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环氧化物
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY · 2012 ·Vol. 113 ·期 2 ·939-945 · IF 1.604

Thermal and mechanical properties of epoxy resin toughened with epoxidized soybean oil

Chen Yan,Yang Liting,Wu Jiahui,Ma Lijun,Finlow David E.,Lin Shaoquan,Song Keming

A series of new modified epoxy resin (EP) cured products were prepared from epoxidized soybean oil and commercial epoxy resin, with methyl nadic anhydride as curing agent and 1-methylimidazole as promoting agent. The thermal properties of the resins were characterized by DMA and TG; DSC was used to determine the curing process. Fourier transform infrared spectroscopy was utilized to investigate their molecular structures and scanning electron microscopy was used to observe the micro morphology of their impact fracture surfaces. Tensile and impact testing was employed to characterize the mechanical properties of the cured products. The combination of commercial EP with 20 wt% ESO resulted in a bioresin with the optimum set of properties: 130.5 °C T g , 396.9 °C T 50 % , 74.89 MPa tensile strength, and 48.86 kJ m −2 impact resistance.

研究领域: 高分子材料 · 复合材料科学 · 生物基聚合物 · 材料化学 · 热固性树脂
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