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APPLIED SURFACE SCIENCE · 2014 · IF 2.538

Large-scale fabrication of superhydrophobic polyurethane/nano-Al2O3 coatings by suspension flame spraying for anti-corrosion applications

Xiuyong Chen,Jianhui Yuan,Jing Huang,Kun Ren,Yi Liu,Shaoyang Lu,Hua Li

This study aims to further enhance the anti-corrosion performances of Al coatings by constructing superhydrophobic surfaces. The Al coatings were initially arc-sprayed onto steel substrates, followed by deposition of polyurethane (PU)/nano-Al 2 O 3 composites by a suspension flame spraying process. Large-scale corrosion-resistant superhydrophobic PU/nano-Al 2 O 3 -Al coatings were successfully fabricated. The coatings showed tunable superhydrophilicity/superhydrophobicity as achieved by changing the concentration of PU in the starting suspension. The layer containing 2.0   wt.%PU displayed excellent hydrophobicity with the contact angle of ∼151° and the sliding angle of ∼6.5° for water droplets. The constructed superhydrophobic coatings showed markedly improved anti-corrosion performances as assessed by electrochemical corrosion testing carried out in 3.5   wt.% NaCl solution. The PU/nano-Al 2 O 3 -Al coatings with superhydrophobicity and competitive anti-corrosion performances could be potentially used as protective layers for marine infrastructures. This study presents a promising approach for fabricatiing superhydrophobic coatings for corrosion-resistant applications.

研究领域: 材料科学 · 表面工程 · 腐蚀与防护 · 海洋工程 · 高分子材料 · 金属涂层
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