octylbenzene sulfonates, and 36.0 for sodium dodecylbenzene sulfonates. In addition, double chain alkylbenzene sulfonates show an improved emulsifying and wettability performance compared to sodium dodecylbenzene sulfonate. This demonstrates that the capability of alkylbenzene sulfonate to decrease the surface tension are closely related to the total carbon number of side chain-alkyl groups connected to the benzene ring.
研究领域:
化学工程
·
材料科学
✓ 已验证
DOI
高影响因子
MOLECULAR CRYSTALS AND LIQUID CRYSTALS
·
2020
·
IF 0.512
Gege Jin,Yongmin Guo,Limin Wu,Yi Li,Baozong Li,Yonggang Yang
Three series of meta-perfluoroalkylphenol esters are synthesized. Both SmA and SmC phases are identified. Their clearing points increase with increasing the perfluorocarbon chain length, while decrease with increasing the alkoxy chain length. Comparison of the 3-tridecafluorohexylbenzoates and 3-tridecafluorohexylphenol esters, the 3-tridecafluorohexylbenzoates show higher clearing points, indicating that the direction of the ester bond plays an important role in the thermostability of the liquid crystalline phases. Moreover, it was proposed that the compounds with short and long alkoxy chains packed into different structures.
研究领域:
材料化学
·
分子结构研究
✓ 已验证
产品关联
DOI
高影响因子
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
·
2018
·
IF 2.829
Ling Zhang,Changming Zhao,Yulian Jiang,Yue Wang,Wensheng Yang,Tiexin Cheng,Guangdong Zhou
The effect of sodium dodecyl benzene sulfonate (SDBS) on morphology and structure of calcium silicate hydrate (CSH) prepared via precipitation in solution were investigated by XRD , FT-IR and SEM techniques. The formation mechanism of spherical shell of CSH was also discussed. The results suggested that different concentrations of SDBS affect differently the structure and morphology of CSH. When the SDBS concentration was less than the critical micelle concentration (CMC), the agglomeration among CSH particles reduced, the degree of order of CSH increased and the polymerization degree of Si-O decreased. When the SDBS concentration was greater than CMC, the spherical micelles were fabricated in aqueous solution, which induced CSH to form a spherical structure in the shape of spherical micelle rather than produce a layered CSH under the normal condition. After centrifugation and vacuum drying procedures, internal micelles of CSH spherical particles disappeared and turned into spherical shell structures. This experiment provides a reliable method for the preparation of CSH with specific morphology and size, which can simplify experimental conditions and increase the possibility of its application in the field of drug delivery.
研究领域:
材料科学
·
化学工程
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
·
2018
·
IF 2.891
Sujitraj Sheth,Mengyuan Li,Qijun Song
Due to clinical importance, detection of dopamine by using easy and rapid method is still ongoing challenge. Here we present a simple and quite efficient method for dopamine (DA) detection in alkalescent medium using in situ prepared Ru(II) complex and sodium dodecyl benzyl sulfonate (SDBS) as highly luminescent luminophore. The luminescence enhancement in the Ru(II) complex (Ru-CIP) has been observed in the miceller medium formed by SDBS. The capability to successively quench the luminescence intensity has been tested for variety of molecules and only dopamine as analyte found to be able to quench luminescence effectively. Hence selective quenching of luminescence by dopamine was used as a tool to detect dopamine and two linear concentration ranges has been established from 0.1 μM to 1μM and from 2 μM to 10 μM with limit of detection (LOD) is 6.6 nM (S/N = 3). Spectral evidence showed that luminescence quenching mechanism arose via Forster resonance energy transfer (FRET) among oxidized DA (i.e. DA quinone) and in situ generated Ru-CIP and SDBS assembly. Due to ultra sensitivity and high selectivity of the prescribed (Ru-CIP-SDBS) luminescent probe has a strong potential for practical analytical application in clinical diagnosis.
研究领域:
分析化学
·
临床诊断
·
生物医学
✓ 已验证
产品关联
DOI
高影响因子
TENSIDE SURFACTANTS DETERGENTS
·
2023
·Vol. 60
·期 4
·368-375
·
IF 1
Yarou Yang,Xu Li,Jinxiang Dong
Benzene and 1-dodecene are often alkylated to produce linear alkylbenzene (LAB). LAB is the raw material for the production of linear alkylbenzene sulfonate (LAS), a very important anionic surfactant used in both industrial cleaning and commercial laundry processes, as well as in household laundry detergents. In the present study, we investigated the use of [Et 3 NH]Cl–2AlCl 3 modified with CuCl 2 as a catalyst for the alkylation of benzene with 1-dodecene, specifically looking at the effect of reaction conditions on product activity. The results showed that a conversion of 1-dodecene of 100.0 % and a selectivity of LAB of 93.79 % could be obtained when the following ideal reaction conditions were present: molar ratio of benzene/1-dodecene = 6, reaction temperature = 25 °C, reaction time = 10 min, stirring speed of 1000 rpm and addition of 5.0 mol % CuCl 2 ). The catalyst concentration was 7.0 mol %. FTIR and 31 P-TMPO-NMR measurements were performed to characterise the ionic liquid before and after the addition of CuCl 2 . After the addition of CuCl 2 , it was found that the acidity of the ionic liquid had decreased. The regeneration of the catalyst was also investigated and the cause of inactivation of the catalyst was determined. The results showed that CuCl 2 modified the ionic liquids and decreased the benzene/1-dodecene ratio, but the high product selectivity was maintained.
