The potential of graphene for electric field sensing is limited by its zero bandgap. This study employs a combined first-principles and experimental approach to enhance its response via heterojunctions with ZnO, SnO2, and Al2O3. Calculations reveal spontaneous formation and interfacial charge transfer in all systems, with SnO2/graphene exhibiting the most significant charge transfer (0.3636 e) and inducing a finite bandgap (0.017–0.064 eV). Experimentally, SnO2-graphene/PDMS composites demonstrated the highest relative permittivity (3.19) and a 7.76% increase in normalized induced voltage over pure PDMS within 50 Hz–50 kHz. This work establishes a direct correlation between interfacial charge transfer, bandgap opening, and macroscopic dielectric enhancement, identifying SnO2/graphene as the optimal heterojunction. The integrated multi-scale methodology provides a clear design principle for high-performance, graphene-based field-sensitive materials.
The advancement of intelligent soft actuators is progressively emphasizing the incorporation of environmental sensing capability to actuation, thereby enhancing the adaptability and interactivity of artificial systems. In the current situation where the sensing and actuation functions of soft actuators are generally separated, this work proposes an autonomous three-dimensional (3D) noncontact sensory actuator (NSA), based on the coupling of ″dielectric polarization-electrothermal conversion-thermal actuation″ triple effects. Specifically, the NSA hybrid membrane is composed of multiple interpenetrating networks, including a boron nitride nanosheet (BNNS) dielectric network for electrostatic field sensing and polarization, a silver nanowires (AgNWs) percolation network for dielectric enhancement and electrothermal conversion, and thermally contracted shape memory fiber (SMF) and thermally expanded polydimethylsiloxane (PDMS) networks for directional actuation. Based on the principle of electrostatic field and dielectric polarization, the SMF/BNNS composite (SMF-BN) fibrous membrane can logically sense the noncontact 3D motion, static/dynamic state of external objects, and distinguish material categories. Subsequently, the output sensing potential facilitates the built-in AgNWs nanonetwork heater to trigger electrothermal actuation of NSA. Lastly, as a biomimetic tongue, the autonomous noncontact “sensing-decision-actuating” of NSA is verified by seamless energy conversion in the process of sensing “prey” approaching and capturing. The proposed sensory actuator would facilitate multimodal integration for future wearable and human-machine-environment interaction technologies.
危险品化学品经营许可证（带存储）