Polypropylene (PP) is regarded as an environmentally friendly cable insulation material to replace cross-linked polyethylene (XLPE) owing to its thermoplastic nature, high-temperature resistance, and outstanding dielectric characteristics. Grafting modification was applied to satisfy the demand for a higher voltage power grid, and it was proved to be effective in enhancing the insulating performance of PP. The electrical tree is a common cause for cable insulation failure. This study examines the electrical tree initiation and growth characteristics of methyl methacrylate (MMA)-grafted PP under different temperatures. Our results indicate that high temperature can promote the electrical treeing process while grafting modification can hinder the process. The trap characteristics show that more deep traps are introduced in the grafted materials that can limit the motion of electrons and, thus, restrict the electrical tree initiation process. The crystallization morphology shows that the size of spherulites increases and the boundaries of the spherulites become blurry with higher MMA content. The compressed amorphous region and the tortuous boundaries of the crystalline can hinder the electrical treeing process. High temperature may improve charge carrier mobility and enhance the molecular chain relaxation, thus enlarging the free volume and finally accelerating the treeing process. The findings of this study would serve as a reference for designing grafted PP insulation for power cables.
It remains challenging to promptly inhibit and autonomically heal electrical trees inside insulating dielectrics, which are caused by sustained strong electrical fields and substantially shorten electronic device lifetimes and even cause premature failure of electrical equipment. Therefore, we demonstrate a magnetically targeted ultraviolet (UV)-induced polymerization functional microcapsule (MTUF-MC) to endow insulating materials with physical and electrical dual-damage self-healing capabilities. Specifically, Fe3O4@SiO2 and TiO2 nanoparticles, which serve as magnetic targets and UV shields (thereby preventing the healing agent from prematurely triggering), constitute a functional microcapsule shell, ensuring a low dopant concentration and excellent self-healing ability of the epoxy composites without affecting the intrinsic performance of the matrix. By exploiting insitu electroluminescence originating from electrical trees, UV-induced polymerization of healing agent is handily triggered without any applying external stimuli to intelligently, contactlessly, and autonomously self-healing electrical trees inside insulating dielectrics.
危险品化学品经营许可证（带存储）