研究领域:
化学工程
·
催化剂科学
✓ 已验证
产品关联
DOI
高影响因子
ENERGY & FUELS
·
2023
·
IF 5.3
Zhiqi Zhao,Xue Xia,Yanan Li,Daiwei Liu,Wei Cai,Chuanxian Li,Guangyu Sun,Bo Yao,Fei Yang
Dodecylbenzenesulfonic acid (DBSA) is injected into wellbores as an asphaltene dispersant to alleviate asphaltene deposition problems. The addition of DBSA will change the dispersion of asphaltenes in the crude oil, affecting the wax precipitation property of the crude oil as well as the adsorption behavior of asphaltenes at the oil–water interface, thus significantly altering the W/O emulsion’s stability. In order to provide better theoretical guidance for oil–water separation in oilfield gathering and production processes, in the paper, the effects of DBSA concentration (from 0 to 500 ppm) on the emulsions’ stability containing both asphaltenes and paraffin wax and the mechanism were systematically investigated at two different temperatures (30 and 15 °C) based on the wax precipitation and rheological properties of the model crude oil, the oil–water interface adsorption properties, and the macroscopic and microscopic properties of the emulsion. The outcomes demonstrated that the test temperature had a highly substantial impact on the model emulsion. The main element affecting the stability of the emulsion at 30 °C (above the wax appearance temperature (WAT)) was the interfacial structure’s strength. The low-temperature flowability of the oil phase primarily controlled the process of emulsion stabilization at 15 °C (below the WAT). Furthermore, we speculate that the wax crystals could precipitate on the surface of the emulsified droplets, which also facilitated emulsion stability at 15 °C. Combining the above experimental observations, the mechanism of DBSA concentration affecting the emulsion stability was proposed, which would contribute to solving the issues in the emulsion breaking and dewatering process of crude oil emulsions.
研究领域:
石油工程
·
界面化学
·
流变学
✓ 已验证
产品关联
DOI
高影响因子
NEW JOURNAL OF CHEMISTRY
·
2022
·Vol. 46
·期 19
·9229-9237
·
IF 3.925
Jiabin Liu,Yuxiang Xin,Yiyang Bai,Wei She,Jing Wang,Gaungming Li
The selective oxidation of alkylbenzenes contributes greatly to the production of high-value chemicals. However, developing novel and efficient catalysts remains a great challenge. To explore new and efficient catalysts, a series of POMs of H(4+n)SiMo(12−n)VnO40 (SiMoVn, n = 1, 2 and 3) were reacted with rht-MOF-1 ([Cu6O(TZI)3(H2O)6]4·nH2O) by a one-pot self-assembly solvothermal method. As a result, three SiMoVn@rht-MOF-1 (1, n = 1; 2, n = 2 and 3, n = 3) were isolated. Single crystal analysis revealed that SiMoVn were successfully introduced in the cages of rht-MOF-1. When complex 3 was employed as a catalyst, it effectively catalyzed the selective oxidation of alkylbenzene with a conversion of 99% and selectivity of 99% under optimized reaction conditions. Recycling experiments proved that complex 3 is stable and recyclable after six cycles. In comparison with analogous catalysts, complex 3 exhibits outstanding catalytic performance. Furthermore, the kinetics and reaction mechanism were investigated and verified by EPR and XPS analysis. This approach paves a facile route to prepare POMs@MOFs for the selective oxidation of various alkylbenzenes.
研究领域:
化学
·
材料科学
✓ 已验证
DOI
高影响因子
DALTON TRANSACTIONS
·
2020
·Vol. 50
·期 2
·715-721
·
IF 4.174
Jianhui Xie,Bing Li,Huijing Liu,Yijun Li,Jian-Bo He,Yanzhen Zheng,Kai-Chung Lau,Tai-Chu Lau
Ferrate(VI), [FeO4]2−, is a very powerful oxidant that can oxidize a wide variety of inorganic and organic compounds. However, the mechanisms of many of these oxidation reactions have not been studied in detail. In this work, we have investigated the kinetics and mechanism of the oxidation of 4-alkylbenzenesulfonates by ferrate in aqueous solutions at pH 7.45–9.63 by UV/Vis spectrophotometry. The reactions are first order with respect to both [ferrate] and [4-alkylbenzenesulfonate]. The second-order rate constants for the oxidation of 4-isopropylbenzenesulfonate by ferrate at 25 °C and I = 0.3 M are found to be (5.86 ± 0.08) × 10−1 M−1 s−1 and (4.11 ± 1.50) × 10−3 M−1 s−1 for [Fe(O)3(OH)]− and [FeO4]2−, respectively, indicating that [Fe(O)3(OH)]− is two orders of magnitude more reactive than [FeO4]2− and is the predominant oxidant in neutral and slightly alkaline solutions. This is further supported by the effect of the ionic strength on the rate constant. No solvent kinetic isotope effect (KIE) was found but a moderate primary KIE = 1.6 ± 0.1 was observed in the oxidation of 4-ethylbenzenesulfonate and 4-ethylbenzenesulfonate-d9. Alkyl radicals were trapped by CBrCl3 in the oxidation of alkylarenes by ferrate. Combined with DFT calculations, a hydrogen atom transfer (HAT) mechanism was proposed for the reactions between [Fe(O)3(OH)]− and 4-alkylbenzenesulfonates.
研究领域:
化学
·
环境科学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
危险品化学品经营许可证（带存储）