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CARBOHYDRATE POLYMERS · 2020 · IF 7.182

MPEG grafted alkylated carboxymethyl chitosan as a high-efficiency demulsifier for O/W crude oil emulsions

Renliang Lyu,Ting Xia,Cheng Liang,Cheng Zhang,Zeqin Li,Lichun Wang,Yi Wang,Ming Wu,Xiaogang Luo,Jiayu Ma,Cunwen Wang,Caili Xu

Three kinds of novel environmentally benign and high-efficiency crude oil demulsifiers were prepared using methoxy polyethylene glycol (MPEG) to modify alkylated carboxymethyl chitosan (ACMC). Structures of the demulsifiers were confirmed using FT-IR and 1 H NMR, and the relationship between surface tension and concentration was tested. Demulsification performance was investigated using the bottle test method with oil-in-water (O/W) emulsions that were prepared in lab conditions. The demulsification efficiency was as high as 79.1 %–84.9 %, and the possible mechanism of the demulsification process is discussed. Results show that MPEG-grafted ACMC (MPEG-ACMC) has a promising application as a demulsifier for dealing with emulsified O/W crude oil.

研究领域: 化学工程 · 环境科学 · 材料科学
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JOURNAL OF APPLIED POLYMER SCIENCE · 2017 ·Vol. 135 ·期 7 ·45867 · IF 1.86

MPEG grafted quaternized carboxymethyl chitosan for demulsification of crude oil emulsions

Guangtan Fan,Renliang Lyu,Xiao Gao,Cheng Liang,Cunwen Wang

Four novel environmentally friendly and highly branched crude oil demulsifiers were prepared by using different molecular weight ( M n = 350, 750, 1000, 1900 g/mol) of methoxy poly(ethylene glycol) to modify quaternized N,O-carboxymethyl chitosan. Fourier transform infrared and 1 H-nuclear magnetic resonance were employed to confirm the structure of the demulsifiers. The surface tension of demulsifies was determined and hydrophile–lipophile balance value was calculated at the critical micelle concentration. The demulsification performance was evaluated by the bottle test method against water-in-oil emulsions simulated in the laboratory and it was found that the dehydration rate of four demulsifiers can come to 74.2%–80.4%, which have better demulsification performance than the commercial demulsifier JL-1. Demulsification mechanism was discussed, and it was encouraging to find that the tiny water droplets in the emulsion coalesced to form the water phase and separated with the water from the polarization microscope. Results show that methoxy poly(ethylene glycol) grafted quaternized carboxymethyl chitosan has a promising application as a demulsifiers for dealing with W/O crude oil emulsions. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135 , 45867.

研究领域: 化学工程 · 材料科学 · 环境科学
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